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PRETREATMENT TRAMETES VERSICOLOR DAN PLEUROTUS OSTREATUS PADA BAGAS UNTUK PRODUKSI BIOETANOL Anita, Sita Heris; Fajriutami, Triyani; Fitria, -; Ermawar, Riksfardini Annisa; Yuli Yanto, Dede Heri; Hermiati, Euis
Teknologi Indonesia Vol 34 (2011)
Publisher : LIPI Press

Single and mix cultures of white-rot fungi Trametes versicolor and Pleurotus ostreatus has been applied onto sugarcane bagasse as a pretreatment process. The purpose of this research was to investigate the effect of single and mix cultures of white-rot fungi in lignin degradation while maintaining minimum loss of ?-cellulose of sugarcane bagasse. Single and mix cultures of white-rot fungi T. versicolor and P. ostreatus have been inoculated onto sugarcane bagasse which varied in 5%, 10%, and 15% (w/v) with inoculum comparison 1:1. After 4-week incubation, analysis was carried out on the content of extractives, lignin, ?-cellulose and hemicellulose. The result showed that 4-week incubation of single culture of P. ostreatus was more advantageous as a pretreatment method for sugarcane bagasse, with considerable number of lignin degradation (17,95%) and minimum loss of cellulose (11,00%) and hemicelluloses (5,75%). As with mix cultures, incubation period should have been reduced to prevent significant loss of cellulose and hemicellulose. Furthermore, with shorter incubation period, this biological pretreatment process will be more interesting and feasible for the industry.

Optimization of Xylose Production from Sugarcane Trash by Microwave-Maleic Acid Hydrolysis Hermiati, Euis; Oktaviani, Maulida; Ermawar, Riksfardini Annisa; Laksana, Raden Permana Budi; Kholida, Lutfi Nia; Thontowi, Ahmad; Mardiana, Siti; Watanabe, Takashi
Reaktor Volume 20 No.2 June 2020
Publisher : Dept. of Chemical Engineering, Diponegoro University

Sugarcane trash contains significant amount of xylan that could be hydrolysed to xylose. The xylose could be further fermented to produce xylitol, a sugar alcohol that has low calories and does not cause carries of teeth. In this study we optimized the production of xylose from sugarcane trash by microwave-assisted maleic acid hydrolysis using response surface methodology (RSM). The factors optimized were acid concentration, time, and temperature. The xylose yield based on the weight of initial biomass was determined and it served as a response variable. Results show that acid concentration and interaction between time and temperature had significant effect on xylose yield. The quadratic regression model generated from the optimization was fit and can be used to predict the xylose yield after hydrolysis with various combinations of acid concentration, time, and temperature. The optimum condition for xylose production from sugarcane trash was using maleic acid of 1.52%, and heating at 176 Â°C for 6.8 min. At this condition the yield of xylose was 24.3% per initial biomass or 0.243 g/ g biomass.Keywords: maleic acid; microwave heating; response surface methodology; sugarcane trash, xylose

Optimizing the Synthesis of Lignin Derivatives from Acacia mangium to Improve the Enzymatic Hydrolysis of Kraft Pulp Sorghum Bagasse Fatriasari, Widya; Hamzah, Fajar Nur; Pratomo, Bagas Ikhasan; Fajriutami, Triyani; Ermawar, Riksfardini Annisa; Falah, Faizatul; Laksana, Raden Permana Budi; Ghozali, Muhammad; Iswanto, Apri Heri; Hermiati, Euis; Winarni, Ina
International Journal of Renewable Energy Development Vol 9, No 2 (2020): July 2020
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.9.2.227-235

The present study is aimed at optimizing the synthesis of Amphipilic lignin derivatives (A-LD) from the isolated lignin of A.mangium black liquor (BL), using the one and two step acid isolation method, and commercial lignin (LS) was used as comparison. The experimental design was conducted using Taguchi method, which consisted of four parameters and two level factors, with reference to the matrix orthogonal array, L8, including temperature, reaction time, amount of polyethylene glycol diglycidylethers (PEGDE) and Kraft lignin (KL). Furthermore, the kraft pulp of sweet sorghum bagasse (SSB) was used as substrate in the enzymatic hydrolysis (NREL method), with addition of A-LD, whose functional group and surface tension were then characterised using ATR-FTIR and surface tension equipment. Conversely, an improvement in the reducing sugar yield (RSY) compared to the control was observed after adding various A-LDs to the substrate during enzymatic hydrolysis. This product was more prospective for L2S than others products under milder circumstances, due to the fact that it possesses the lowest surface tension. Also, Taguchi analysis demonstrated the treatment at 60 Â°C for 1 h with 3.0 g and 1.0 g of PEDGE and lignin, respectively as the optimum condition, while the amount of lignin present was included as a factor with the propensity to significantly affect A-LD L1S and LS. Therefore, it was established that the A-LDs from A. mangium kraft lignin require milder synthesis conditions, compared to other existing methods and despite the differences in optimum experimental condition for L2S and LS, the functional groups in the IR spectra possessed very identical characteristics.Â

