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Journal : Chemistry Indonesian Journal of Chemical Research

The Effectiveness of Magnetite Modified Gallic Acid Synthesized by Sonochemical Method As AuCl4- Adsorbent-Reductor Rahmayanti, Maya; Santosa, Sri Juari; Sutarno, Sutarno; Paweni, Astuti
Indonesian Journal of Chemical Research Vol 8 No 3 (2021): Edition for January 2021
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2021.8-may

Abstract

In recent years gallic acid has been developed as an AuCl4- adsorbent-reducing agent. In this research, gallic acid was modified with magnetite by sonochemical method (GA-Fe3O4), and its effectiveness as an AuCl4- adsorbent was studied. GA-Fe3O4 was synthesized through one-stage (GA-Fe3O4-SK1) and two-stage (GA-Fe3O4-SK2) methods. The effectiveness of GA-Fe3O4 was studied through optimization studies on pH, time, kinetics, and isotherm adsorption of AuCl4-. The adsorption method used was the batch method in the pH range 2-7. While the kinetics model used was the Lagergren and Ho kinetics model. The adsorption isotherm model used was the Freundlich and Langmuir isotherm model. The results showed that the optimum pH conditions for adsorption of AuCl4- on GA-Fe3O4 occurred at pH 3. Adsorption of AuCl4- on GA-Fe3O4-SK1 and GA-Fe3O4-SK2 both followed the Ho kinetic model, while the adsorption isotherm followed the Freundlich isotherm model with values KF were 0.041 and 0.034 mol/g respectively.
The Interaction Mechanism of Papaya Seeds (Carica papaya L.) as a Natural Coagulant and Remazol Red Under Different pH Conditions Dewi, Vina Melinda Inka; Rahmayanti, Maya
Indonesian Journal of Chemical Research Vol 10 No 1 (2022): Edition for May 2022
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2022.10-vin

Abstract

Batik wastewater contains a high concentration of dye that comes from the batik dyeing process. In this study, papaya seeds were applied as a natural coagulant to reduce the concentration of remazol red in batik wastewater. Dried papaya seeds were characterized using Fourier Transform Infrared Spectroscopy (FTIR). The coagulation method used the batch method in the pH range of 1-6. The FTIR spectra showed that the papaya seeds contained compounds with -NH2 and -COOH functional groups. The results of coagulation showed that the pH of batik wastewater had an effect on the ability of papaya seeds to reduce the concentration of remazol red. The optimum pH condition was obtained at pH 2 with a decrease in the concentration of remazol red by 96.1%. The interaction that occurs between the coagulant of papaya seeds and the remazol red of batik wastewater is through electrostatic interactions.