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INDONESIA
Indonesia Chimica Acta
Published by Universitas Hasanuddin
ISSN : 2085014X     EISSN : 26556049     DOI : -
Core Subject : Engineering,
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) is a peer-reviewed research journal that is devoted to the dissemination of new and original knowledge in all branches of chemistry. The result of research and development in the fields of chemistry in both experimental and theory/ computation, chemical-based technological innovations, and chemical applications in industrial fields. The journal publishes original research articles or review articles in organic chemistry, inorganic chemistry, analytical chemistry, physical chemistry, biochemistry, and environmental chemistry.
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Articles 148 Documents
UTILIZATION OF ETHYL ACETATE FRACTION KETAPANG LEAF (Terminalia catappa) AS BIOREDUCTOR IN SYNTHESIS GOLD NANOPARTICLES AND ANALYSIS ANTIBACTERIAL PROPERTIES Sarwina Hafid; Muhammad Zakir; Seniwati Dali
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 8 No 2 - December 2015
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v8i2.2470

Abstract

Gold nanoparticles was synthesized by bioreduction method using ethyl acetate fraction of ketapang leaf (Terminalia catappa). Nanoparticles formed were characterized using spectrophotometer UV-Vis, Fourier Transform Infra Red (FTIR) and X-Ray Diffraction (XRD). In the   analysis   of   spectrophotometer   UV-Vis   gold   nanoparticles   with   a   precursor   solution concentration of 0.5 mM and 1 mM each has an absorption between 533.5-540 nm and 539-587 nm. Analysis of functional groups of gold nanoparticles was analyzed by Fourier Transform Infra Red (FTIR). Crystal system of gold nanoparticles is cubic with nanoparticles size of 17.13 nm. The evaluation of test antibacterial activity was performed using several bacteria test such as Staphylococcus aureus, Escherichia coli, and Bacillus subtilis. Gold nanoparticles can not inhibit the activity of a test bacterium Staphylococcus aureus, Escherichia coli, and Bacillus subtilis so that differences in the concentration of gold nanoparticles did not affect the inhibition of bacteria.
Isolasi Dan Karakterisasi α-amilase Isolat Bakteri Amilolitik Asidofilik Dari Taman Nasional Rawa Aopa Watumaohai Sapto Raharjo; Ardiansyah Ardiansyah; Agus Chahyadi
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 1 No 1 - December 2008
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v1i1.2451

Abstract

Isolation and characterization α-amylase acidophilic amylolytic bacteria isolate from Rawa Aopa Watumohai National Park has been carried out. The aims of these studies are to know the characteristics of acidophilic amylolytic bacteria isolate, the optimum concentration of substrate and temperature α-amylase activity yielded, and specific activity in each enzyme purification steps. Activity of α-amylase was measured with DNS (Dinitrosalisilic acidI) method at λ 550 nm and the rate of protein enzyme was measured with Biuret method at λ 540 nm. The content of this research were obtained the isolate bacteria TR 1 which higher amylolytic activity is the colonies are pale-yellow with convexelevated, undulate, bacill sel, and negative Gram. The maximum activity and protein content obtained with (NH4)2SO4 extracted at 60% (w/v). The specific activity of α-amylase in crude extract was 0.038 U/mg enzyme, after extracted with (NH4)2SO4 60% (w/v) was 0.146 U/mg enzyme with purification fold 3.8, and after dialysis was 0.255 U/mg enzyme with purification fold 3.8, respectively. The optimum concentration of substrate (amylose) was 1.25% (w/v) and the optimum incubation temperature was 45oC.Keywords : Rawa Aopa Watumohai National Park, acidophilic amylolytic bacteria, α-amilase
Skrining Bioaktivitas Beberapa Bagian Jaringan Tumbuhan Paliasa(Melochia umbellata (Hout) Stapf var. Degrabrata K) Erwin Erwin; Alfian Noor; Nunuk Hariani Soekamto; Tjodi Harlim
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 2 No 1 - June 2009
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v2i1.974

