Jurnal Penelitian Pendidikan IPA (JPPIPA)
Vol 12 No 6 (2026)

Acid-Catalyzed Synthesis of Biodiesel from Calabash (Crescentia cujete) Seed Oil

Nelson Gaspersz (Universitas Pattimura)
Matheis F. J. D. P. Tanasale (Pattimura University)
Chalvin Marco Paula (Pattimura University)
Mimi Salamawati (Pattimura University)
Priska Marisa Pattiasina (Pattimura University)



Article Info

Publish Date
25 Jun 2026

Abstract

This study evaluated the acid-catalyzed production of biodiesel from Calabash (Crescentia cujete) seed oil using sulfuric and nitric acids as transesterification catalysts. Oil extracted by Soxhlet extraction yielded 35.20% and was converted into biodiesel under various reaction conditions to determine the optimum catalyst loading, reaction time, temperature, and oil-to-methanol molar ratio. Sulfuric acid exhibited superior catalytic performance, achieving the highest biodiesel yield of 91.20% at 4% catalyst loading, 65 °C, 4 h, and an oil-to-methanol molar ratio of 1:12. Under optimum conditions, nitric acid produced a lower yield of 65.85% at 3% catalyst loading, 65 °C, 6 h, and a molar ratio of 1:9. GC-MS analysis identified seven methyl esters in the sulfuric acid-derived biodiesel, predominantly methyl hexadecanoate (16.93%), methyl stearate (15.07%), and methyl 9-octadecenoate (43.64%). Biodiesel synthesized using nitric acid contained eight methyl esters, with methyl hexadecanoate (16.55%), methyl stearate (26.90%), and methyl 9-hexadecenoate (21.51%) as the major components. The corresponding burning rates were 1.96 × 10⁻³ and 2.71 × 10⁻³ cm²/s for sulfuric and nitric acid catalysts, respectively. Overall, sulfuric acid proved more effective, producing higher biodiesel yield in a shorter reaction time and demonstrating the potential of C. cujete seed oil as a non-edible biodiesel feedstock.

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Journal Info

Abbrev

jppipa

Publisher

Subject

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Education Materials Science & Nanotechnology Physics

Description

Science Educational Research Journal is international open access, published by Science Master Program of Science Education Graduate Program University of Mataram, contains scientific articles both in the form of research results and literature review that includes science, technology and teaching ...