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Indonesian Journal of Chemistry

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Published by Universitas Gadjah Mada

ISSN : 14119420 EISSN : 24601578 DOI : -

Core Subject : Science, Engineering,

Chemical Engineering, Chemistry & Bioengineering Chemistry

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology and Higher Education (RISTEKDIKTI) No : 21/E/KPT/2018 (in First Rank) and indexed in Scopus since 2012. Since 2018 (Volume 18), Indonesian Journal of Chemistry publish four issues (numbers) annually (February, May, August and November).

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Articles 25 Documents

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Search results for , issue "Vol 10, No 1 (2010)" : 25 Documents clear

CONFORMATIONAL STUDIES OF LIGNANS FROM Durio oxleyanus Griff. (Bombacaceae) Rudiyansyah Rudiyansyah; Lynette K Lambert; Mary J Garson
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Searching for secondary metabolites from the wood bark of Durio oxleyanus has afforded two new lignans, namely threo-carolignan Y (1) and erythro-carolignan Y (2) together with three other known lignans erythro-carolignan X (3), boehmenan X (4) and boehmenan (5). The relative configurations of compounds 1 and 2 were established by J-based configurational analysis and 2D NOESY studies.

ISOTOPIC CHARACTERIZATION OF ORGANIC MATERIALS LEACHED FROM LEAVES IN WATER OF MUNDARING WEIR DAM Markus Heryanto Langsa
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

This study examined the organic constituents aquatically leached from leaf components of two tree species (wandoo eucalyptus and pinus radiate). In particular this study aimed to assess the stable isotope composition behaviour of dissolved organic carbon (DOC) from the residue leaves after leaching over five months. The changes in the stable carbon and nitrogen isotope compositions of the leached leaves materials were investigated using an elemental analyzer-isotope ratio mass spectrometry (EA-irMS). The stable isotope compositions were found to vary according to microbially-mediated alteration and decomposition. The average d13C content of the raw plant elements was consistent with the d13C values of terrestrial plants using a C3 photosynthetic pathway. The isotope compositions of leached materials of wandoo eucalyptus fresh leaf were continually depleted in d13C over the leaching period of three months. These variations correlated well with its DOC profile. Changes in d13C values may also relate to the differential leaching of the macromolecular precursors of the original material. Lignin, for example, has a typically low d13C and probably contributed to the decrease of d13C in residue of the plant materials.

USE OF NANOSIZED CHROMIUM DOPED TiO2 SUPPORTED ON ZEOLITE FOR METHYLENE BLUE DEGRADATION Aarti Ameta; Indu Bhati; Rakshit Ameta; Suresh C. Ameta
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

The photocatalytic degradation of methylene blue dye under visible light has been investigated using chromium modified titanium dioxide supported on zeolite (Cr-TiO2/zeolite). The photocatalyst was prepared by sol-gel method and characterized by X-ray diffraction and SEM. The rate of photodegradation of dye was monitored spectrophotometrically. The effect of pH, dye concentration, amount of photocatalyst and intensity of light on the rate of photocatalytic reaction was observed. The results showed that the use of Cr-doped TiO2 increased the rate of photocatalytic degradation of methylene blue as compared to untreated TiO2. The photocatalytic mechanism of Cr-TiO2 catalyst has been tentatively discussed.

ACTIVATED CARBON FROM DURIAN SEED BY H3PO4 ACTIVATION: PREPARATION AND PORE STRUCTURE CHARACTERIZATION Amri Ismail; Hanggara Sudrajat; Desi Jumbianti
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Activated carbons have been produced from the natural biomaterial durian (Durio zibethinus) seed, using phosphoric acid (H3PO4) as the activating agent. The effects of impregnation ratio, activation temperature, heating rate on the carbon surface area, porosity and mass yield are presented. A two step process has been used, the first step was a low temperature impregnation at 150 °C using phosphoric acid and the second step was the carbonization at high temperatures, namely, 600 and 900 °C. The most outstanding carbon with the highest surface area of 2123 m2/g was prepared using an impregnation ratio of 2, an activation temperature of 600 °C for 4 h and a heating rate of 1 °C/min.