Abstract

Paliasa is one of tropical plants that used as an etnobotanical traditional drug by the people of South Sulawesi. Paliasa leaves is believed and used as a drug for hypertension, diabetes mellitus, cholesterol, and hepatitis diseases. Preliminary study was done by Brine shrimp lethality test with Artemia salina to a tissue part of one of type paliasa, Melocia umbellata (Houtt.) Stapf. var. degrabrata K. The result show that the wood of this plant is the most active with LC50 value of 1,80 ppm. Keywords : Paliasa, traditional drug, M. umbellata, bioactivity.
UTILIZATION OF CACAO FRUIT PEEL (Theobroma cacao) AS A BIOSORBENT OF Ni(II) IONS METAL Malimongan M; Nursiah La Nafie; Paulina Taba
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 8 No 1 - June 2015
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v8i1.2479

Abstract

Nickel is one of the heavy metals which is very dangerous because it is carcinogenic and can cause a variety of acute and chronic diseases. Biosorption is one alternative method for the removal of heavy metals from the environment using a biomaterial called biosorbent. Biosorption of Ni(II) ion using cacao fruit peel (Theobroma cacao) with variation of contact time, pH and concentration has been investigated. The concentration of Ni(II) ion before and after adsorption was determined by Atomic Absorption Spectrophotometer (AAS). The result showed that cacao fruit peel (Theobroma cacao) was able to adsorb Ni(II) ion and the optimum biosorption occured at a contact time of 10 minutes and at a pH of 5. Langmuir and Freundlich isotherm models were used to study the adsorption isotherm. Biosorption of Ni(II) ion by cacao fruit peel (Theobroma cacao) fulfilled the Langmuir isotherm with a biosorption capacity of 0,21 mmol/g. The functional groups involved in the  biosorption of Ni(II) ion by cacao fruit peel (Theobroma cacao) are –OH and N-H.
Eksplorasi Metabolit Sekunder dari Spons di Wilayah Sulawesi Selatan dan Uji Bioaktivitasnya terhadap Artemia salina Beddu Jawahir; Nunuk Hariani Soekamto; Rosmawaty Rosmawaty
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 2 No 2 - December 2009
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v2i2.2465

Abstract

Abstract. Explorations of secunder metabolic, especially non active fraction of Clathria reinwardtii, of spons from South Sulawesi have been done. Bioactivity test against Artemia salina was carried out with Brine Shrimp Lethality Test method. Separation techniques contain of extraction, fractionation, and purification. Qualitative tests and structure elucidation on the compound obtained was based on the physical and spectroscopic data UV, IR and NMR. Two compounds which are isolated from Clathria reinwardtii are suggested as fenolic compound and steroid group i.e. β-sitosterol.Keywords : β-sitosterol, Artemia salina Leach, Clathria reinwardtii, fenolic.
Hubungan Sifat Reologis Adonan Terhadap Karakteristik Sensorik Produk Makanan Tepung Komposit Terigu-Sorgum Muhammad Zakir
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 1 No 1 - December 2008
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v1i1.2445

Abstract

Rheological characteristics of wheat-sorghum flour doughs has been investigated. The rheological properties of wheat dough were observed in the Laboratory of Quality control, PT Berdikari Sari Utama Flour Mills, Makassar. Organolepttic Test on bread made of the dough was conducted in the Laboratory of Food Processing and Chemistry, Research Institute of Cereals, Maros. Sorghum flour replaced wheat flour in the dough at substitution levels of 0, 10, 20, 30, 40 and 50%, respectively. Dough rheology was studied by extensigraph method. An interesting thing on the substitution level can be pointed out from the extensigram characteristics of the composite flour dough. Based on the R’5/E and Rm values, dough with similar baking characteristics to wheat flour dough was still obtained from composite flour until 20% substitution. The organoleptic test on the bread in terms of colour, taste, flavour and texture showed that substitution level at 20% level produced bread closely similar to wheat bread.Key words: Rheology, dough, flour composite, organoleptic, sensoric perception.
ELECTRODEPOSITION OF Cu ON THE SURFACE OF SILICA FREE RICE HUSK ACTIVATED CARBON WITH ULTRASONIC IRRADIATION Ryan Andhika; Muhammad Zakir; Maming Maming
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 8 No 2 - December 2015
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v8i2.2471

