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All Journal International Journal of Acta Material
A. Kamari
Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris 35900. Tanjong Malim, Perak, Malaysia
Chemistry Materials Science & Nanotechnology Physics

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Extraction of Tannin Compounds from Samanea saman (Jacq.) Merr Leaves and Their Application as Corrosion Inhibitor in ST 37 Steel S. Kasim; S. Fauziah; R. Ananda; I. W. Sutapa; A. Kamari
International Journal of Acta Material Vol. 1 No. 1 (2024): August 2024
Publisher : Faculty Mathematics and Natural Sciences, Halu Oleo University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62749/ijactmat.v1i1.3

Abstract

Research has been conducted on extracting tannin compounds from Samanea saman (Jacq) Merr leaves and their potential application as corrosion inhibitors for ST 37 steel. The purpose of this study was to evaluate the impact of adding Samanea saman (Jacq) Merr leaf extract on the corrosion rate and inhibition efficiency of ST 37 steel when exposed to 25% acetic acid. The immersion process was carried out with different concentrations: 0%, 5%, 10%, 20%, and 30%, and with immersion time intervals of 2, 4, 6, and 8 days. The concentration and optimum immersion time results were then further tested at temperatures of 20ºC, 30ºC, and 40ºC. The test results indicate that corrosion occurs uniformly on the surface of the steel. The corrosion rate was determined using the weight loss method, and it was observed that the weight reduction of the steel without inhibitor was higher compared to that of the steel treated with Samanea saman (Jacq) Merr leaf extract inhibitor. Based on the study findings, the highest inhibition efficiency was achieved with a concentration of 20% and an immersion time of 6 days, resulting in an efficiency of 87.3464% and a corrosion rate of 1.9143 mpy. Regarding temperature variations, the highest inhibition efficiency was observed at 20ºC, with an efficiency of 66.6908% and a corrosion rate of 2.8435 mpy.
The Latest Green Synthesis of Silver Nanoparticles Using Cocoa Fruit Peel Extract (Theobroma cacao L.) as a Bioreductant S. Kasim; W. Riskiyani; A.N. Zahra; I W. Sutapa; A. Kamari; C. Baskar
International Journal of Acta Material Vol. 2 No. 1 (2025): August 2025
Publisher : Faculty Mathematics and Natural Sciences, Halu Oleo University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62749/ijactmat.v2i1.17

Abstract

Cocoa fruit peel contains a variety of phytochemicals, including tannins, flavonoids, alkaloids, terpenoids, and saponins, which are anticipated to act as reducing agents. The green synthesis method employs methanol as a solvent to extract organic compounds from cocoa fruit peel, which serve as bio-reductants. This study aims to synthesize silver nanoparticles utilizing cocoa fruit peel extract as a bio-reductant. It involved the preparation of silver nitrate (AgNO₃) solutions at varying concentrations of 0.5 mM, 1 mM, and 1.5 mM. Characterization of the nanoparticles was conducted using a UV-Vis spectrophotometer and a Particle Size Analyzer (PSA). The study observed the formation of silver nanoparticle colloids after 30 minutes of stirring, as evidenced by a color change in the colloid to brown. UV-Vis spectrophotometer analysis revealed a maximum wavelength of 461 nm with an absorbance value of 2.032. Notably, as the concentration of silver nitrate (AgNO₃) increased, the absorbance value correspondingly increased. The PSA results indicated that the silver nanoparticles had an average size of 96.08 nm.
Co-Authors A.N. Zahra C. Baskar I W. Sutapa I. W. Sutapa R. Ananda S. Fauziah S. Kasim W. Riskiyani