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STUDI PEMANFAATAN Mo-ZAA SEBAGAI KATALIS DAN PENGARUH VARIASI TEMPERATUR HIDROCRACKING TERHADAP PRODUK HIDROCRACKING MINYAK JARAK PAGAR Syahputri, Yulian; Mara, Adi
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Publisher : Fakultas Matematika dan ilmu pengetahuan Alam. Universitas Pakuan.

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (344.292 KB)

Abstract

Study of utilization of Natural Zeolites Active-Mo (Mo-ZAA) as a catalyst and influence of temperature variation on hydrocracking product temperature hydrocracking has done. Castor oil hydrocracking process done with a variation of the temperature of 250oC, 300oC, 350oC, 400oC, 450oC, 500oC and 550oC, flow rate of hydrogen gas 3.5 mL/minute and weighs 1.5 g catalysts. Hydrocracking castor oil products have been analyzed including the burning heat, density and viscosity by using the bom kalorimeter, picnometer and Ostwald viscometer instrument. The results of this study showed that the best value of the burning heat, density and viscosity in a row is on the 53.0003 kJ/g; 0.9698 g/mL and peace of 3.1691, each of which is operated at a temperature of 350oChydrocracking. Using the Mo-ZAA as a catalyst also plays a role in the process of hydrocracking. This can be seen from the value of the heat of combustion, the density and viscosity of castor oil hydrocracking product is better than the heat of combustion, density and viscosity prior hydrocracking. Key Words : Hydrocracking, Catalyst, Active Natural Zeolite, Castor Oil
PENGARUH VARIASI TEMPERATUR HIDROCRACKING TERHADAP INDEKS BIAS PRODUK HIDROCRACKING MINYAK JARAK PAGAR DENGAN KATALIS Mo-ZAA Syahputri, Yulian; Mara, Ady
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Publisher : Fakultas Matematika dan ilmu pengetahuan Alam. Universitas Pakuan.

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (132.862 KB)

Abstract

This research aim to determine the influence of hydrocracking temperature variation to refraction index of hydrocracking castor oil product by using Mo-active natural zeolite catalyst. Hydrocracking process of castor oil was conducted with variation of temperature 250oC, 300oC, 350oC, 400oC, 450oC, 500oC and 550oC, whereas the flow rate of hydrogen gases 3.5 mL/min and the weight of catalyst 1.5 g. The refraction index of hydrocracking product of castor oil was analysed by using refractometer instrument. The result of this research showed that the best value of refraction index was 1.4681 which operated at 300oC temperature of hydrocracking. Key words : hydrocracking, catalyst, castor oil, refraction index
Photocatalytic Degradation of Paraquat Dichloride using TiO2-Fe Nano Powder under Visible and Sunlight Irradiation Linda J Kusumawardani; Yulian Syahputri; Ani Iryani
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 6, No. 1, May 2020
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1011.355 KB) | DOI: 10.15408/jkv.v6i1.13625

Abstract

Paraquat dichloride, is an active herbicide with the chemical formula [(C6H7N2)]Cl2, and in the last decade became the most widely used agricultural pesticide in Indonesia. It has an important role in oil palm plantations but recently appeared many problems and caused environmental pollution. In this research, the photodegradation of paraquat herbicide using TiO2-Fe nanopowder was investigated. The TiO2-Fe catalyst was prepared by the sol-gel method and characterized using XRD and DRS. The characterization results showed that Fe as a dopant on TiO2 produced a small crystal size. This condition can increase the performance of photocatalysis from the area of UV to visible light. Degradation of paraquat dichloride is carried out under visible and sunlight irradiation to significantly increase photocatalytic activity. Decreasing of paraquat content was observed for every 15 minutes and measured by spectrophotometer UV-Vis. The addition of 0.5 gram of TiO2-Fe catalyst to 50 mL of sample solution increased the degradation percent by 98.4% for 75 minutes with a concentration of Fe3+ 10% (w/w). These results indicate that the presence of Fe dopants on TiO2 can increase the photocatalytic activity of nano TiO2 particles from UV light to visible light.
DESAIN DAN APLIKASI MODEL PENDUGAAN BEBAN LINGKUNGAN INDUSTRI GULA KRISTAL PUTIH MENGGUNAKAN METODA LIFE CYCLE ASSESSMENT Hermawan Hermawan; Yulian Syahputri; Adriana Sari Aryani; Sawarni Hasibuan
Seminar Nasional Informatika (SEMNASIF) Vol 1, No 1 (2020): Peran Digital Society dalam Pemulihan Pasca Pandemi
Publisher : Jurusan Teknik Informatika

