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All Journal Makara Journal of Technology
Hinode, Hirofumi
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Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Electrical & Electronics Engineering Engineering Materials Science & Nanotechnology Mechanical Engineering

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Sorption and Ion Exchange Behaviour of Natural Zeolite Packing Purnomo, Chandra Wahyu; Lenora, Bernice; Budhijanto, Wiratni; Hinode, Hirofumi
Makara Journal of Technology Vol. 21, No. 1
Publisher : UI Scholars Hub

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Abstract

It is well known that zeolite is an efficient metal ions adsorbent. The excess charge of the zeolite building blocks i.e. (AlO4)-5 and (SiO4)-4 creating a negative surface charge that attract metal cations. Beside the surface charge, zeolite also has three dimensional pore structure and reasonably large surface area which also can be used as adsorption sites. Ease of cation uptake make it suitable for many process with adsorption and desorption application. This study was conducted to observe the sorption and ion exchange behaviour of zeolite-betonite rings toward iron and cobalt cations. The results shows that the adsorption patterns follow Langmuir isotherm with the highest uptake capacity is 59,9 mg/g for Fe(II) and 57. 8 mg/g for Co(II).
Ethanol Purification Using Activated Natural Zeolite Purnomo, Chandra Wahyu; Putri, Nelliza; Perdana, Indra; Hinode, Hirofumi
Makara Journal of Technology Vol. 21, No. 2
Publisher : UI Scholars Hub

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Bio ethanol is one of the potential fuels in the future. However, ethanol in water mixture has an azeotropic concentration of 95.6 wt. %, which makes it difficult to purify further. The common method of purification is by using an azeotropic distillation column, which requires an intensive energy and an addition of specific solvent. In this study, ethanol purification is done using an adsorption column packed with zeolite Raschig rings. The natural zeolite ring was modified beforehand using the NaOH solution to enhance the material’s water adsorption performance. The ethanol purity can reach more than 99% with the modified zeolite packing. The modification also increases the saturation time of the packed bed column, thus making it more efficient.
Co-Authors Chandra Wahyu Purnomo Indra Perdana Lenora, Bernice Putri, Nelliza Wiratni Budhijanto