Jurnal Teknik Kimia
Vol 19, No 2 (2025)

STUDY OF KINETIC MODELING FOR SEA WATER IMPURITIES REMOVAL (SO4) USING DISODIUM PHOSPHATE (NA2HPO4) AND CALCIUM CHLORIDE (CACL2)

Pujiastuti, Caecilia (Chemical Engineering Department, Faculty of Engineering and Science, Universitas Pembangunan Nasional “Veteran” Jawa Timur)
Rohmah, Aisyah Alifatul Zahidah (Chemical Engineering Department, Faculty of Engineering and Science, Universitas Pembangunan Nasional “Veteran” Jawa Timur)
Muchammad, Raka Selaksa Charisma (Chemical Engineering Department, Faculty of Engineering and Science, Universitas Pembangunan Nasional “Veteran” Jawa Timur)
Sumada, Ketut (Chemical Engineering Department, Faculty of Engineering and Science, Universitas Pembangunan Nasional “Veteran” Jawa Timur)



Article Info

Publish Date
02 Mar 2025

Abstract

Salt is an essential mineral for human life, typically containing NaCl along with various impurities such as Mg²⁺, SO₄²⁻, and K⁺. The production of industrial-grade salt can be achieved through chemical treatments to bind these impurities. This study aims to investigate the kinetics of Sulphate (SO4) precipitation in order to lower impurities concentrations in seawater (Mg²⁺, SO₄²⁻, and K⁺), which is used as raw material for salt production, by adding chemical agents disodium phosphate (Na₂HPO₄) and calcium chloride (CaCl₂), each at a concentration of 2N. The research was conducted using continuous stirred tank technology with a stirring speed of 100 rpm and a solution pH of 9. The kinetics of impurity reduction in seawater were simulated using mathematical formulations, specifically pseudo-first-order and pseudo-second-order models. The results indicated that the process achieved the best outcomes with the addition of SO₄ solution, resulting in the highest removal value of 757.86 mg/L compared to others. Additionally, this correlated with an R² value close to 1 for the second-order kinetics, specifically 0.9871.

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Journal Info

Abbrev

tekkim

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Jurnal Teknik kimia fokus pada proses perpindahan panas dan massa, material maju, teknik reaksi kimia, pengolahan dan pengelolaan limbah, biomassa dan energi, termodinamika, biokimia, elektrokimia, perancangan dan pengendalian proses, proses pencampuran dan pemisahan. Rung lingkup (Scope) Jurnal ...