Jurnal Teknik Kimia USU
Vol. 14 No. 2 (2025): Jurnal Teknik Kimia USU

Optimasi dan Sintesis Selulosa Dialdehid Berbasis Limbah Tandan Kosong Kelapa Sawit

Sitinjak, Elvri Melliaty (Unknown)
Masmur, Indra (Unknown)
Shuwanto, Hardy (Unknown)
Dina, Sari Farah (Unknown)
Hutajulu, Poltak Evencus (Unknown)
Saragih, Gimelliya (Unknown)
Siahaan, Immanuel (Unknown)
Damanik, Fadhila Natania (Unknown)
Doloksaribu, Rahel Argana (Unknown)



Article Info

Publish Date
27 Sep 2025

Abstract

Empty Fruit Bunches of Oil Palm (EFB) represent one of the most problematic biomass wastes in Indonesia due to their massive volume, inefficient management, and underutilization of their chemical potential, leading to significant environmental, economic, and technical impacts. The degradation or processing of such large-scale waste generally requires a long period of time. This study focuses on converting the cellulose content in EFB into dialdehyde cellulose (DAC), which can be applied as a wet strength agent. The aim is to reduce EFB waste by isolating cellulose from EFB biomass and subsequently converting it into DAC, which can be utilized as a wet strength additive in paper or tissue products. The oxidation of EFB cellulose into DAC was optimized using sodium periodate (NaIO₄) as the oxidizing agent, with varying reaction times of 3, 6, and 9 hours. The synthesized DAC was qualitatively analyzed using the Fehling’s test and solubility observations, followed by functional group identification via FTIR and morphological characterization using SEM. Among the samples, DAC-6 exhibited the most optimal characteristics, with a degree of oxidation reaching 82.1% and a carbonyl content of 52.8%. FTIR analysis confirmed the presence of carbonyl functional groups in all DAC samples, indicating successful oxidation of hydroxyl groups in cellulose. DAC-6 showed the most prominent carbonyl absorption peak at a wavenumber of 1748 cm⁻¹.

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Journal Info

Abbrev

jtk

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology

Description

Jurnal Teknik Kimia USU merupakan jurnal elektronik yang mempublikasikan karya ilmiah di bidang teknik kimia yang diterbitkan oleh Departemen Teknik Kimia, Fakultas Teknik, Universitas Sumatera Utara. Jurnal ini tidak terbatas pada mahasiswa dan dosen Universitas Sumatera Utara, tetapi terbuka untuk ...