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All Journal Jurnal Rekayasa Proses Jurnal Rekayasa Proses International Journal of Applied Sciences and Smart Technologies Metalurgi
Widi Astuti
Research Unit for Mineral Technology, Indonesian Institute of Sciences (LIPI)
Computer Science & IT Education Energy Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology Social Sciences

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Effect of Surfactant Type on Synthesis and Characteristics of Nanonickel Hydroxide Kevin Cleary Wanta; Stephen Lim; Ratna Frida Susanti; Gelar Panji Gemilar; Widi Astuti; Himawan Tri Bayu Murti Petrus
Jurnal Rekayasa Proses Vol 15, No 2 (2021)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.69723

Abstract

Nickel hydroxide has a vital role in various applications, especially as a support material for energy storage materials. Nickel hydroxide can be synthesized through the hydroxide precipitation method. However, the product formed by this method may be large or more than 100 nm because the agglomeration step can occur easily. This present work aims to study the effect of surfactant types in the synthesis and characterization of nickel hydroxide nanoparticle. Nickel sulfate (NiSO4) solution was used as a precursor solution, while 5M sodium hydroxide (NaOH) solution was used as a precipitation agent. The surfactants studied were alkyl benzene sulfonate (ABS), sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB), and polyvinylpyrrolidone (PVP). The nickel hydroxide synthesis process was carried out at 50 oC for 1 hour. The surfactant concentration used was at the critical micelle concentration (CMC), where the CMC for ABS, SDS, CTAB, and PVP were 0.01; 0.05; 3; and 0.5 %w/v, respectively. The synthesis of nickel hydroxide nanoparticle was carried out successfully precipitated almost 100% of Ni2+ ions. The product characterization that has been carried out shows that ABS surfactant produces the best nickel hydroxide nanoparticle product where the particle size is 3.12–4.47 nm.
Effect of Surfactant Type on Synthesis and Characteristics of Nanonickel Hydroxide Kevin Cleary Wanta; Stephen Lim; Ratna Frida Susanti; Gelar Panji Gemilar; Widi Astuti; Himawan Tri Bayu Murti Petrus
Jurnal Rekayasa Proses Vol 15, No 2 (2021)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.69723

Abstract

Nickel hydroxide has a vital role in various applications, especially as a support material for energy storage materials. Nickel hydroxide can be synthesized through the hydroxide precipitation method. However, the product formed by this method may be large or more than 100 nm because the agglomeration step can occur easily. This present work aims to study the effect of surfactant types in the synthesis and characterization of nickel hydroxide nanoparticle. Nickel sulfate (NiSO4) solution was used as a precursor solution, while 5M sodium hydroxide (NaOH) solution was used as a precipitation agent. The surfactants studied were alkyl benzene sulfonate (ABS), sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB), and polyvinylpyrrolidone (PVP). The nickel hydroxide synthesis process was carried out at 50 oC for 1 hour. The surfactant concentration used was at the critical micelle concentration (CMC), where the CMC for ABS, SDS, CTAB, and PVP were 0.01; 0.05; 3; and 0.5 %w/v, respectively. The synthesis of nickel hydroxide nanoparticle was carried out successfully precipitated almost 100% of Ni2+ ions. The product characterization that has been carried out shows that ABS surfactant produces the best nickel hydroxide nanoparticle product where the particle size is 3.12–4.47 nm.
Study of Nickel Extraction Process from Spent Catalysts with Hydrochloric Acid Solution: Effect of Temperature and Kinetics Study Ivanna Crecentia Narulita Simanungkalit; Elsha Pamida Bahri; Ratna Frida Susanti; Gelar Panji Gemilar; Widi Astuti; Himawan Tri Bayu Murti Petrus; Kevin Cleary Wanta
International Journal of Applied Sciences and Smart Technologies Volume 03, Issue 02, December 2021
Publisher : Universitas Sanata Dharma

