Indonesian Journal of Chemistry
Vol 21, No 2 (2021)

Development of Voltammetry Analysis Method of Copper Metal Ions by Solid-State Membrane with Carbon Nanotube

Suyanta Suyanta (Department of Chemistry Education, Universitas Negeri Yogyakarta, Jl. Colombo No. 1, Yogyakarta 55281, Indonesia)
Sunarto Sunarto (Department of Chemistry Education, Universitas Negeri Yogyakarta, Jl. Colombo No. 1, Yogyakarta 55281, Indonesia)
Regina Tutik Padmaningrum (Department of Chemistry Education, Universitas Negeri Yogyakarta, Jl. Colombo No. 1, Yogyakarta 55281, Indonesia)
Karlinda Karlinda (Department of Chemistry Education, Universitas Negeri Yogyakarta, Jl. Colombo No. 1, Yogyakarta 55281, Indonesia)
Illyas Md. Isa (Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia)
Rahadian Rahadian (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Padang, Jl. Prof. Dr. Hamka, Padang 25173, West Sumatera, Indonesia)



Article Info

Publish Date
23 Mar 2021

Abstract

This study was aimed to develop a method for metal analysis in continuous integration using voltammetry techniques. The research subject was copper(II) ions. The objects of research were linearity, scan rate, repeatability of readings, and the presence of Cu(II) levels in well water samples. In this study, a selective electrode was developed with a solid membrane voltammetry system using differential pulse voltammetry measurement. The results showed the regression line of voltammetry method, y = 10.265 ln (x) + 330.47, with a correlation value of 0.9654, the optimum scan rate was 10 mV/s, and within five repetitions of each measurement for one electrode, it showed good repeatability. Meanwhile, the result of regression with the UV-Vis spectrophotometric method for Cu(II) was y = 0.12386x + 0.00879 with a correlation value of 0.9943. The voltammetry method was found to be much better than the UV-Vis method because it was able to be used for analysis up to a concentration of 6.35 × 10–4 ppm (or 1.00 × 10–11 M), while the UV-Vis method was only able to analyze up to 1.5 ppm (or 2.36 × 10–5 M).

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...