Sains Natural: Journal of Biology and Chemistry
Vol. 14 No. 3 (2024): Sains Natural

Detection of Pb(II) and Cr(III) Using Dy(III) Ion with Pyrazoline Derivatives Ligand

Syahputri, Yulian (Unknown)
Sutanto (Unknown)
M. Daud Mahmudin (Unknown)
Mohammad Rommy Izha Ramadhan (Unknown)



Article Info

Publish Date
09 Aug 2024

Abstract

Exposure to heavy metal ions Pb2+ and Cr3+ in Indonesia is getting more attention, especially in various industries and transportation. The sensor complex compound Dy3+ with fluorescence-based pyrazoline-derived ligands (fluorosensor) has the potential to detect heavy metal ions Pb2+ and Cr2+. This research was initiated by synthesizing the pyrazoline derivative ligand and then reacting it with Dy3+ metal ion.  The formed Dy3+ complex compounds was then characterized using spectroscopic methods. The results of scanning complex compounds using a UV-Vis spectrophotometer obtained two maximum wavelengths namely at 255 and 359 nm are indicating the presence of a transition type n→π* and π→π*. The results of fluorescence spectrophotometer analysis obtained maximum fluorescence intensity of Dy3+ complex compound was in the wavelength at 370 nm with fluorescence intensity of 4273 a.u. Fluorescence based sensor studies of the Dy complex when Pb2+ and Cr3+ metal ions were added showed changes in fluorescence intensity so that the fluorosensor type was obtained for the Dy3+ metal ion complex compound with Pb2+ and Cr3+, namely "turn-on-off" and "turn-off" respectively.

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Journal Info

Abbrev

JSN

Publisher

Subject

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Jurnal Sains Natural is a peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication with the objectives to explore the knowledge about natural sciences. This journal incorporates not only all branches of chemistry and biology, but ...