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INDONESIA
Indonesia Chimica Acta
Published by Universitas Hasanuddin
ISSN : 2085014X     EISSN : 26556049     DOI : -
Core Subject : Engineering,
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) is a peer-reviewed research journal that is devoted to the dissemination of new and original knowledge in all branches of chemistry. The result of research and development in the fields of chemistry in both experimental and theory/ computation, chemical-based technological innovations, and chemical applications in industrial fields. The journal publishes original research articles or review articles in organic chemistry, inorganic chemistry, analytical chemistry, physical chemistry, biochemistry, and environmental chemistry.
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Articles 5 Documents
Search results for , issue "Volume 17, No 1: June 2024" : 5 Documents clear
Synthesis of Smart Packaging Based on Chitosan-PVA/Binahong Extract as an Antibacterial Plastic Aras, Neny Rasnyanti M; Lestari, Mega Fia; Irwana, Adinda
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 17, No 1: June 2024
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v17i1.31419

Abstract

Chitosan-PVA composite with the addition of binahong extract is a bioplastic that is being developed aims to make eco-friendly product and contain antibacterial agents. This bioplastic is useful as packaging to maintain the freshness quality of food. The purpose of this research is to study and develop smart packaging with the addition of binahong leaf extract as an antibacterial agent. The manufacture of plastic in this study was carried out by varying the addition of binahong leaf extract ranging from 60-100%. The characteristics of the chitosan-PVA plastic were tested through FTIR, water uptake, and antibacterial tests. Chitosan-PVA plastic with the addition of 100% concentration of binahong extract had a good bacterial inhibition of 12 mm. The resulting chitosan-PVA plastic with binahong extract showed the presence of chemical bonds between the chitosan, PVA and flavonoid groups. The bioplastics produced have quite a large water uptake compared to non-biodegradable commercial packaging, reaching 491.52% with the addition of 90% binahong extract with the best antibacterial capabilities in the packaging with the addition of 100% binahong extract.
Theoretical Study of Metal Ion Impact on Geometry and Bond Vibrational Properties of Salophen Compound Manurung, Tety Wahyuningsih; Afthoni, Muhammad Hilmi; Steven , Kur Yehezkiel; Pasaribu, Marvin Horale; Ariefin, Mokhamat; Alfanaar, Rokiy
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 17, No 1: June 2024
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v17i1.31808

Abstract

Coordination compounds are compounds consisting of a metal atom as a center surrounded by ligands, which are important in applications such as catalysts and pharmacological sensors. Salophen, as one of the organic ligands, is capable of forming complexes with various metal ions. This study uses a computational chemistry approach to model the geometry, electronic properties, and bond vibrations of compound complexes between salophen and Zn(II), Cd(II), and Hg(II) metal ions using the PM6 semiempirical method. Modeling results show that the metal ion radius affects the dihedral angle of salophen, with the largest angle occurring in the complex with Hg(II) ions, while the complex with Cd(II) ions tends to be close to planar. FTIR analysis shows that the vibrational pattern is influenced by the bond length of salophen with metal ions. In addition, the HOMO-LUMO gap energy of the three complexes is also slightly different, with the Zn-salophen complex having the smallest Egap of 0.25709 eV.
Membranes with Chitosan-Chitosan/Phthalate Matrix and Montmorillonite-Carbon Nanotubes Filler for DMFC Applications Manimoy, Herianus; Botahala, Loth; Mautuka, Zakarias
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 17, No 1: June 2024
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v17i1.32613

