JURNAL REKAYASA KIMIA & LINGKUNGAN
Vol 14, No 1 (2019): Jurnal Rekayasa Kimia & Lingkungan (June, 2019)

Adsorpsi Logam Berat Menggunakan Selulosa Xanthat dari Bagas Tebu

Dewi Agustina Iryani (Dept. Chemical Engineering University of Lampung)
Nisa Meutia Risthy (Unknown)
Simparmin Br. Ginting (Unknown)
Darmansyah Darmansyah (Unknown)



Article Info

Publish Date
02 Jul 2019

Abstract

The most effective way to reduce the pollution of heavy metal waste is the adsorption process using an adsorbent. Sugarcane bagasse is one of materials that has high affinity to absorb heavy metals. The adsorption capacity of sugarcane bagasse can be increased by converting it into cellulose xanthate by reaction of cellulose with carbon disulfide (CS2). Synthesis of cellulose xanthate consists of three stages, i.e isolation, alkalization, and xanthation. In this study, the preparation of cellulose xhantate was conducted by adding carbon disulfide (CS2) about 180% (w/w). The temperature of xhantation reaction was varied at 35C, 40C and 45C. The effect of temperature reaction into degree of substitution (DS), the degree of polymerization (DP) and the metal adsorption capacity of cellulose xanthate for Zn2+ and Pb2+ were determined by quantitative and qualitative analyze. Morphological characteristics of cellulose xanthate was characterized by SEM and the functional groups contained in the cellulose xanthate was characterized by FTIR. The result showed that cellulose xanthate synthesized at temperature of 35C have a highest value of DS, DP, and the adsorption capacity higher than two variations of temperature (40C and 45C). The value of DS, DP, and the adsorption capacity is 0.389, 299.27, 48.353 mg/g for Zn2+ metal and 51.763 mg/g for the metals Pb2+, respectively

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Journal Info

Abbrev

RKL

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Energy Engineering

Description

The Journal of Chemical Engineering and Environment is an open access journal that publishes papers on chemical engineering and environmental engineering. The following topics are included in these sciences: Food and biochemical engineering Catalytic reaction engineering Clean energy technology ...