Indonesian Food Science and TechnologyJournal
Vol. 8 No. 1 (2024): Volume 8. Number 1, December 2024 |IFSTJ|

Optimization of Nanobentonite-CuO Adsorption for Reducing 3-MCPDE, Free Fatty Acids, and Peroxide Values in Bulk Cooking Oil: A Study of Adsorption Efficacy and Isotherm Modeling

Permana, Edwin (Unknown)
Naswir, Muhammad (Unknown)
Hidayat, Ali Nurdin Hidayat (Unknown)
Wijaya, Dhian Eka (Unknown)
Rahayu, Martina Astri (Unknown)
Wazzan, Huda (Unknown)



Article Info

Publish Date
31 Dec 2024

Abstract

Indonesia is the largest palm oil producing country in the world. A factor that affects the quality of cooking oil is the presence of diglycerides and free fatty acids. Diglycerides in palm oil serve as precursors for the carcinogenic chemical 3-Monochloropropane-1,2-diol ester (3-MCPDE), whilst elevated concentrations of free fatty acids (ALB) might compromise oil stability. Numerous investigations indicate that the cooking oil present in the population includes the 3-MCPDE molecule at levels ranging from 8,150 to 58,140 ug/kg. The maximum permissible amount is 2 ug of 3-MCPDE per kilogram of body weight per day. The pillarization process involves the amalgamation of Cu(NO3)2 and NaOH inside an activated bentonite solution. The adsorption analysis of 3-MCPDE employing nanobentonite-CuO was performed using Gas Chromatography Mass Spectrometry (GC-MS) in accordance with the AOCE Cd 29a-2013 method, while free fatty acid and peroxide values were evaluated by a titration method that accounted for temporal variations. The peak efficacy of Nanobentonite-CuO in adsorbing the 3-MCPDE molecule was seen at 15 minutes, with an adsorption efficiency of 52.4%. Peroxide numbers achieved ideal performance at 45, 60, and 75 minutes, with an adsorption efficiency of 80%, whilst free fatty acids reached top performance at 75 minutes with an adsorption efficiency of 76.69%. The adsorption of 3-MCPDE compounds, free fatty acids, and peroxide content by Nanobentonite-CuO, as indicated by Adsorption Isotherm modeling, conforms to the Freundlich Isotherm, implying a physical adsorption mechanism.

Copyrights © 2024






Journal Info

Abbrev

ifstj

Publisher

Subject

Agriculture, Biological Sciences & Forestry

Description

The journal aims and scope contains original research results and scientific review includes research in the field of Food Science and Technology sciences clumps like food chemistry, food processing, microbiology food safety and food engineeringas well as nutrition. In addition, it also covers ...