Metalurgi
Vol 35, No 3 (2020): Metalurgi Vol. 35 No. 3 Desember2020

SYNTHESIS AND CHARACTERIZATION OF NICKEL HYDROXIDE FROM EXTRACTION SOLUTION OF SPENT CATALYST

Kevin Cleary Wanta (Department of Chemical Engineering, Faculty of Industrial Technology, Parahyangan Catholic University)
Felisha Hapsari Tanujaya (Department of Chemical Engineering, Faculty of Industrial Technology, Parahyangan Catholic University)
Federick Dwi Putra (Department of Chemical Engineering, Faculty of Industrial Technology, Parahyangan Catholic University)
Ratna Frida Susanti (Department of Chemical Engineering, Faculty of Industrial Technology, Parahyangan Catholic University)
Gelar Panji Gemilar (PT. Petrokimia Gresik)
Widi Astuti (Research Unit for Mineral Technology, Indonesian Institute of Sciences (LIPI))
Himawan Tri Bayu Murti Petrus (Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada)



Article Info

Publish Date
28 Dec 2020

Abstract

Nickel is an essential metal element and is applied in various sectors. One of the useful nickel–based derivatives products is nickel hydroxide [Ni(OH)2]. This compound is widely applied as raw material for electrodes of rechargeable batteries, capacitors, electrolyzers, and catalysts. This study focuses on the synthesis of Ni(OH)2 using the hydroxide precipitation method. A solution from the extraction process of spent catalysts was used as a precursor solution. After the precursor solution was obtained, the precipitation process was carried out at pH 10, where the operating temperature was varied at 30–60oC. NaOH, KOH, and MgO solutions were used as precipitating agents. The experimental results show that the Ni(OH)2 compounds were produced optimally at low temperatures, 30oC. It could be indicated from the lowest concentration of Ni2+ ions in the liquid phase that reached that temperature. The three precipitation agents also gave good results in the precipitation of Ni2+ ions, where almost all of the Ni2+ ions were precipitated from the liquid phase. The precipitated products were characterized using SEM, XRD, and XRF. The analysis results showed that the product was agglomerated and formless. The purity of the precipitates formed were 24.1 and 29% for the precipitating agents MgO and NaOH, respectively.

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Journal Info

Abbrev

metalurgi

Publisher

Subject

Industrial & Manufacturing Engineering Materials Science & Nanotechnology

Description

The objective of this journal is the online media for disseminating results in Research and Development and also as a media for a scientist and researcher in the field of Metallurgy and Materials. The scope if this journal related on: Advanced materials and Nanotechnology Materials and Mineral ...