Abstract

Composite membranes consist of matrix and filler. The matrices used are C and CP. Meanwhile, the filler used is MMT-CNT. The aim of this research is to improve the properties and performance of composite membranes by reviewing the effect of adding montmorillonite particle filler as a matrix and MM-Carbon as a filler. The membrane was made using the phase inversion method and solvent evaporation. The physical characterization carried out was FTIR, XRD, and SEM. Meanwhile, for characterization of membrane performance, namely swelling, methanol uptake, ion exchange capacity, methanol permeability, proton conductivity, and TGA. The results of this characterization showed that the optimum membrane was found at C 1.96 - CP 0.09/ MMT-CNT. In this membrane, methanol permeability was found to be 2.64x10-6 cm2/s, proton conductivity was 3.352x10-6 S/cm, selectivity was 1.2714 Ss/cm3, and membrane stability at a temperature of 290°C. So the optimum composition is C 1.96 grams, CP 0.09 grams, and MMT-CNT 0.129 grams.
Profiling of Modified Chitosan-Based Composites as Tetracycline Hydrochloride Drug Release Systems Anjartikasari, Nurul; Yuanita, Emmy; Dharmayani, Ni Komang Tri; Sudirman, Sudirman; Sudewianingsih, Ni Made; Ulfa, Maria
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 17, No 1: June 2024
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v17i1.33590

Abstract

Controlled drug release systems (DRS) are a crucial technology in the medical field, and they continue to be developed today. Chitosan is useful in manufacturing-controlled drug release systems due to its non-toxic, biodegradable, and biocompatible properties. However, it has some limitations when it comes to its physical and mechanical properties. Combining chitosan with other materials, such as bacterial cellulose (BC), graphite (Gr), ZnO, and TiO2, can improve its mechanical properties and antibacterial activity. This study aims to synthesize Chi/BC/Gr/TiO2 and Chi/BC/Gr/ZnO composites as drug release systems. When tested with TCH, an antibiotic model, the drug release kinetics of the composite followed the Hixson-Crowell and Korsmeyer-Peppas kinetics models. Additional tests for physical and mechanical properties, as well as antibacterial activity, have also been conducted. Mechanical properties in terms of tensile strength and Young’s modulus in composites with adding Gr, TiO2, and ZnO have higher values than Chi/BC alone. Compared to positive control, both TCH-loaded composites show higher inhibition against S. aureus bacteria. Based on the results of this study, composite Chi/BC/Gr/TiO2 and Chi/BC/Gr/ZnO have potential applications as DRS such as wound dressing.
Comparative Study of Synthesis and Characterisation of Complex Compounds of Co(II) and Fe(III) Metal Ions with Ligands N-Etilisopropyldithiocarbamate and Its Application as an Additive in Lubricants Dian , Ranggina; Yunus, Muhammad Arham; Afrianti S, Lamuru; Indah , Raya
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 17, No 1: June 2024
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v17i1.34606

Abstract

The aim of the synthesis and characterization of Co(II) and Fe(III) metal ions with N-Ethylisopropyldithiocarbamate ligands is to produce dithiocarbamate complex molecules that can be utilized in pharmacology, industry, agriculture, and chemistry in the future. The in situ method, which involves reacting secondary amines with carbon disulfide in ethanol solvent (dithiocarbamate ligands) and metals dissolved in ethanol solvent (metal ions), was used to synthesize complicated chemicals. Melting point, conductivity value, FT-IR, and UV-Vis analyses were used to characterize complicated compounds. The resulting Co(II)-N-Etilisopropyldithiocarbamate complex compounds are black in color and Fe(III)-N-Ethylisopropyldithiocarbamate are dark green, with a yield of 64.12% and 41.87%, respectively, with different conductivity values,≠0 (electrolyte compound). From the results of the FT-IR analysis, the presence of Co-S bonds was identified at the absorption band of 362.62 cm-1 and Fe-S at the absorption band of 354.90 cm-1. Maximum wavelength absorption UV-Vis, Co(II) (λmax = 330 nm) > Fe(III) (λmax = 310 nm). Characterization results based on the measurement of kinematic viscosity values, Fe(III)-N-ethylisopropyldithiocarbamate complex compounds are more effective as the additives in lubricants than Co(II)-N–Ethylisopropyldithiocarbamate at a temperature of 100 oC.

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