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Journal : Jurnal Natural

SINTESIS MEMBRAN POLIURETAN BERBASIS MINYAK BIJI ALPUKAT (Avocado Seed Oil) DAN HEKSAMETILEN-1,6-DIISOSIANAT (HMDI) Fitriani Fitriani; Marlina Marlina; Khairan Khairan
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (137.304 KB) | DOI: 10.24815/jn.v16i2.5126

Abstract

This research aims to synthesize polyurethane membrace from avocado seed oil as a source of hydrixyl (-OH) and hexametylhene -1.6-dissocyanate (HDMI) as a source of isocynate (-NCO). The oil were extracted from avocado seeds at temperature of  60-80oC for 2 hours using n-hexane solvent. The results of FTIR spectrum analysis from avocado seed oil showed that there were -OH clusters absorption on the wavelength number of 3393.819 cm-1, thus this oil can be used to synthesize polyurethane membrane. The isocyanate composition, time and temperature during synthesis process of polyurethane membrane were varied. The polyurethane membrane were moulded in petri dishes, then heated up for 48 hours on the temperature of  70oC, and finally taken out from its mould. The characteristics of the polyurethane membrane from avocado seed oil are brown in colour, homogenous, elastic, solid, transparent and shaped like a membrane. The measurements from FTIR spectrum showed that the -NCO clusters are no longer present. This condition happened because there were no more absorption in the wavelength number of  2270 cm-1 . It can be concluded that the isocyanate has completely reacted during polymerization and the curing process, thus urethane was created in the 1699,965 cm-1 absorption which was the urethane C=O clusters absorption.
PENGARUH KOMBINASI EKSTRAK PETROLEUM ETER BAWANG PUTIH (Allium sativum Linn) DENGAN VITAMIN C TERHADAP AKTIVITAS Candida albicans Nurul Khaira; Misrahanum Misrahanum; Rinaldi Idroes; Muhammad Bahi; Khairan Khairan
Jurnal Natural Volume 16, Number 1, March 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (170.59 KB) | DOI: 10.24815/jn.v16i1.4725

Abstract

Garlic (Allium sativum) contains organosulfur compound that plays an important role as an antibacterial and antifungal activities. Ascorbic acid or vitamine C also has been show has a good activity as an antioxidant and as an antifungal. The aims of the research is to determine the effect of the combination of petroleum ether garlic extract with vitamin C against Candida albicans. Zone of inhibition testing done by Kirby-Bauer method. The results showed that the combination of petroleum ether garlic extract with vitamin C in concentration of 50% did not show an activity significantly. Meanwhile, the activity of petroleum ether garlic extract alone at concentration of 50 and 75% showed activities towards Candida albicans with a diameter of inhibition zone are 19.46 and 27.46 mm respectively. 
PENGARUH KOMBINASI EKSTRAK PETROLEUM ETER BAWANG PUTIH (Allium sativum Linn) DENGAN VITAMIN C TERHADAP AKTIVITAS Candida albicans Nurul Khaira; Misrahanum Misrahanum; Rinaldi Idroes; Muhammad Bahi; Khairan Khairan
Jurnal Natural Volume 16, Number 1, March 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v16i1.4725

Abstract

Garlic (Allium sativum) contains organosulfur compound that plays an important role as an antibacterial and antifungal activities. Ascorbic acid or vitamine C also has been show has a good activity as an antioxidant and as an antifungal. The aims of the research is to determine the effect of the combination of petroleum ether garlic extract with vitamin C against Candida albicans. Zone of inhibition testing done by Kirby-Bauer method. The results showed that the combination of petroleum ether garlic extract with vitamin C in concentration of 50% did not show an activity significantly. Meanwhile, the activity of petroleum ether garlic extract alone at concentration of 50 and 75% showed activities towards Candida albicans with a diameter of inhibition zone are 19.46 and 27.46 mm respectively. 
SINTESIS MEMBRAN POLIURETAN BERBASIS MINYAK BIJI ALPUKAT (Avocado Seed Oil) DAN HEKSAMETILEN-1,6-DIISOSIANAT (HMDI) Fitriani Fitriani; Marlina Marlina; Khairan Khairan
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v16i2.5126

Abstract

This research aims to synthesize polyurethane membrace from avocado seed oil as a source of hydrixyl (-OH) and hexametylhene -1.6-dissocyanate (HDMI) as a source of isocynate (-NCO). The oil were extracted from avocado seeds at temperature of  60-80oC for 2 hours using n-hexane solvent. The results of FTIR spectrum analysis from avocado seed oil showed that there were -OH clusters absorption on the wavelength number of 3393.819 cm-1, thus this oil can be used to synthesize polyurethane membrane. The isocyanate composition, time and temperature during synthesis process of polyurethane membrane were varied. The polyurethane membrane were moulded in petri dishes, then heated up for 48 hours on the temperature of  70oC, and finally taken out from its mould. The characteristics of the polyurethane membrane from avocado seed oil are brown in colour, homogenous, elastic, solid, transparent and shaped like a membrane. The measurements from FTIR spectrum showed that the -NCO clusters are no longer present. This condition happened because there were no more absorption in the wavelength number of  2270 cm-1 . It can be concluded that the isocyanate has completely reacted during polymerization and the curing process, thus urethane was created in the 1699,965 cm-1 absorption which was the urethane C=O clusters absorption.