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Jurnal Akademika Kimia
Published by Universitas Tadulako
ISSN : 24775185     EISSN : 23026030     DOI : -
Core Subject : Science, Education,
Jurnal Akademika Kimia merupakan jurnal elektronik open access yang bertujuan untuk mempublikasi hasil-hasil penelitian terbaru dalam area pendidikan akademik khususnya pada bidang pendidikan kimia meliputi asesment pembelajaran, model pembelajaran dan pengembangan perangkat pembelajaran, serta kimia murni termasuk kimia organik, kimia anorganik, kimia analitik, kimia fisik, biokimia dan bidang kimia lainnya seperti kimia lingkungan.
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Articles 12 Documents
Search results for , issue "Vol 6, No 2 (2017)" : 12 Documents clear
Uji Aktivitas Antioksidan Ekstrak Daun dan Kulit Labu Air (Lagenaria siceraria (Molina) Standl.) Masrifah, Masrifah; Rahman, Nurdin; Abram, Paulus H.
Jurnal Akademika Kimia Vol 6, No 2 (2017)
Publisher : Universitas Tadulako

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Abstract

The aim of the study was to determine the inhibitory concentration (IC50) of free radicals on an extract of calabash’s leaves and skins. The sample used in this study was the extract of calabash’s leaves and skins that made of 100 mg/L concentration. Determination inhibitory concentration of free radicals after adding DPPH (2,2-diphenyl-1-picrylhydrazyl) on the samples was determined using UV-Vis spectrophotometry. Concentration variations in leaves and skins extract of calabash used was 5, 10, 15 and 20 mg/L. The positive control used a vitamin C solution with a concentration that identical to the concentration of sample 5, 10, 15 and 20 mg/L. In the other hand, the negative control used a DPPH solution that was dissolved in ethanol p.a. The results showed that the leaves and skins extract of calabash with control of vitamin C have a concentration inhibition of free radicals (IC50) respectively was 9.268 mg/L (leaf extract), 9.332 mg/L (skin extract) and 6.839 mg/L (Vitamin C). The matter it was indicated that leaves and skins extract of calabash was a powerfully natural antioxidant.
Front Matter JAK Vol. 6 No. 2 2017 Walanda, Daud K.
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

Uji Aktivitas Antioksidan Ekstrak Air dan Ekstrak Etanol Daun Kelor (Moringa Oleifera LAM) Rizkayanti, Rizkayanti; Diah, Anang Wahid M.; Jura, Minarni Rama
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

Moringa (moringa oleifera Lam) leaves contains many molecules as inhibitors for free radicals such as phenolic compounds (phenolic acids, flavonoids, quinones, coumarins, lignans, stilbenes, tannins), nitrogen compounds (alkaloids, amines, betalain), vitamins, terpenoids (including carotenoids), and several other endogenous metabolites as antioxidants. This study aimed to determine the antioxidant potency of water and ethanol extracts of moringa (moringa oleifera Lam) leave obtained by maceration and dekok. The concentration of free radical 1,1-diphenyl-2-picrylhydrazyl (DPPH) was analyzed using UV-Vis spectrophotometer after addition of various concentrations of Moringa leaves extracts. Various concentrations of moringa leave extracts used were 20 ppm, 40 ppm, 60 ppm and 80 ppm. Vitamin C solutions as the positive control were prepared on similar various concentrations. The negative control was prepared using DPPH solutions dissolved in absolute ethanol. The results indicated that the ethanol extract of moringa leaves prepared by maceration method showed the antioxidant potency with an IC50 value of 22.1818 ppm, but the IC50 value of water extract of moringa leaves prepared by dekok was 57.5439 ppm. While, the IC50 value of Vitamin C was 8.8084 ppm. Based on the IC50 data it can be concluded that Vitamin C is a stronger antioxidant than moringa leaves extracts.
Analisis Unsur Hara Pupuk Organik Cair dari Limbah Ikan Mujair (Oreochromis mosambicus) Danau Lindu dengan Variasi Volume Mikroorganisme Lokal (MOL) Bonggol Pisang Lepongbulan, Winda; Tiwow, Vanny M. A.; Diah, Anang Wahid M.
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

The Lake Lindu is one of the potential water resources in Central Sulawesi with various species of fish and one of the most commonly found fish are species mujair fish. Mujair fish processing wastes such as offal can be polluted the environment if not managed properly. The study aim is to determine the contents of NPK nutrients in the liquid organic fertilizer by adding MOL banana weevil. The contents of nitrogen (N), phosphorus (P), and potassium (K) was determined by using spectro direct. The NPK contents in the liquid organic fertilizer of mujair fish waste from Lake Lindu reached the maximum NPK contents of nitrogen (N) of 0.311% by addition 100 mL MOL banana weevil, phosphorus (P) 0.167% by addition 150 mL of MOL banana weevil, and potassium (K) of 0.037% by addition 150 mL MOL banana weevil.
Pengaruh Alumina Terhadap Membran Blend Kitosan-Polivinil Alkohol- LitiumSebagai Membran Elektrolit Baterai Mesakh, Eka Putra; Napitupulu, Mery; Gonggo, Siang Tandi
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