This research was conducted to study the effects of pretreatment with white-rot fungi on pulp properties of betung bamboo. Inoculum stocks of white-rot fungi (25 ml) were injected into polybag contained barkless fresh bamboo chips of 1.6 cm in width. Each polybag contained 221.21-230.43 g oven dry weight of chips. Bamboo chips in the polybags were inoculated by P. ostreatus and T. versicolor. Both of them were then incubated for 30 and 45 days in an incubator. Bamboo chips were cooked in open ho Widya FATRIASARI; Riksfardini Annisa ERMAWAR; Faizatul FALAH; Dede Heri Yuli YANTO; Euis HERMIATI
Jurnal Ilmu dan Teknologi Hasil Hutan Vol. 2 No. 2 (2009): Jurnal Ilmu Teknologi Hasil Hutan
Publisher : Departemen Hasil Hutan, IPB

Show Abstract | Download Original | Original Source | Check in Google Scholar

This research was conducted to study the effects of pretreatment with white-rot fungi on pulp properties of betung bamboo. Inoculum stocks of white-rot fungi (25 ml) were injected into polybag contained barkless fresh bamboo chips of 1.6 cm in width. Each polybag contained 221.21-230.43 g oven dry weight of chips. Bamboo chips in the polybags were inoculated by P. ostreatus and T. versicolor. Both of them were then incubated for 30 and 45 days in an incubator. Bamboo chips were cooked in open hot soda process. The cooked bamboo chips were then fibrillated using beater hollander and stone refiner. Yield, kappa numbers (TAPPI 236 cm-85) and freeness (CSF) of the pulp were then analyzed. Pulp yield pretreated with P.ostreatus and incubated for 30 days was the highest (increased by control 22.31%), while that pretreated with T.versicolor was the lowest (decreased by control 22.20%). The increasing of incubation time had positive correlation with the reduction of kappa number. Statistic test (ANOVA) at 95% level of confidence show that fungi give significant effect on kappa number, freeness, and kappa number degradation. Besides that fungi, the interaction between fungi and incubation times give significant effect on the yield changes and pulp yield. T. versicolor had better activity in 45 days of incubation. Pulp freeness resulted from this study were still lower than the desired value. Pretreatment of betung bamboo using T. versicolor with 45 days of incubation was considered better than the other treatments. Keywords : Betung bamboo, biopulping, pulp yield, kappa number, degree of freeness

Synthesis of cellulose acetate (CA) from algae Gracilaria sp. composited with nickel oxide (NiO) as a supercapacitor base material Risdianto, I Wayan; Ahmad, Ahyar; Ermawar, Riksfardini Annisa
Communications in Science and Technology Vol 8 No 1 (2023)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.8.1.2023.1176

In this research, electrodes were made from cellulose acetate (CA) synthesized from algae Gracilaria sp. and then composited with nickel oxide (NiO), the concentration of which varied from 0, 0.2, 0.4, and 0.6 grams. Furthermore, FT-IR characterized cellulose acetate, and the CA-NiOn electrode was characterized by XRD, SEM, and cyclic voltammetry (CV). The results showed that CA was successfully synthesized from Gracilaria sp. Increasing the concentration of NiO added to CA as an electrode could increase the specific capacity, energy density, and power density of the electrode with the highest degree of 83.27 F/g, energy density of 4 Wh/kg, and a power density of 0.4 W/kg at a concentration of 0.6 gram NiO. The effect of the addition of NiO on the characteristics of the CA-NiOn electrode was also studied such as crystallinity, crystal size, and porosity. The presentation of CA doped with NiO has the promising prospects as a supercapacitor base material.

The Utilization of Gracilaria sp. as Raw Material for Cellulose in Cellulose Acetate-Nickel Oxide (CA-NiO) as Electrode for Energy Storage Technology Karim, Abdul; Ahmad, Ahyar; Arfah, Rugaiyah Andi; Ermawar, Riksfardini Annisa; Karim, Harningsih; Putra, Andi Erwin Eka; Putri, Suriati Eka; Negara, Satria Putra Jaya; Larekeng, Siti Halimah
Indonesian Journal of Chemistry Vol 25, No 1 (2025)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.96533

In the modern era, electrical energy has become a significant need that drives the large consumption of fossil fuels and their environmental impacts. Supercapacitors can reduce this large consumption of natural polymers such as cellulose acetate (CA), which can be synthesized from Gracilaria sp. Composites with CA can be an environmentally friendly alternative electrode with low toxicity. The results show that the cellulose has been successfully synthesized from the algae Gracilaria sp., which was proven by FTIR spectra analysis. The results also show that supercapacitor electrodes have been successfully made where the manufactured electrodes form a composite between CA and nickel oxide (NiO), with the highest specific capacitance and specific energy values of 15.5 × 102 F/g and 13.3 × 102 Wh/kg, respectively, on the CA-NiO2 electrode, but when the NiO concentration is higher than the CA concentration the specific capacitance and specific energy decrease as shown on the CA-NiO electrode with NiO mass of 0.6 g. Thus, the materials results of this study can be applied to electric vehicles and technology that requires electricity storage in the future.

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