Science and Technology Indonesia
Vol. 9 No. 2 (2024): April

Synthesis of Ion Imprinted Polymers (IIPs) Adsorbent Materials Using Fe(III) Leaching Process with Variation of Hydrochloric Acid Solvent Concentration and Heat Treatment

Royani, Idha (Unknown)
Maimunah (Unknown)
Edianta, Jaya (Unknown)
Alfikro, Ihsan (Unknown)
Fiber Monado (Unknown)
Jorena (Unknown)
Satya, Octavianus Cakra (Unknown)
Virgo, Frinsyah (Unknown)



Article Info

Publish Date
02 Apr 2024

Abstract

Fe(III)-IIPs material was prepared using a cooling-heating method with different leaching variations. The synthesis process used several chemical components, including EGDMA, MAA, and BPO as the crosslinker, functional monomer, and initiator. This study focused on the template formation process of IIPs with leaching variations, using parameters such as molarity concentration, solution mixture, and temperature to influence the amount of template formed in the polymer body. The spectra of XRD showed a widening value of FWHM as higher molarity was applied during the leaching process, with the widest one at 0.163 rad for IIPs 3 M. Fe(III) peak is located at 680-610 cm−1 or 1386-1350 cm−1 within the unleached sample, according to FTIR spectra. It also can be traced at minimum intensity in leached samples. SEM data processing showed that higher concentrations were essential in releasing Fe(III) ions from the polymer body. Meanwhile, heat treatment did not strongly impact the template formation sites of IIPs. Synthesized Fe(III)-IIPs materials had adsorption capacity, optimum time, and efficiency of 9.35 mg.g−1, 40 minutes, and 93.48%, respectively. Based on the results, Fe(III)-IIPs materials had great potential as adsorbents for removing metal pollutants from water.

Copyrights © 2024






Journal Info

Abbrev

JSTI

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Environmental Science Materials Science & Nanotechnology Physics

Description

An international Peer-review journal in the field of science and technology published by The Indonesian Science and Technology Society. Science and Technology Indonesia is a member of Crossref with DOI prefix number: 10.26554/sti. Science and Technology Indonesia publishes quarterly (January, April, ...