Indonesian Journal of Chemistry
Vol 22, No 3 (2022)

Synthesis of Mesoporous Silica from Beach Sand by Sol-Gel Method as a Ni Supported Catalyst for Hydrocracking of Waste Cooking Oil

Siti Salamah (Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan, Jl. Kapas 9, Semaki, Umbulharjo, Yogyakarta 55166, Indonesia)
Wega Trisunaryanti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Indriana Kartini (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Suryo Purwono (Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
27 May 2022

Abstract

Mesoporous silica (MS) supported by nickel was synthesized from Parangtritis beach sand and assessed for its activity and selectivity as catalysts in hydrocracking waste cooking oil into biofuel. The synthesis of MS was done by the sol-gel method. Ni/MS catalysts using Ni weight variations of 1, 5, and 10 wt.% were denoted as Ni/MS1, Ni/MS5, and Ni/MS10 and were compared to standard mesoporous silica (Ni/SBA-15). The catalysts were characterized using FTIR, XRD analysis, N2 gas sorption analysis, SEM-EDX, and TEM. Catalyst Ni/MS1, Ni/MS5, Ni/MS10, and Ni/SBA-15 have specific surface areas of 130.5, 195.9, 203.9, and 381.2 m2/g and the average pores of 12.30, 9.80, 11.12, and 8.70 nm, respectively. The hydrocracking was run four times to evaluate the catalyst reusability. The hydrocracking WCO has 95.8, 82.4, and 85.2%, respectively. While Liquid fractions produced were 38.8, 43.2, and 50.2 wt.%, each of which contains gasoline of 37.09, 39.76, and 44.27 wt.%, Ni/MS10 has the highest liquid products of 50.2 wt.% and was selective to gasoline fractions up to 44.27%. Therefore, the catalyst synthesized from Parangtritis beach sand is selective for gasoline-fraction hydrocarbon and has hydrocracking activity up to 4 runnings.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...