Zarlaida Fitri
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Enhancing the Solubility of Indrapuri Clay (Local “Kieserite”Fertilizer) M. Adlim; Zarlaida Fitri; . Sulastri; Ratu Fazlia Inda Rahmayani; Yuliza Laini
Proceedings of The Annual International Conference, Syiah Kuala University - Life Sciences & Engineering Chapter Vol 2, No 2 (2012): Engineering
Publisher : Syiah Kuala University

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Abstract

Study on enhancing the solubility of clay containing magnesium of localproduction (Indrapuri) has been conducted. The clay is commercially available and named as “kieserite” produced by local companies. The sample was taken randomly from fertilizer shops and analysed with AAS and XRF methods. XRF data of local kieserite showed the dominated chemical content; MgO(33.19%); SiO2(33.11%); CaO(1.90%);Al2O3 (5.77%) and Fe2O3(6.32%). The MgO content is higher than that of magnesium sulphate monohydrate (CAS No.: 14168-73-1) which is only 28%. The concentration of soluble magnesium ions of local kieserite naturally soluble was 0.0186% which is very low compared with the soluble magnesium of magnesium sulphate monohydrate (CAS No.:14168-73-1) which is 25%. The Enhancing the magnesium solubility was done by soaking the local kieseriteinto 0.1-0.5M HNO3 before neutralized with NH4OH or mixing the local kieserite with in alluvial, entisol, red-yellow-podsolik (RYP) soils with and without addition of 0.1-0.5M of (NH4)2SO4. The amount of dissolved magnesium of kieserite was found morein entisol soil than the other type of soils. The concentration increased up between 0.59-1.00% along with the incrementof (NH4)2SO4 concentration (0.1-0.5 M). Both in entisol soil and in 0.1 M of (NH4)2SO4, the dissolved magnesium ion increased up to 0.825% but decreased at higher concentration of (NH4)2SO4
Preparations of chemical sensors for simple formalin detection in contaminated food (A model for final project works for pre-service teachers in chemistry subject) M. Adlim; . Hasan; Zarlaida Fitri; Yulida Amri; Martina Sari; Saiful Mahya
Proceedings of The Annual International Conference, Syiah Kuala University - Life Sciences & Engineering Chapter Vol 1, No 2 (2011): Engineering
Publisher : Syiah Kuala University

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Teaching chemistry must include some learning skills in scientific works. The students must have experience conducting small research in chemistry to train them the scientific methods. Some chemistry projects have been carried out by the students of teaching training college (FKIP) as called pre-service teachers in chemistry subject.  The students were given research problem that is how to formulate a simple sensor for detection of formalin in contaminated food. The students were asked to review literature on the composition and analysis technique of formalin. The students wrote the research proposal and presented their proposal in front of four reviewers before they start conducting research. The project of formalin sensor preparation was started with studies of the active reagent composition in liquids phase, immobilizing the active reagent in soft media, and following with studies of the sensor sensitivity toward formalin contamination in food. The Schiff Fuchsine (SF) and NASH methods for aldehyde determination were chosen as the basic theory for formalin determination.  Schiff Fuchsine (SF) in diluted sulfuric acid solution was kept overnight before use.  The media for holding of the reagent was cotton coated with chitosan, then it was pasted in tacon foil, this sensor was called forpastrip (student project-1). It could detect formalin as low as 2% (v/v) of formalin or equivalent with 0,8% of formaldehyde in contaminated food and the expired date was 10 weeks. The forpastrips was tested on food and the chemical interference was also studied (student project-2). Another project was also carried by replacing the cotton with synthetic felt and this formula was recorded as student project-3. The SF reagent immobilized in synthetic felt coated by chitosan was inserted into narrow-plastic straws. The sensitivity of this sensor increased and the detection limit as low as 0.25% (v/v) of formalin in contaminated food and the expired date was more than 12 weeks. The forth project was replacing SF with NASH reagent immobilized in cotton coated by chitosan and inserted in narrow-plastic straws. The detection limit was 0.015% (v/v) of formalin in contaminated food. All Sensors were still effective to detect formalin in sample although the sample contained of sugar, salt, fat and protein as the impurity. The research findings were written by students in their final report (script, like a thesis) after approved by the two supervisors. They students then presented their research in comprehensive exam in front of reviewers before they were graduated. Having interviews with students, they claimed that they have experience in conducting research, have followed all scientific methods. They said the research theme is very interesting, simple, contextual and it might be applied in high schoo