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Abstract

AbstrakLife Cycle Assessment (LCA) dipergunakan untuk menilai dampak lingkungan yang secara potensial ditimbulkan dari aftifitas industri, dengan konsep dari muasal hingga musnah. Penilaian LCA sesuai dengan prinsip ISO 14040 terdiri dari penetapan ruang lingkup, pengumpulan data, penyusunan Life Cycle Inventory (LCI), perumusan Life Cycle Impact Assessment (LCIA), Interpretasi dan penyajian. Model LCA yang dirancang untuk prototype aplikasi komputer, merupakan kombinasi besaran Environmental Burden (EB) suatu substansi dengan LCIA Convert Matrix. Prototype Aplikasi LCA telah diuji coba pada salah satu industri gula kristal putih dengan menggunakan data tahun 2017, 2018, dan 2019. Output prototype aplikasi LCA menghasilkan karakterisasi dampak lingkungan yakni Energy Depletion Potential (EDP), pemanasan global (GWP), ecotoxicity aquatic (ETA), ecotoxicity terresterial (ETT), Abiotic Depletion Potential (ADP), Photochemical Oxydant Formation (POF), Acidification Potential (ACP), Human Toxicity Potential (HTP), Nutrification Potential (NTP), Ozone Depletion Potential (ODP). Kontribusi empat terbesar terhadap beban lingkungan dari pabrik gula responden berdasarkan data tahun 2019 adalah GWP 375.966,95 Ton setara CO2, disusul ACP 89.183,03 Ton setara NOx, EDP senilai 33.086,91 Ton setara bahan bakar minyak, dan NTP 14.598,66 Ton setara COD. Selain itu, perlu juga mendapat perhatian adalah HTP 11.621,83 Ton setara fenol, ETA 11,163.18 Ton setara BOD5, serta ETT 9,748.49 Ton setara abu.Kata kunci: Life Cycle Assessment (LCA), Aplikasi komputer LCA, Pabrik Gula Kristal Putih, Standar ISO 14040. 
Environmental Burden Computation in White Crystal Sugar Industry using the Life Cycle Assessment Methods Hermawan Hermawan; Yulian Syahputri; Kotim Subandi; Adriana Sari Aryani
Journal of Applied Sciences and Advanced Technology Vol 3, No 2 (2020): Journal of Applied Sciences and Advanced Technology
Publisher : Faculty of Engineering Universitas Muhammadiyah Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24853/jasat.3.2.35-44