OXIDATION KINETICS AND QUANTIFICATION METHOD OF CHOLESTEROL USING CHOLESTEROL OXIDASE ENZYME CATALYST Iip Izul Falah; Ritmaleni Ritmaleni; M. Utoro Yahya
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

In view of health, cholesterol is believed as one of many sources can raise several diseases. Hence, both of research in quantification and developing simple, rapid and accurate analysis method of cholesterol in a sample is very important. Aim of this research was to investigate cholesterol oxidation kinetics and its quantification method based on oxidation of cholesterol and formation complex compound of hexathiocyanato ferat(III), {Fe(SCN)6}-3. The kinetics analysis and quantification, involved cholesterol oxidation in 0.1 M and pH 7.0 phosphate buffer solution to produce cholest-4-en-3-one and hydrogen peroxide, in the presence of cholesterol oxidase enzyme. The formed hydrogen peroxide was used to oxidize iron(II) ion, which was reacted furthermore with thiocyanate ion to raise the red-brown complex compound. Results of the study showed that the complex was stable at 10-120 min since the reaction was started, with maximum wavelength of 530-540 nm. While the kinetics analysis gave first order oxidation reaction with a reaction rate constant, kapp = 5.22 x 10-2 min-1. Based on this kinetics data, cholesterol analysis method could be developed i.e. by oxidizing cholesterol within 1.5 h using cholesterol oxidase as a catalyst, and then reacted with Fe2+, in a solution containing thiocyanate ion. Absorbencies of solutions of the complex compound, measured at wavelength of 535 nm, were linearly proportional to their cholesterol concentrations, in the range of 50-450 ppm.

INFLUENCE OF CYANIDE ON REMOVAL OF COPPER ION FROM THE SOLUTION BY PHOTOCATALYTIC REDUCTION METHOD WITH TiO2 SUSPENSION Endang Tri Wahyuni; Mudasir Mudasir; Tania Avia Gusman
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

The removal of Cu(II) by photoreduction method using TiO2 photocatalyst in the presence of CN- is reported. Photoreduction was carried by batch technique using UV lamp with 290-350 nm of wavelength. The research results indicate that the present of CN- ion gives different effects on the photoreduction effectiveness depends on the mole ratio of both ions. The addition of CN- less than 2 moles for each mole of Cu (II) ion can improve the photoreduction, and the photoreduction sharply goes down into very low degree when the mole number of CN- is increased up to 4, and by further enlarging the mole number into 6, the photoreduction degree remains constant. Furthermore, increasing solution pH generally leads to a decrease in the photoreduction. In the solution with pH 1, the maximal photoreduction degree is reached, while increasing pH from 1 to 9 has declined the photoreduction, and the photoreduction is totally inhibited at pH higher than 9. The effect of the solution pH is related with the speciation of Cu (II), CN- and TiO2 in the solution.

SYNTHESIS OF TETRA-p-PROPENYLTETRAESTERCALIX[4]ARENE AND TETRA-p-PROPENYLTETRACARBOXYLICACIDCALIX[4]ARENE FROM p-t-BUTYLPHENOL Triana Kusumaningsih; Jumina Jumina; Dwi Siswanta; Mustofa Mustofa
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

A research has been conducted to synthesize tetra-p-propenyltetraestercalix[4]arene and tetra-p-propenyltetracarboxylicacidcalix[4] arene using p-t-butylphenol as a starting material. The synthesis was carried out in following stages, i.e (1) synthesis of p-t-butylcalix[4]arene from p-t-butylphenol, (2) debutylation of p-t-butylcalix[4]arene, (3) tetraallilation of 25,26,27,28-tetrahydroxycalix[4]arene with NaH and allilbromida in dry tetrahydrofuran, (4) Claissen rearrangement of 25,26,27,28-tetrapropenyloxycalix[4]arene, (5) esterification of tetra-p-propenyltetrahydroxycalix[4]arene, (6) hydrolisis of tetra-p-propenyltetraestercalix[4]arene. The all structures of products were observed by means of melting point, FTIR, and 1H-NMR spectrometers. Tetra-p-propenyltetraestercalix[4]arene compound was obtained as yellow liquid product in 55.08% yield. Tetra-p-propenyltetracarboxylicacidcalix[4]arene compound was obtained as white solid product with the melting point 135-137 °C at decomposed and in 70.05% yield.

