Indonesian Journal of Chemistry
Vol 18, No 1 (2018)

Synthesis and Kinetic Study of the Urea Controlled Release Composite Material: Sodium Lignosulfonate from Isolation of Wood Sawdust-Sodium Alginate-Tapioca

Arif Cahyo Imawan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Yehezkiel Steven Kurniawan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Muhammad Fernadi Lukman (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Jumina Jumina (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Triyono Triyono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Dwi Siswanta (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
28 Feb 2018

Abstract

A synthesis and kinetic study of the urea controlled-release composite material based on isolated Na-lignosulfonate, Na-alginate and tapioca was carried out. This experiment’s aims were to isolate Na-lignosulfonate from wood sawdust and to applicate this isolated Na-lignosulfonate, along with tapioca and Na-alginate as urea control release composite material. A kinetic study of urea released from the composite materials was also conducted. Na-lignosulfonate was isolated by Kraft lignin method to give a brown solid yield of 16.92% and was characterized by FT-IR spectrophotometer and SEM-EDX. The composite materials were synthesized by blending urea as the active compound with composite material as the carrier compound. Three types of material were prepared: complete material (A), low-concentration Na-lignosulfonate material (B) and material without tapioca (C). The composite material had a spherical form with 0.79 mm radius and 2.16 mm swollen radius. Urea content inside material was 40.425 mg urea/g material. The urea diffusivity coefficient for material A, B, and C were 7.27 x 10–6; 15.50 x 10–6 and 0.94 x 10–6 m2 h–1, respectively. Modelling analysis showed the experiment obeyed around only 15% of the Korsmeyer–Peppas model, but there was good correlation (80%) with the unsteady-state diffusion model.

Copyrights © 2018






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...