Abstract

Electrodeposition of Cu on the surface of silica free rice husk activated carbon with ultrasonic irradiation aimed to increase the value of specific capacitance was carried out. Silica free rice husk activated carbon was synthesized using H3PO4  activator and extraction of silica using KOH. The surface area of rice husk carbon was obtained before and after the extraction of silica and after activation were 57.2833 m2/g, 180.5378 m2/g and 184.6074 m2/g, respectively. XRF analysis showed that Cu depositioned on the surface of silica free rice husk activated carbon and based of CV measurements showed that electrodeposition of Cu with ultrasonic irradiation can increased the value of specific capacitance. Specific capacitance of silica free rice husk activated carbon before and after electrodeposition of Cu with ultrasonic irradiation were 657.75 nF/g and 721.08 nF/g, respectively.
Pengaruh Asam Amino Glisin dan Histidin Terhadap Nilai Koefisien Selektivitas EKT Polipirol-Glutamat Sebagai Sensor Potensiometrik Abdul Karim; Damma Salama; Nurwahyuni Ode
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 2 No 2 - December 2009
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v2i2.2461

Abstract

A research on the effect of amino acids, glycine and hystidine, on the selectivity of Coated Wire Electrode (EKT)-glutamate has been conducted. Membrane consisted of 0.1 M pyrrole; 0.1 M glutamic acid and 0.1 M HClO4. Analysis of the electrode performance was conducted by looking at the Nernstian factor, detection limit, and solution pH. The effect of amino  acids,  glycine  and hystidine,  on measurement  of glutamic  acid can be  studied  by calculating its selectivity coefficient. Results showed that the electrode gave response of the Nernstian value of 30.24 mV/decade in the concentration range of 10-8  – 10-1  M, detection limit of 2.735 x 10-8  M and pH of 3. Amino acids, glycine and hystidine did not affect the performance of EKT-glutamate with the selectivity coefficient of less than 1.Keywords: Coated Wire Electrode (EKT)-glutamate, Nernstian, selectivity
Proses Transesterifikasi Biji Minyak Jarak Dengan Bantuan Enzim Lipase Sebagai Penghasil Biodiesel Yusafir Hala; Muh. Zulkifli Jufri; Astina Tambung
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 2 No 1 - June 2009
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v2i1.975

Abstract

The investigation was carried out to prevent the scarce of fosil based fuel. In this investigation used seed of castor oil plan (Jathropha curcas L.) as natural row material to make castor oils and converted to biodiesel so that it’s friendly to the biological environment. Castor oils produced by extraction process with soxhletation methods used n-hexane solvent. The result of extraction then converted to biodiesel by transesterification process at optimum temperature 40o C with methanol and catalyzed with lipase enzyme. Free fatty acid analysis and total fat analysis was done to the result product, and then biodiesel converted value as 88.67% gotten. Some characteristics analysis of biodiesel castor oils like density, viscosity, pouring point, flaming point, and caloric value according ASTM D6751. The result of investigation showed castor oils biodiesel can be used as diesel fuel.Keywords : fuel, castor oils, biodiesel, transesterfication, and optimum temperature.
Synthesis and Characterization of Nanoporous Carbon from Sugarcanne Bagasse (Saccharum officianarum) with ZnCl2 Activator by Ultrasonic Irradiation as Electrochemical Energy Storage Material Arniati Labannia; Nasir La Hasan; Maming Maming; muhammad zakir
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 8 No 1 - June 2015
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v8i1.2480

Abstract

A study on synthesis and characterization of nanoporous carbon derived from sugarcane bagasse   (Saccharum   officianarum)   by   ultrasonik   irradiation   using   ZnCl2     activator   for electrochemical capasitor application has been investigated. Nanoporous carbon is a basic material for the electrode in the electrochemical energy storage. Nanoporous carbon has been synthesized based on three-steps procedures, i.e. carbonization in temperature of 350 0C, silica extraction, and activation using ZnCl2  with ultrasonic irradiation. Activated carbon with irradiation showed an increasing in intensity of the –OH functional group stretch at wave number of 3419,79. The results of XRF analysis showed the highest content of oxide compound in the activated carbon was ZnO as 97,06%, and result of XRD analysis showed that activated carbon has both amorphous and crystalline. The result of SEM analysis showed that the pores evolvement of irradiated activated carbon was better than un-irradiated activated carbon, with diameter of the pores 1,5 to 2 µm. The surface area of the carbon in optimum temperature of 30 oC for 60 minutes was 171, 2802 m2/g and the energy storage capacity was 0,3284 x 10-5 F/g.

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