JURNAL KIMIA SAINS DAN APLIKASI
Vol 28, No 4 (2025): Volume 28 Issue 4 Year 2025

Synthesis and Optical Properties of Carbon Quantum Dots Based on Terung Dayak (Solanum Ferox) Fruit Juice as Antioxidant and Metal Ion Sensor

Ariefin, Mokhamat (Unknown)
Pasaribu, Marvin Horale (Unknown)
Manurung, Tety Wahyuningsih (Unknown)
Hakim, Muh. Supwatul (Unknown)
Iftitah, Elvina Dhiaul (Unknown)
Suma, Joy Angel Aria (Unknown)
Cahyani, Risfiah Ruli (Unknown)



Article Info

Publish Date
31 May 2025

Abstract

Carbon dots (CDs) are a novel class of carbon-based nanomaterials with diverse applications due to their biocompatibility, optical properties, and chemical stability. This study aims to synthesize CDs from Terung Dayak (Solanum ferox) using a microwave-assisted method and evaluate their optical properties, metal ion sensing capability, and antioxidant activity. The CDs were synthesized with variations in microwave power and citric acid concentration, specifically: CD-a using 1 g citric acid at 600 W, CD-b using 2 g citric acid at 600 W, CD-c using 3 g citric acid at 600 W, and CD-d using 2 g citric acid at 800 W, and then characterized using UV-Vis and fluorescence spectroscopy. The results revealed strong UV absorption with maximum peaks at 250 nm for all CDs synthesized and 275 nm for CD-d, depending on synthesis conditions. The CDs exhibited fluorescence intensity influenced by microwave power, with the highest intensity observed for CDs synthesized at 800 W and 2 g of citric acid. The optical bandgap from UV-Vis spectra, determined via Tauc plot analysis, ranged from 4.03 eV to 4.71 eV, indicating quantum confinement effects for all CDs. Furthermore, CD-d demonstrated selective fluorescence quenching for Fe3+ ions, which quenched the fluorescence of the CD. Antioxidant activity was confirmed via 2,2-diphenyl-1-picryhydrazyl (DPPH) radical scavenging, with an IC50 value of 126 ppm for CD-d. These findings highlight the potential of Terung Dayak-derived CDs as multifunctional materials for sensing and antioxidant applications.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...