Abstract

Life Cycle Assessment (LCA) is used to assess environmental impacts that can potentially result from an industrial activity, from cradle to grave. LCA assessment in accordance with the principles of ISO 14040 is carried out starting from the stage of determining the scope, collecting data, preparing the Life Cycle Inventory (LCI), formulating the Life Cycle Impact Assessment (LCIA), interpretation and presentation. At the LCI stage, data from a sugar factory studied is collected from the results of material balance analysis, exhaust gas analysis, liquid waste analysis, and solid waste calculations for the 2019 period. Life Cycle Impact Assessment characterizes each LCI data towards potential environmental impacts that are make it possible. Characterization was carried out by grouping the impacts on Energy Depletion Potential (EDP), global warming (GWP), Eco toxicity aquatic (ETA), terrestrial Eco toxicity (ETT), Abiotic Depletion Potential (ADP), Photochemical Oxydant Formation (POF), Acidification Potential (ACP) , Human Toxicity Potential (HTP), Nutrification Potential (NTP), Ozone Depletion Potential (ODP). The fourth largest contribution to the environmental burden of sugar factories based on 2019 data is GWP 375,966.95 tons of CO2 equivalent, followed by ACP 89,183.03 tons equivalent to NOx, EDP worth 33,086.91 tons of fuel oil equivalent, and NTP of 14,598.66 tons equivalent to COD . In addition, it also needs attention, namely HTP 11,621.83 tonnes equivalent to phenol, ETA 11,163.18 tonnes equivalent to BOD5, and ETT 9,748.49 tonnes equivalent to ash.
DEVELOPMENT OF COD (CHEMICAL OXYGEN DEMAND) ANALYSIS METHOD IN WASTE WATER USING UV-VIS SPECTROPHOTOMETER Uswatun Hasanah; Ade Heri Mulyati; Sutanto .; Diana Widiastuti; Siti Warnasih; Yulian Syahputri; Tri Panji
Journal of Science Innovare Vol 3, No 2 (2020): Journal of Science Innovare
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33751/jsi.v3i2.3007

Abstract

The COD (Chemical Oxygen Demand) analysis method based on the Indonesian National Standard (SNI) is a revision of SNI 06-6989.2-2004, Water and wastewater - Part 2: Method of testing for chemical oxygen demand (COD) with closed reflux spectrophotometrically. This SNI uses references from international standard methods, namely Standard Methods for the Examination of Water and Wastewater, 21st Edition, editor of LS Clesceri, AE Greenberg, AD Eaton, APHA, AWWA and WEF, Washington DC, 2005, Methods 5220 D (Closed Reflux, Colorimetric Methods). The purpose of this study was to validate the total method for testing chemical oxygen demand (COD) in water and wastewater with the reduction of Cr2O7 2- spectrophotometrically in the range of COD values of 100 mg / L to 900 mg / L measurements were made at a wavelength of 600 nm. and COD values less than or equal to 90 mg / L measurements were made at a wavelength of 420 nm. The results showed that the method SNI 06-6898.2- 2009  has good validation results including the r results obtained from the calibration curve equation of 0.998, a precision of 1.82%, an accuracy of 98.25% and LOD and LOQ of 12.27 mg / L and 25, 61 mg / L.
DEVELOPMENT OF COD (CHEMICAL OXYGEN DEMAND) ANALYSIS METHOD IN WASTE WATER USING SPECTRODIRECT Ade Heri Mulyati; Leny Heliawati; Sutanto .; Uswatun Hasanah; Diana Widiastuti; Siti Warnasih; Yulian Syahputri
Journal of Science Innovare Vol 3, No 2 (2020): Journal of Science Innovare
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33751/jsi.v3i2.3006

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Increased human activities will cause various problems, one of which is water pollution in water sources because it receives a pollution load that exceeds its carrying capacity. In the context of environmental conservation, the government has set quality standards for liquid waste produced by various industries and other activities in a Decree of the State Minister for the Environment. COD (Chemical Oxygen Demand) is one of the most important parameters in wastewater quality standards. This study aims to validate the COD analysis method which refers to COD Thermoreactor System (LOVIBOND brand) at Pakuan University Service Laboratory, to ensure the validity of COD analysis results at Pakuan University Service Laboratory. Spectrodirect COD analysis method provides results that meet the requirements of accuracy, precision, LOD, and LOQ which is quite good. The results of the Coefficient of Variation give good results with a value of 1.8841% indicating the accuracy of the analysis method is good. The accuracy parameter also gives good results and meets the requirements with a% recovery value of 98.70351%. Overall, it can be stated that the spectrodirect analysis method tested is an accurate, precise, simple, and economical method for determining COD levels
Utilization Of White-Meat, Red-Meat And Super Red Dragon Fruit (Hylocereus sp) Skin Waste As An Alternative Food Source Yulian Syahputri; Diana Widiastuti
Journal of Science Innovare Vol 1, No 01 (2018): Journal of Science Innovare
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (283.658 KB) | DOI: 10.33751/jsi.v1i01.679

