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Science and Technology Indonesia

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Published by Universitas Sriwijaya

ISSN : 25804405 EISSN : 25804391 DOI : -

Core Subject : Science, Social, Engineering,

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Environmental Science Materials Science & Nanotechnology Physics

An international Peer-review journal in the field of science and technology published by The Indonesian Science and Technology Society. Science and Technology Indonesia is a member of Crossref with DOI prefix number: 10.26554/sti. Science and Technology Indonesia publishes quarterly (January, April, July, October). Science and Technology Indonesia is an international scholarly journal on the field of science and technology aimed to publish a high-quality scientific paper including original research papers, reviews, short communication, and technical notes. This journal welcomes the submission of articles that covers a typical subject of natural science and technology such as: > Chemistry > Biology > Physics > Marine Science > Pharmacy > Chemical Engineering > Environmental Science and Engineering > Computational Engineering > Biotechnology Journal Commencement: October 2016

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Articles 5 Documents

Search results for , issue "Vol. 2 No. 1 (2017): January" : 5 Documents clear

Preparation of polyoxometalate compound (NH4)6(β-P2W18O62)/SiO2 by sol-gel method and its characterization Osin Restinawaty Tambunan; Risfidian Mohadi
Science and Technology Indonesia Vol. 2 No. 1 (2017): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Preparation of polyoxometalate compound of (NH4)6(β-P2W18O62)nH2O supported with silica derived from the hydrolysis of tetraethyl orthosilicate by sol-gel method has been conducted. The compound was synthesized and characterized using FT-IR spectrophotometer, crystallinity using XRD analysis and the determination of acidity via quantitatively and qualitatively. Qualitative analysis was performed using ammonia and pyridine adsorption and quantitative analysis using potentiometric titration. FT-IR spectrum of (NH4)6(β-P2W18O62)nH2O appeared in wavenumber 786.96 cm-1 (W-OC-W), 918.12 cm-1 (W-Oe-W), 964.41 cm-1 (W=O), 1087.85 cm-1 (P-O), 3572.17 cm-1 (O-H), 1404.18 cm-1 (N-H) reinforced with wavenumber 1612.49 cm-1 with show vibration NH dari NH+, and to (NH4)6(β-P2W18O62)nH2O/SiO2 appears in wavenumbers 794.67 cm-1 (W-Oc-W), 918.12 cm-1 (W-Oe-W), 1049.28 cm-1 (W=O), 1087.85 cm-1 (P-O), 3564.15 cm-1 (O-H), 470.63 cm-1 (Si-O). Diffraction pattern of (NH4)6(β-P2W18O62)nH2O and (NH4)6(β-P2W18O62)nH2O/SiO2 compound show high crystanillity. The acidic properties showed (NH4)6(β-P2W18O62)nH2O/SiO2 more acidic than (NH4)6(β-P2W18O62)nH2O. Analysis of the effect of temperature on the stability of the compounds polyoxometalate (NH4)6(β-P2W18O62)nH2O/SiO2 show that the temperature of 600ºC the shift in wavenumbers of the compounds caused by vibration W=O, W-OC-W, W-Oe-W has been lost. This shows that at a temperatures of 600ºC on heating can cause changes in the structure of polyoxometalate (NH4)6(β-P2W18O62)nH2O/SiO2. Keywords : (NH4)6(β-P2W18O62).nH2O, Polyoxometalate, SiO2

Bentonite intercalated organometallic complex as adsorbent of procion red Lora Vitanesa; Radja Nardo Purba; Aldes Lesbani; Muhammad Said
Science and Technology Indonesia Vol. 2 No. 1 (2017): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Insertion of bentonite with organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)]as adsorbent of procion red with comparison weight ratio of bentonite: organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)] i.e.: (2.5:1), (1:1), (1:2) and (1:3) has been done. The results of insertion bentonite were characterized using FT-IR spectrophotometer, XRD, and XRF. Furthermore, the product of optimum insertion was used as an adsorbent of procion red. The spectrogram from FT-IR shows the process of insertion was not optimum for every weight ratio. Characterization using XRD showed the optimum insertion process ratio (1:2) and (1:3) was indicated the presence of diffraction appearing at 2θ region by a shift in the diffraction angles 5.00 and 39o from the original activated bentonite of 20.8o. Characterization using XRF analysis in the ratio (1:3) shows percentage of metal oxide Cr2O3 increase to 82.28%, so at the ratio of 1:3, the process insertion of organometallic compounds into the bentonite has stated success base on its highest percentage. The adsorption process of insertion bentonite organometallic compounds [Cr3O(OOCH)6(H2O)3 (NO3)] ratio (1: 3) shows the magnitude of the rate of adsorption (k) at 0.004 min-1, the adsorption capacity (b), the largest at a temperature of 70oC at 72.99 mol/g, the largest adsorption energy (ΔG) at a temperature of 60oC i.e. 17.05 kJ / mol, the largest enthalpy (ΔH) is 105720.8 kJ/mol, entropy (ΔS) 315 kJ/mol and pH 11 has the biggest value of procion red adsorped, i.e. 33.38 mg/L. Keywords: Bentonite, Organometallic compound [Cr3O(OOCH)6(H2O)3(NO3)].Adsorption, Procion Red

