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Sintesis dan Karakterisasi Grafena dengan Metode Reduksi Grafit Oksida Menggunakan Pereduksi Zn Yudha Taufantri; Irdhawati Irdhawati; Ida Ayu Raka Astiti Asih
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 2, No. 1, Mei 2016
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (573.348 KB) | DOI: 10.15408/jkv.v2i1.2233

Abstract

Graphene is a thin material, has a hexagonal two-dimentional lattice and is considered as an interesting material for adsorption process. Nowadays, graphene has been known as a potential material for diverse application, such as adsorbent. In this study graphene was synthesized from graphite. Furthermore, graphene was applied for adsorption of dichloro diphenyl trichloroethane (DDT). Graphene was synthesized by Hummer’s method using hydrothermal and reduced by Zn. The samples were characterized by Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD) methods. The results of the XRD showed graphene structure in the 2θ, appeared at 23.9369 with interlayer spacing was about 3.71763 Å, compared with graphite oxide structure in the 2θ appeared at 11.2055 with interlayer spacing was about 7.89649 Å. The results of SEM analysis showed graphene has one layer with planar hexagonal structure and seems transparent whose single layer and multi layers. The graphene adsorption was analyzed by using the UV-Visible spectrophotometer. The results indicated the surface area of graphene was shown as 46.8563 m2/g. The amount of DDT adsorbed by graphene during 15 minutes was 7.5859 mg/g. This adsorption mechanism of DDT and graphene might be due to π-π and hydrogen interactions.   Keywords: Adsorption, dichloro diphenyl trichloroethane (DDT), graphena. DOI: http://dx.doi.org/10.15408/jkv.v2i1.2233
Investigation of Polymer Flood Performance in Light Oil Reservoir: Laboratory Case Study Dadan DSM Saputra; Bayu D Prasetiyo; Hestuti Eni; Yudha Taufantri; Ghifahri Damara; Yusuf D Rendragraha
Scientific Contributions Oil and Gas Vol. 45 No. 2 (2022): SCOG
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The use of polymer solutions in the application of chemical EOR injection technology has a role in increasing oil recovery efforts by improving oil mobility in porous media. The addition of the polymer solution is expected to increase the viscosity value of the displacement fluid so that it can form a “piston-like” effect to increase the volumetric sweep efficiency of the light oil reservoir. The polymer used in this study was HPAM using 3 concentrations, namely 500 ppm, 1000 ppm, and 1500 ppm conducted at a temperature of 70 °C. The rheology test of the polymer included concentration vs temperature and shear rate vs viscosity. Thermal stability testing of polymer for 7, 14, 30, 60, and 90 days at 70 °C was done to determine the stability of the polymer solution. Filtration testing was conducted with the criteria of FR <1.2. The static adsorption test has been done with the standard limit of adsorption value <400 µg / gr. Polymer injectivity test using 3 variations of injection rates and coreflooding test were conducted to determine the reduction of Sor in reservoirs due to polymer displacement. From the polymer testing stage, it was found that HPAM polymers at 3 concentrations were compatible with the injection. This is indicated with the clear solution for 3 concentrations at room temperature and 70 °C. The rheology test results showed that the polymer solution with 3 concentrations was decreased in viscosity with the addition of the shear rate value. In the thermal stability test, the viscosity value of the HPAM with 500 ppm was relatively constant. The value of the FR for HPAM 500 ppm is 1.1, HPAM 1000 ppm is 1.07 and HPAM 1500 ppm is 1.03. The results of the static adsorption test showed the lowest HPAM value of 500 ppm was 156 µg/gr. In the injectivity test results, the resistance residual factor (RRF) values at injection rates of 0.3, 0.6, and 1 cc/min were 0.8, 1.04, and 1.12. The RRF value was close to 1, indicating that after injection of 500 ppm of HPAM tended to not experience plugging. Polymer flooding shows the oil recovery factor (RF) of water injection is 39% OOIP, and RF after polymer injection with 0.35 PV with flush water is 13.5% OOIP or 22% Sor. Knowing the behavior of HPAM polymer with various concentrations to be used for chemical EOR injection, it could provide advantages for future implementation in the light oil reservoir in Indonesia.