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24071/ijasst.v3i2.3606

Abstract

As one of the hazardous and toxic solid wastes, spent catalysts need to be treated before the waste is discharged into the environment. One of the substances that need to be removed from the spent catalysts is the heavy metal ions and/or compounds contained therein. The method that can be applied is the extraction method using an acid solvent. In this study, the extraction process was carried out on spent catalysts samples from PT. Petrokimia Gresik. The focus of the study is on nickel extraction by varying the temperature in the range of 30–85 oC. A 1 M hydrochloric acid (HCl) solution was used as a solvent while the extraction process was 120 minutes. The experimental results show that the maximum nickel recovery of 14.70% can be achieved at a temperature of 85 oC. Kinetic studies were carried out using two kinetic models. The results of both models evaluation on the research data show that the lump model gives better results than the shrinking core model. The average error percentage of the lump model is smaller than the shrinking core model. It indicates that the extraction process was controlled by the diffusion step through the ash layer in the solid and chemical reactions simultaneously.
SYNTHESIS AND CHARACTERIZATION OF NICKEL HYDROXIDE FROM EXTRACTION SOLUTION OF SPENT CATALYST Kevin Cleary Wanta; Felisha Hapsari Tanujaya; Federick Dwi Putra; Ratna Frida Susanti; Gelar Panji Gemilar; Widi Astuti; Himawan Tri Bayu Murti Petrus
Metalurgi Vol 35, No 3 (2020): Metalurgi Vol. 35 No. 3 Desember2020
Publisher : National Research and Innovation Agency (BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (706.089 KB) | DOI: 10.14203/metalurgi.v35i3.572

Abstract

Nickel is an essential metal element and is applied in various sectors. One of the useful nickel–based derivatives products is nickel hydroxide [Ni(OH)2]. This compound is widely applied as raw material for electrodes of rechargeable batteries, capacitors, electrolyzers, and catalysts. This study focuses on the synthesis of Ni(OH)2 using the hydroxide precipitation method. A solution from the extraction process of spent catalysts was used as a precursor solution. After the precursor solution was obtained, the precipitation process was carried out at pH 10, where the operating temperature was varied at 30–60oC. NaOH, KOH, and MgO solutions were used as precipitating agents. The experimental results show that the Ni(OH)2 compounds were produced optimally at low temperatures, 30oC. It could be indicated from the lowest concentration of Ni2+ ions in the liquid phase that reached that temperature. The three precipitation agents also gave good results in the precipitation of Ni2+ ions, where almost all of the Ni2+ ions were precipitated from the liquid phase. The precipitated products were characterized using SEM, XRD, and XRF. The analysis results showed that the product was agglomerated and formless. The purity of the precipitates formed were 24.1 and 29% for the precipitating agents MgO and NaOH, respectively.
INCREASING OF METAL RECOVERY IN LEACHING PROCESS OF SPENT CATALYST AT LOW TEMPERATURE: THE ADDITION OF HYDROGEN PEROXIDE AND SODIUM CHLORIDE Kevin Cleary Wanta; Edward Yonathan Natapraja; Ratna Frida Susanti; Gelar Panji Gemilar; Widi Astuti; Himawan Tri Bayu Murti Petrus
Metalurgi Vol 36, No 2 (2021): Metalurgi Vol. 36 No. 2 Agustus 2021
Publisher : National Research and Innovation Agency (BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (689.602 KB) | DOI: 10.14203/metalurgi.v36i2.591

Abstract

One of the factors that affect the leaching process of a mineral source is the mineral characteristics of the raw materials. Not all mineral phases can be leached directly and completely. Thus, some minerals require special treatment so that the leaching process can take place optimally. This study will focus on studying the effect of additive compounds addition, i.e. hydrogen peroxide and sodium chloride, in the leaching process of spent catalyst using a sulfuric acid solution. The leaching process was carried out at a concentration of 1 M sulfuric acid solution for 240 minutes at room temperature. The hydrogen peroxide concentration was varied at 0–9%v/v, while the sodium chloride concentration was varied at 0–0.8 mol/L. The experimental results showed that the two additive compounds were able to increase nickel recovery significantly. The highest nickel recovery of 95.08% was achieved when hydrogen peroxide was used at 9%v/v. The nickel recovery is 3.5 times higher than without the addition of hydrogen peroxide. Meanwhile, sodium chloride concentration of 0.8 mol/L was able to provide the highest nickel recovery of 50.38% or an increase of 1.9 times compared to without the addition of sodium chloride.
Co-Authors Edward Yonathan Natapraja Elsha Pamida Bahri Federick Dwi Putra Felisha Hapsari Tanujaya Gelar Panji Gemilar Himawan Tri Bayu Murti Petrus Ivanna Crecentia Narulita Simanungkalit Kevin Cleary Wanta Ratna Frida Susanti Stephen Lim