Adsorption of congo red using Mg/Al hydrotalcite Muhammad Said; Neza Rahayu Palapa
Science and Technology Indonesia Vol. 2 No. 1 (2017): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Polyoxometalate H4[α-SiW12O40].nH2O intercalated layered double hydroxide (1:1) was used as adsorbent colored-dye. Polyoxometalate H4[αSiW12O40].nH2O intercalated layered double hydroxide ratio (1:1) was applied as the adsorbent of Congo red-dye, and produce 51.38 (min-1) of the adsorption rate, for the largest of the adsorption capacity (b) 9.091 mol/g at 70°C, the largest adsorption energy 10.752 kJ/mol at 30°C. The value of the enthalpy (ΔH) and entropy (ΔS) decreased with increasing concentration of Congo red-dye. Effect adsorption of pH was show the optimal pH at 8 with the amount Congo red absorbed were 47.529 ppm. Keywords: Hydrotalcite, layered double hydroxide, polyoxometalate, intercalated, Congo red, adsorption

Preparation, characterization, and thermal stability of B2O3-SiO2 Winda Fitriana; Aldes Lesbani
Science and Technology Indonesia Vol. 2 No. 1 (2017): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Preparation of B2O3-SiO2 compound by inorganic synthesis was carried out. B2O3-SiO2 was characterized by FT-IR spectro-photometer, analysis of crystallinity by XRD, and test of acidity. B2O3-SiO2 was also tested by thermal stability with temperature range at 300-700 ⁰C. The results showed that the FT-IR spectrum of B2O3-SiO2 has some vibrations of B-O, Si-O-Si, Si-O-B stretching, and Si-O-B bending at 1442.8 cm-1, 779.2 cm-1, 925.8 cm-1, and 648.1 cm-1. The X-Ray diffraction pattern results showed that the analysis of B2O3-SiO2 has high crystallinity with two peaks diffraction identified at 26.6⁰ and 20.9⁰. The thermal stability test of B2O3-SiO2 showed that B2O3-SiO2 has high thermal stability with temperature range at 300-700 ⁰C. The results showed that the acidity analysis of B2O3-SiO2 has potential number 122.71 mV so that indicated B2O3-SiO2 was high acidity. Keywords : boric oxide, silica dioxide, boric silica, B2O3-SiO2

Thermal stability effect of H4[PVMo11O40]/SiO2 Leni Sinaga; Aldes Lesbani
Science and Technology Indonesia Vol. 2 No. 1 (2017): January
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Synthesis and characterization of supported polyoxometalate H4[PVMo11O40].nH2O with SiO2 through sol-gel method have been done. The compound H4[PVMo11O40]/SiO2 was characterized through FT-IR spectrophotometer, XRD, and SEM-EDX. The results showed that FT-IR spectrum of H4[PVMo11O40]/SiO2 has the primary vibration on wavenumber at 1064.7 cm-1 (P-O); 964.4 cm-1 (Mo=O); 864.1 cm-1 (Mo-Oe-Mo); 779.2 cm-1 (Mo-Oc-Mo); 462.9 cm-1 (Si-O); and 1087.9 cm-1 (Si-O-Si). The XRD diffraction pattern showed that H4[PVMo11O40].nH2O has the highest crystallinity. However, after it’s supported with SiO2, the properties of crystallinity has decreased due to the excess water during the support process. The result of SEM-EDX showed that H4[PVMo11O40]/SiO2 material has homogeneous distribution with particle size distribution of 1330 nm (1,33 μm). The acidity test by qualitative and quantitative methods show that H4[PVMo11O40]/SiO2 more acidic than H4[PVMo11O40].H2O. The effect temperature on the crystallinity showed that increasing calcination temperature made the crystallinity properties of H4[PVMo11O40]/SiO2 increased. Keywords : polyoxometalate, H4[PVMo11O40].nH2O, SiO2.

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