Adiba Arief
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, University Of Hasanuddin Jl. Perintis Kemerdekaan Km. 10 Makassar 90245

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Journal : MARINA CHIMICA ACTA

DETERMINATION AND DEGRADATION PYRENE FROM PAOTERE PORT SEDIMENTS WITH OXIDIZER KMnO4 Rachma Surya Masnawan; Nursiah La Nafie; Adiba Arief
Marina Chimica Acta Vol. 18 No. 1 (2017): Volume 18, No. 1 (2017)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (256.399 KB) | DOI: 10.20956/mca.v18i1.1831

Abstract

Paotere port is one of port in Makassar which functions as a stopover place of ships, also serves as fish market and fishermen settlements. Various activities of transportation, commerce and households occurred in the Paotere port area can be a source of pollution of pyrene compounds to the surrounding environment. Pyrene compounds that accumulate and can not be degrade will impact the environment and marine life. Determination pyrene in sediment from Paotere Port have been carried out using GC-MS by sonication using dichloromethane as solvent. Result show that there was no PAH in sediment of the three sampling stations. Pyrene compound chemically degradation was conducted by sonication for 1 hour using an oxidant KMnO4 concentration of  0.05 M, 0.07 M and 0.1 M. Results show that KMnO4 as oxidizing agent could to degrade the whole pyrene with concentration of 87,8554 ng/g in sediment.
ANALYSIS OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) COMPOUNDS FROM SEDIMENT IN THE WATERS KAYU BANGKOA PORT AND DEGRADATION OF PHENANTHRENE IN SEDIMENT BY USING KMNO4 OXIDIZER Tiameisetia Sumomba; Nursiah La Nafie; Adiba Arief
Marina Chimica Acta Vol. 18 No. 1 (2017): Volume 18, No. 1 (2017)
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (274.219 KB) | DOI: 10.20956/mca.v18i1.1839

Abstract

Research about analysis of Polycyclic Aromatic Hydrocarbon (PAH) from sediments in water of Kayu Bangkoa Port and degradation of phenanthrene from sediments by using KMnO4 have been conducted by Gas Chromatography Mass Spectrophotometry (GC-MS). The samples of sediment were taken at three location in the waters of the Kayu Bangkoa Port. Measurements of phenanthrene performed by standard internal method and analyzed using GC-MS. The results show that KMnO4 oxidizing agent capable of degradated the whole phenanthrene with concentration of 137,13 ng/g in sediment