Abstract: This study aims to analyze the effect of the tryout policy on student achievement in chemistry class XII Science at SMAN 1 Talibura. The data collection method uses a documentation study with a try out as an independent variable and national exam as the dependent variable. The population is Talibura State High School, students. The research sample included all students of class XII Science. Test the validity of the instrument using the Spearman-Brown formula and reliability using the Alpha formula from Cronbach, and fulfilling valid and reliable requirements. Hypothesis testing uses the formula of normality, linearity, simple linear regression, F test, and t-test. The results obtained a probability value of 0.016 ≤ 0.05 and the results of the analysis where the significance is constant 0,000 <0.05 and the significance of Try out are 0.033 <0.05 so it can be concluded that the tryout variable is significantly correlated with the national examination variable. Testing the effect of Try Out on chemistry learning outcomes obtained a constant T count of 6.351 and Try out 2.167 is greater than the T-table (1.9853) then H0 is rejected and H1 is accepted. While the value of F-count = 5.892
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