SEPARATION OF Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(II) METAL IONS USING POLY(EUGENYL OXYACETIC ACID) AS AN ION CARRIER BY A LIQUID MEMBRANE TRANSPORT METHOD La Harimu; Sabirin Matsjeh; Dwi Siswanta; Sri Juari Santosa
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

Fe (III), Cr(III), Cu(II), Ni(II), Co(II), and Pb(II) metal ions had been separated using poly(eugenyl oxyacetic acid) as an ion carrier by bulk liquid membrane transport method. The effect of pH, polyeugenyl oxyacetic acid ion carrier concentration, nitric acid concentration in the stripping solution, transport time, and metal concentration were optimized. The result showed that the optimum condition for transport of metal ions was at pH 4 for ion Fe(III) and at pH 5 for Cr(III), Cu(II), Ni(II), Co(II), and Pb(II) ions. The carrier volumes were optimum with concentration of 1 x 10-3 M at 7.5 mL for Cr(III), Cu (II), Ni(II), Co(II) ions and at 8.5 mL for Fe(III) and Pb(II) ions. The concentration of HNO3 in stripping phase was optimum at 2 M for Fe(III) and Cu(II) ions, 1 M for Cr(III), Ni(II) and Co(II) ions, and 0.5 M for Pb(II) ion. The optimum transport times were 36 h for Fe(III) and Co(II) ions, and 48 h for Cr(III), Cu (II), Ni(II), and Pb(II) ions. The concentration of metal ions accurately transported were 2.5 x 10-4 M for Fe(III) and Cr(III) ions, and 1 M for Cu (II), Ni(II), Co(II), and Pb(II) ions. Compared to other metal ions the transport of Fe(III) was the highest with selectivity order of Fe(III) > Cr(III) > Pb(II) > Cu(II) > Ni(II) > Co(II). At optimum condition, Fe(III) ion was transported through the membrane at 46.46%.

SYNTHESIS AND CHARACTERIZATION OF CROSSLINKED POLYACRYLAMIDE (PAAM)-CARRAGEENAN HYDROGELS SUPERBASORBENT PREPARED BY GAMMA RADIATION Erizal Erizal
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

A series of superabsorbent hydrogels were prepared from acrylamide and carrageenan by gamma irradiation at room temperature. Carrageenan solutions with different concentration (0.5%, 1%, 1.5%, 2%) have been blended with 5% of acrylamide and irradiated at doses 20-40 kGy. The properties of the prepared hydrogel were evaluated in terms of the gel fraction and the kinetics swelling was studied. It was found that the incorporation only 2% carrageenan (kappa) with 5% acrylamide can produces an elastic hydrogel when irradiated with gamma rays up to 40 kGy. Under optimum conditions, poly(acrylamide)-carrageenan hydrogels with gel fraction ~ 60% and optimum swelling 250 g/g were prepared gamma radiolyticcally from aqueous solution containing 5% acrylamide and 2% carrageenan at the doses 20-40 kGy. The FT-IR spectra indicated that network of irradiated PAAM-carrageenan hydrogel was in the semi IPN structure. The hydrogels were also found to be sensitive to ionic strength of the medium, pH and temperature.

SEPARATION OF PENICILLIN G FROM FERMENTATION BROTH BY EMULSION LIQUID MEMBRANE TECHNIQUE Imam Santoso; Bachri Amran; Apriliana Laily Fitri
Indonesian Journal of Chemistry Vol 10, No 1 (2010)
Publisher : Universitas Gadjah Mada

The separation of penicillin G from fermentation broth can be done by emulsion liquid membrane technique. The aim of this research is to establish the optimal conditions for the extraction and separation of penicillin G using emulsion liquid membrane technique. The optimal conditions were found to be at ratio of internal phase volume to membrane phase volume of 1:1 ; time of making emulsion, 1 min ; emulsion contact rate, 300 rpm; rate of stirring of emulsion, 2000 rpm ; rest time of emulsion, 13 min; concentration of penicillin G as external phase, 375 ppm; and concentration of surfactant, 5% (v/v). pH of internal phase is 8; pH of external phase 5; ratio of emulsion phase volume to external phase volume, 1:2 and concentration of carrier 2 mM. The concentration of penicillin G and phenylacetic acid from fermentation results were 24771 mg/L and 32675 mg/L. Extraction by emulsion liquid membrane technique gave the percentage of penicillin G 53.38% and phenylacetic acid 60.41%. The percentage phenylacetic acid which is still higher (60.41%) indicated that the penicillin G could not completely be separated from phenylacetic acid by emulsion liquid membrane technique.

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