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The Effect of Adding Activated Sludge and Types of Series Circuit Systems Microbial Fuel Cell (MFC) Using Chinese Food Restaurant Wastewater Danang Jaya; Tunjung Wahyu Widayati; Singgih Adi Nugroho; Firda Ellysa
Eksergi Vol 19, No 1 (2022)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v19i1.6479

Abstract

Electricity consumption expands every year. However, in Indonesia, electricity is still highly dependent on conventional energy sources such as coal. A microbial fuel cell (MFC) is one of the alternative inventions that consists of a series of tools which converts chemical energy into electrical energy in the presence of microbial metabolism. In addition to produce electrical energy, it may also help to solve environmental issues by dealing with waste. This research was purposed to investigate the potency of Chinese food restaurant waste as substrate to generate electricity in microbial fuel cell. The research was done in three stages: wastewater preparation, assembly of MFC tools in various circuits, and running MFC processes. Results showed that the best electrical average (1.02 V) was found in the treatment system without active sludge. The best circuit was in the system in 4 series, which obtained a maximum voltage of 3.76 V and the largest power density of 62.66  mW/m2. In addition, with the addition of active sludge, biological oxygen demand (BOD) of the wastewater could be lowered up to 29.27%, and chemical oxygen demand (COD) up to 51.58%. Total suspended solid (TSS) could be decreased up to 49% on the sample withoud sludge addition.
Enhancing coal tailing quality by Flotation Method using Biosurfactant from Lerak (Sapindusrarak De Candole) Danang Jaya; Tunjung Wahyu Widayati; Refina Yuni Mustika; Halim Nur Aziz Suwardi
Eksergi Vol 17, No 1 (2020)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v17i1.3298

Abstract

Wasted from coal mining that mixed with the wasted of the coal washing product called Coals Tailing (CT) has a low calorific value,high sulfur and ash content. To upgrade its quality by increasing its calorific value and to reduce environmental pollution by reducing sulfur and its ashes, coal must improve from its impurities, one of which is to try with flotation method. Flotation is a process that describes solids that occur due to differences in surface properties (surface properties). The flotation process takes place in a system consisting of three phases, namely gas phase, liquid, and solid, which are interrelated to complete the appearance (with the help of flotation agent  /  surfactant)  so  that  discussion  occurs  between  the  hydrophobic  component  (waterproof)  and  the hydrophilic component (like water). The main objective of the research is to improve the quality of coals tailing (CT), by increasing the calorific value (reducing the content of sulfur, ash, and other impurities) using the flotation method, and using lerak (Sapindus rarak De Candole) as a surfactant. From this research show that an optimal conditions were obtained, at particle size of -80 / + 100 mesh, operating conditions at pH 6, calorific value increased from initially 3230,171 cal/gr to 5035,622 cal/gr, sulfur content decreased according to   the optimum condition reached 2026.08 mg /kg, and the ash content decreased from 54.61% to 33.9%. From the results of these research indicate, Lerak as a surfactant is is enhanced to improve the quality of Tailings Coal (CT) by flotation method.
Production of biodiesel from waste cooking oil using heterogeneous catalyst Danang Jaya; Tunjung Wahyu Widayati; Hanum Salsabiela; Muhammad Fathan Abdul Majid
Eksergi Vol 19, No 1 (2022)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v0i0.6132

Abstract

The world's oil reserves are running low, which makes the government also implement a mandatory B30 policy starting in early 2020. With this policy, it is necessary to develop energy by utilizing renewable energy such as vegetable oil that can be converted into biodiesel. Waste cooking oil is one of the vegetable oils that has the potential to be processed into biodiesel because the use of waste cooking oil in Indonesia is still not developed. In this study, we report the yield of biodiesel from waste cooking oil with variations in the ratio of the number of moles and weight of heterogeneous catalysts. Biodiesel is made by esterification and transesterification with a heterogeneous catalyst (CaO), then a separation process is carried out to separate the biodiesel produced from the by-product in the form of glycerol. The separated biodiesel is then analyzed for density, viscosity, flash point, and pour point. The results showed that the best biodiesel was at a mole ratio of 1:24 with 3% CaO catalyst. Based on the analysis data, this biodiesel has the largest yield of 72.49% with a viscosity value of 4.9806 cSt, a flash point value of 72.5 oC, a pour point value of 0 oC, and a density value of 0.8662 g/ml and calorific value. 8837,302 cal/gram. With the results of the analysis, that are in accordance with the quality standards of SNI 7182:2015.
Sintesis Bio-nanosurfaktan sebagai Deterjen Ramah Lingkungan dari Kombinasi Ekstrak Getah Pepaya (Carica papaya L) dan Daun Sengon (Paraserianthes falcataria L. Nielsen) Tunjung Wahyu Widayati; Hendri Yudisai; I K Gary Devara
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2018: PROSIDING SNTKK 2018
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