The research aim was to study the effect of adding % weight alumina on the conductivity of polymer electrolyte chitosan-PVA-lithium. The characterization of functional groups was determined using fourier transform infrared spectrometry (FTIR). The Ionic conductivity of polymer electrolyte chitosan-PVA-lithium-alumina was measured by using impedance spectroscopy. The measurement results show the polymer electrolyte with the addition of 5% alumina provides the highest ionic conductivity of 3.991 x 10-3S/cm. Battery characteristics of electrolyte polymer of chitosan-PVA-lithium with the addition of alumina have a voltage of 1.4 Volts compared to commercial batteries which have a voltage of 1.5 Volts. These results indicate that alumina can be used as a filler to increase the ionic conductivity.
Arang Eceng Gondok (Eichornia crassipes) sebagai Adsorben Fenol pada Limbah PLTU Palu Tudjuka, Mora Delfita; Walanda, Daud K.; Hamzah, Baharuddin
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

This study aims to determine the optimum capacity and weight of water hyacinth aroma to the adsorption capacity of phenol in Palu PLTU waste. The steps taken in this research are a sampling of PLTU waste, making of adsorbent, determination of phenol concentration in PLTU waste and determination of phenol concentration at equilibrium using a Spektrodirect spectrophotometer. The adsorption capacity of water hyacinth at optimum condition of phenol was determined by weight variations of 10, 20, 30, 40 and 50 mg. The resulting result after adsorption process for adsorption weight at the weight of charcoal 10 mg = 82.78%, 20 mg = 89.13%, 30 mg = 85.49%, 40 mg = 79.72% and 50 mg = 74, 42 %. The optimum weight of charcoal in phenol absorb is 20 mg with% phenol which is absorbed 89.13%. The capacity of adsorbent hailing of water hyacinth scent at optimum condition of 3.03 mg phenol/g of adsorbent.
Pengaruh Lama Waktu Fermentasi Terhadap Kadar Bioetanol dari Pati Ubi Jalar Kuning (Ipomea batata L) Moede, Fika Herlina; Gonggo, Siang Tandi; Ratman, Ratman
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

The sweet potato is yellow is one that the carbohydrate that is high, so it can be used as one of the alternative raw materials for bioethanol. This study aims to determine the levels of ethanol sweet potato is yellow through fermentation with the use of yeast bread with a variety of time 3, 4, 5, 6, dan 7 days at room temperature. The results of the research showed glucose levels derived from the process of hydrolysis using acid HCl 21% were of 4.54% with high levels ethanol that optimum obtained through fermentation use of yeast Saccharomyces cerevisiae of 9.70% over fermentation 5 days.
Back Matter JAK Vol 6 No 2 2017 Walanda, Daud K.
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

Pengaruh Model Pembelajaran Guided Inquiry dengan Mind Map terhadap Hasil Belajar dan Motivasi Siswa pada Materi Redoks di Kelas X SMA Negeri 5 Palu Lumentut, Regina S.; Said, Irwan; Mustapa, Kasmudin
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

This study aimed to investigate the effect of guided inquiry learning model with mind map toward learning achievement and motivation of students on Reduction-Oxidation in Class X at SMA 5 Palu. This study was a quasi-experimental design with a non-randomized pretest-posttest control group design. This study was carried out by holding two groups of Class X Sciences 1 as the experimental group (n = 31) and Class X Sciences2 as the control group (n = 32). Testing of learning achievement data of students used t-test statistical analysis of two parties with the prerequisite tests: normality and homogeneity tests of written test given after learning (posttest). Results of the data analysis showed the average value (i) of the experimental class was 56.48 with a standard deviation of 11.07, and (ii) of the control class was 46.25 with a standard deviation of 11.98. Based on the hypothesis test results with t-test statistical of two parties obtained -ttable ≤ tcountt≥ + ttable (tcount = 2.43 and ttable= 1.67) with a significance level of α = 0.05 and degrees of freedom of 61, then H0 is rejected and Ha is accepted. Results of the data analysis of students motivation by using descriptive statistical analysis from the questionnaire of students motivation showed that the experimental class was currently on attitudes agree with the positive category of 82.58%, and the control class was on attitudes agree with the positive category of 83.78%.It can be concluded that there was an effect of guided inquiry learning model with mind map toward learning achievement of students, but it had no effect on the motivation of students in Class X at SMA 5 Palu on Reduction-Oxidation.
Ekstraksi Ubi Jalar Ungu (Ipomoea batatas L.) Menggunakan Variasi Pelarut Serta Pemanfaatannya Sebagai Indikator Asam-Basa Afandy, Moh. Azhar; Nuryanti, Siti; Diah, Anang Wahid M.
Jurnal Akademika Kimia Vol 6, No 2 (2017)
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Abstract

Purple sweet potato (ipomoea batatas L.) is one source of carbohydrate. Purple sweet potato contains vitamins and minerals that needed by humans such as vitamin A, vitamin C, calcium, and iron. The sweet potato with purple flesh is widely used as natural dyes which are called anthocyanins. The study aim was to determine a suitable solvent to extract the purple sweet potato. Variation of solvent used namely methanol, methanol acidified with HCl 1% and solvent fractionation (n-hexane, ethyl acetate, and methanol). The extraction phase was divided into two, for flesh and for the skin of the purple sweet potato. The extraction results were then compared with phenolphthalein indicator and a methyl orange on acid-base titration. The results showed that the methanol acidified with HCl 1% provided a more stable color changes in acid-base testing, and the testing of phosphate buffer pH 1-12. Purple sweet potato extracts can be used as an acid-base indicator because it gave similar results with comparative indicators, phenolphthalein, and methyl orange.

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