Indonesian Journal of Chemical Analysis (IJCA)
Vol. 6 No. 1 (2023): Indonesian Journal of Chemical Analysis

Synthesis of Ni doped-TiO2 Thin Film Photocatalysts on Glass Surfaces

Margareta Caroline Harunrasjid (Chemistry Department, Universitas Tanjangpura)
Anthoni Batahan Aritonang (Chemistry Department, Universitas Tanjangpura)
M. Agus Wibowo (Chemistry Department, Universitas Tanjangpura)
Puji Ardiningsih (Chemistry Department, Universitas Tanjangpura)
Adhitiyawarman Adhitiyawarman (Chemistry Department, Universitas Tanjangpura)



Article Info

Publish Date
16 Mar 2023

Abstract

Thin film of TiO2 modified Ni2+ cationic (Ni doped-TiO2) thin films were synthesized from titanium tetraisopropoxide (TTIP) and Ni(NO3)2.6H2O using the combined sol-gel and dip coating method followed by calcination at 500oC for an hour. This study aims to determine the concentration of Ni2+ and the optimum number of layers for application as self-cleaning. Frontier transform infrared (FTIR) spectrophotometric analysis observed a shift in the vibration absorption peak of Ti-O towards a smaller wave number as an indication that the Ni2+ cationic have incorporated in the TiO2matrix in forming Ni-TiO2. Based on the of x-ray diffraction (XRD) it is known that Ni-TiO2 has anatase crystalline phase with a crystallite size of 149.20 nm. Diffuse reflectance ultraviolet-visible (DRSUV-Vis) spectrophotometry showed a decrease in the bandgap energy (3.2 eV to 2.22 eV). Surface morphological by scanning electron microscopy (SEM) method showed that the addition of polyethylene glycol (PEG) resulted in a more homogeneous distribution of particles than thin films without PEG. The self-cleaning activity of Ni-TiO2 was tested for surface hydrophilic properties by measuring the contact angle of water and oil droplets under visible light illumination.

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Journal Info

Abbrev

IJCA

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Environmental Science

Description

IJCA (Indonesian Journal of Chemical Analysis) is a chemistry journal published by Chemical Analysis Department, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia. IJCA publishes original research articles or review articles on aspect all of the chemistry fields especially in ...