The purpose of this research is to study formulations Bio-Nano Surfactant by combining papaya sap, Sengon leaf, and HCl to obtain the most efficient concentration in neutralizing calcium oxalate, determine the effect of detergency by Bio-Nano Surfactant and determine the level of contamination by Bio-Nano Surfactant". Detergent formulations using completely randomized design (CRD) with two factors of HCl (0.1%, 0.15%, 0.2%, 0.4%, 0.6%) and papaya sap- sengon leafs concentration (10%, 20%, 30%). The indicator of this research is based on the best combination of parameters to decrease calcium oxalate, protease enzyme levels, and the highest detergency effectiveness in cleaning the substrat. After detergency test, combination of 10% papaya sap - Sengon leafs and 0.2% HCL comes as the best combination. For nanofication, the best sample split into two samples with and without PEG 4000 as nanoparticles template. The samples after nanofication has nano size orde which are the sample with PEG 4000 is smaller (458-686nm) than the sample without PEG 4000 (703-897nm). The detergency of nanoficated samples are higher than before. The results of contaminant level "Bio-Nano Surfactant" is 165.2 ppm for COD and 21.6 ppm for BOD which is lower than COD and BOD limits.
Pengaruh Aktivator Stardec terhadap Proses Pembuatan Pupuk Organik dari Kotoran Sapi Tunjung Wahyu Widayati; Sri Wahyu Murni; Afika Syahliana Sriadi; Deka Prima Rosalinda
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Cow’s feces originated from farms dairy an organic waste that can causing an environmental pollutiontherefore need to be process to make something such as fertilizer using activators that help the decompositionprocess run faster. Activator used in this experiment is Stardec. Decomposition of cow’s feces becomingorganic fertilizer by mixing cow’s feces with Stardec activator. Ratio of cow’s feces weight (Metric Ton) byweight (Kilogram) of Stardec activator is 1:0; 1:1; 1:2; 1:3; 1:4. Thereafter, add the anorganic fertilizer(Urea, KCl, SP-36) and limestone to the mixture each about 2,5 kilograms after that cover the mixture withplastic wrap and make some holes with bamboo. The allowing the mixture for 3 weeks to make an analysis ontemperature and C/N ratio for 3 days. The experiment result shows that process of composition for 21 dayson Stardec with 10 kg weight to produce organic fertilizer consist about 15,23% organic carbon, 0,84% totalnitrogen, 18,13 C/N ratio. These result meet the quality standards set by the Minister of AgricultureNo.70/Permentan/SR.140/10/2011.
Pengaruh Aktivator Effective Microorganism 4 Terhadap Proses Pembuatan Pupuk Organik dari Kotoran Sapi Sri Wahyu Murni; Tunjung Wahyu Widayati; Bassmall Andriouty Pratama; Satriyo Oktavianto
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Cow's excrements originated from slaughterhouse is an organic waste that can damage the environmenttherefore need to be process to make something such as fertilizer using activators that help thedecomposition process run faster. Activator used in this experiment is Effective Microorganism 4.Decomposition of cow’s excrements becoming organic fertilizer by mixing cow’s excrements with EffectiveMicroorganism 4 activator. Ratio of cow’s excrements weight (Metric Ton) by volume (Liter) of EffectiveMicroorganism 4 activator is 1:0; 1:1; 1:2; 1:3; 1:4. Thereafter, add the anorganic fertilizer (Urea, KCl,SP-36) and limestone to the mixture each about 2,5 kilograms after that cover the mixture with plastic wrapand make some holes with bamboo. The experiment result for this study using Effective Microorganism 4activator by adding 4 liter in the decomposition process for 18-21 days to produce organic fertilizer consistabout 15,01% organic carbon, 0,87% total nitrogen, 17,25 C/N ratio. These result meet the qualitystandards set by the Minister of Agriculture No.70/Permentan/SR.140/10/2011.
Pemanfaatan Cangkang Bekicot sebagai Koagulan Alternatif untuk Meningkatkan Kualitas Air Sungai Code Tunjung Wahyu Widayati; Dyah Tri Retno; Nanik Wijayanti
Eksergi Vol 9, No 1 (2009): Versi Cetak
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v9i1.7586

Abstract

Pemanfaatan Cangkang Bekicot sebagai Koagulan Alternatif untuk Meningkatkan Kualitas Air Sungai Code
Leaching SiO₂ On Coal Fly Ash As Ammonium Adsorbent In Tofu Liquid Waste Using Hydrothermal Method Danang Jaya; Anisa Anisa; Dian Prasetyani Basuki; Tunjung Wahyu Widayati
Eksergi Vol 19, No 3 (2022)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v19i3.8204

Abstract

Soybean is one of the main food commodities in Indonesia. One of the soybean processing that is often consumed is tofu. Inappropriate treatment of tofu liquid waste is very dangerous for life. It is noted that the ammonia content in tofu liquid waste is 23.3-23.5 mg/l which can cause odors that disturb the residents' comfort. One alternative solution for purifying tofu liquid waste is to carry out an adsorption process using coal fly ash. Fly ash contains metal oxides in the form of SiO₂, Al₂O₃, Fe₂O₃, CaO, MgO, K₂O, and Na₂O. The content of SiO₂ as much as 60-70% in it causes fly ash to be very potential to absorb ammonia levels. Extraction of SiO₂ using the sol gel method was carried out using fly ash that had gone through a hydrothermal process. The hydrothermal process is a crystallisation technique in a closed container with high temperature and pressure. After going through the extraction stage, the ongoing process was continued with the washing stage to produce silica powder to adsorb ammonium. The mass required for silica to achieve the optimum ammonia concentration adsorption efficiency is 0.25 gram/20 ml of tofu liquid waste. Meanwhile, the contact time required for silica to achieve the optimum adsorption efficiency of ammonium content is 30 minutes. It was noted that the silica from the optimised fly ash processing had a better quality than the unoptimized silica or commercial silica.