Abstract

Dragon fruit skin, waste material (dragon fruit waste), will have a profitable sale value if it can be used as a food raw material. Dragon fruit skin waste contains relatively high dietary fiber so it can be used as a food raw material. This study aims to utilize dragon fruit skin waste for the manufacture of dragon fruit skin flour as an alternative food source. Some tests are made on white-meat dragon fruit skin, red-meat dragon fruit skin and super red dragon fruit skin. The preliminary study is the soaking of the three types of dragon fruit skin in two solutions, namely 0.1% sodium citrate and 0.1% sodium metabisulfite to prevent the browning effect on flour. Dragon fruit skin flour from the soaking with both solutions is then characterized physically, including its texture, color, flavor and rendement. The best physical characterization is followed by chemical characterization, including the contents of water, ash, protein, fat, carbohydrate, dietary fiber, minerals (Fe, Na, K, Ca and P), and also microbiological characterization of Escherichia coli, molds and Bacillus cereus. The chemical and microbiological characterization shows that the red-meat dragon fruit skin flour has better results than the white-meat and super red dragon fruit skin flour does. The red-meat dragon fruit skin flour contains 8.80% water, 0.20% ash, 2.35% fat, 7.69%, protein, 68,29% carbohydrate and 28,72% dietary fiber as well as 4.40 mg K, 8.76 mg Na , 0.65 mg Fe , 10.20 mg Ca and 32.58 mg P. Keywords: Waste, Dragon Fruit Skin, Dragon Fruit Skin Powder, Alternative Food Source
STUDIES ON PREPARATION OF Fe(III)/TiO2 BY SOL-GEL METHOD Linda J Kusumawardani; Yulian Syahputri
Journal of Science Innovare Vol 2, No 01 (2019): Journal of Science Innovare, February 2019
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (327.641 KB) | DOI: 10.33751/jsi.v2i01.1523

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In this study, Fe/TiO2 powder was synthesized by sol-gel method using mixture of Titanium Tetraisopropoxide (TTIP) as precursor and FeCl3 as iron source of 10% (w/w). The Fe/TiO2 powder was calcined at 500 °C for 1 hour. The sample of Fe/TiO2 was characterized using FTIR anad DRS measurements. FTIR analysis showed that Fe was successfully doped on TiO2 and then DRS analysis proved that the visible light was absorbed by Fe/TiO2 with its band gap energy up to 2.3 eV
STUDI PEMANFAATAN Mo-ZAA SEBAGAI KATALIS DAN PENGARUH VARIASI TEMPERATUR HIDROCRACKING TERHADAP PRODUK HIDROCRACKING MINYAK JARAK PAGAR Yulian Syahputri; Adi Mara
EKOLOGIA Vol 15, No 2 (2015): JURNAL ILMIAH ILMU DASAR DAN LINGKUNGAN HIDUP
Publisher : Universitas Pakuan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (344.292 KB) | DOI: 10.33751/ekol.v15i2.196

Abstract

Study of utilization of Natural Zeolites Active-Mo (Mo-ZAA) as a catalyst and influence of temperature variation on hydrocracking product temperature hydrocracking has done. Castor oil hydrocracking process done with a variation of the temperature of 250oC, 300oC, 350oC, 400oC, 450oC, 500oC and 550oC, flow rate of hydrogen gas 3.5 mL/minute and weighs 1.5 g catalysts. Hydrocracking castor oil products have been analyzed including the burning heat, density and viscosity by using the bom kalorimeter, picnometer and Ostwald viscometer instrument. The results of this study showed that the best value of the burning heat, density and viscosity in a row is on the 53.0003 kJ/g; 0.9698 g/mL and peace of 3.1691, each of which is operated at a temperature of 350oChydrocracking. Using the Mo-ZAA as a catalyst also plays a role in the process of hydrocracking. This can be seen from the value of the heat of combustion, the density and viscosity of castor oil hydrocracking product is better than the heat of combustion, density and viscosity prior hydrocracking.Key Words : Hydrocracking, Catalyst, Active Natural Zeolite, Castor Oil