Hendri Muchtar
Balai Riset dan Standardisasi Industri Padang

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Pembuatan dan Karakterisasi Tinta Serbuk Printer Berbahan Baku Arang Aktif dari Limbah Padat Pengolahan Gambir Yudo Purnomo; Salmariza Sy; Hendri Muchtar; Robby Kumar
Jurnal Litbang Industri Vol 7, No 2 (2017)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (589.059 KB) | DOI: 10.24960/jli.v7i2.3242.71-80

Abstract

Research on the utilization of tannins and catechins of gambier has been done a lot. There is no research report however that examines the utilization of gambier processing solid waste. The objective of the research was to utilize the solid waste of gambier processing as a raw material of printer toner. The research was done through pyrolysis process of solid waste with temperature variation 400, 500, 600oC and time variation 30, 60 minutes. The highest carbon content was obtained 42% with 400oC temperature and 60 minutes. The pyrolysis process of the gambier solid waste was further carried out at the optimum temperature and time. The charcoal was activated with H3PO4 at concentrations 0; 5; and 10% for 24 hours, cooled and washed to remove residual of H3PO4, then drying in the oven at temperature 115oC for 24 hours. Size reduction process used a ball milling for 2 hours with speed 500 rpm. Fixed carbon content was obtained between 43-51%. The results of morphological testing by scanning electron microscope showed that the produced carbon powder had not a uniform size yet. The average particle size was between 5-10 µm with polydispersity index 0.9. The most mineral elements of carbon powder analysis using XRF were Ca, Mg, K, Si, Fe, and P. Testing of print quality based on ISO/IEC 19752:2004 using laser jet printers had not provided optimal results yet.ABSTRAKPenelitian pemanfaatan tanin dan katekin gambir telah banyak dilakukan. Namun, belum dilaporkan penelitian yang mengkaji pemanfaatan limbah padat pengolahan gambir. Tujuan penelitian adalah memanfaatkan limbah padat pengolahan gambir sebagai bahan baku pembuatan tinta serbuk printer. Penelitian dilakukan melalui proses pirolisis limbah padat dengan variasi suhu 400, 500, 600oC dan variasi waktu 30, 60 menit. Kadar karbon terikat tertinggi diperoleh sebesar 42% dengan suhu pirolisis 400oC selama 60 menit. Proses pirolisis limbah padat gambir selanjutnya dilakukan pada suhu dan waktu optimal tersebut. Arang aktif dilakukan aktifasi menggunakan aktifator H3PO4 pada konsentrasi 0, 5 dan 10% selama 24 jam, kemudian didinginkan dan dicuci untuk menghilangkan sisa H3PO4, dan selanjutnya dikeringkan dalam oven pada suhu 115 oC selama 24 jam. Proses penghalusan menggunakan ball milling selama 2 jam dengan kecepatan 500 rpm. Hasil pengujian kadar karbon terikat berkisar antara 43-51%. Hasil pengujian morfologi dengan alat Scanning Electron Microscope) memperlihatkan serbuk karbon yang dihasilkan belum mempunyai ukuran seragam. Ukuran partikel serbuk rata-rata 5-10 µm dengan indek polidispersitas sebesar 0,9. Kandungan unsur mineral yang terbanyak dari hasil analisis serbuk karbon adalah unsur Ca, Mg, K, Si, Fe, dan P. Uji coba kualitas cetak berdasarkan ISO/IEC 19752:2004 menggunakan printer laser belum memberikan hasil yang optimal.
Pengaruh Perbedaan Persentase Penambahan Gliserin dan Konsentrasi Larutan Ekstrak Gambir Terhadap Beberapa Sifat Fisika dan Kadar Tanin Tinta Stempel Silfia Silfia; Hendri Muchtar; Failisnur Failisnur
Jurnal Litbang Industri Vol 5, No 1 (2015)
Publisher : Institution for Industrial Research and Standardization of Industry - Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (68.126 KB) | DOI: 10.24960/jli.v5i1.667.53-59

Abstract

Gambier extract derived from leaves of Uncaria Gambier Roxb contain catechin and tannin which belonged to polyphenolic compounds. Gambier extract when added with ferosulfat salt will form a complex compound that can give a green color to black and can be used as a dye in the stamp ink. This study aims was to see how far the effect of adding glycerin and concentration of the Gambier extract solution against some physical properties and levels of tannin stamp ink. The ink manufacturing was done through a washing process of gambier, filtering, cube black manufacture, dissolution and formulation. The making of the stamp ink was done by a non factorial completely randomized design with a variation of the concentration of glycerin Ao = Without the addition of glycerin, A1 = 15% = 20% A2, A3 and A4 = 25% = 30% and the concentration of the extract gambier B1 = 20%, B2 = 25% = 30% B3, B4 and B5 = 35% = 45%. Results of the research showed that the addition of glycerin could increase some physical properties, especially against the homogenity of the ink. The best treatment was obtained on the use of gambier extracts 35% (B3) with pH 3.27, total solids 41.33%, tannin content 2.5788%, visual observation of color strength was clear and flat, viscosity was medium, not expand and not sticky, and homogeneous.ABSTRAKGambir berasal dari ekstrak daun tanaman Uncaria Gambier Roxb, mengandung senyawa katechin dan tanin yang termasuk golongan senyawa polifenol. Ekstrak gambir jika ditambahkan dengan garam ferosulfat akan membentuk senyawa komplek yang dapat memberikan warna hijau sampai hitam dan dapat digunakan sebagai pewarna pada tinta stempel. Penelitian ini bertujuan untukmelihat sejauh mana pengaruh penambahan gliserin dan konsentrasi larutan ekstrak gambir terhadap beberapa sifat fisika dan kadar tanin tinta stempel. Pembuatan tinta dilakukan melalui proses pencucian gambir, penyaringan, pembuatan cube black, pelarutan dan formulasi. Pembuatan tinta stempel dilakukan dengan rancangan acak lengkap non faktorial dengan variasi konsentrasi gliserin (0%, 15%, 20%, 25%, dan 30%) dan konsentrasi ekstrak gambir (25%, 30%, 35%, 40%, dan 45%). Hasil penelitan menunjukkan bahwa penambahan gliserin dapat meningkatkan beberapa sifat fisika terutama terhadap homogenitas tinta. Perlakuan terbaik diperoleh pada penggunaan ekstrak gambir 35% dengan pH 3,27, padatan total 41,33%, kadar tanin 2,58%, pengamatan visual terhadap kekuatan pewarnan jelas dan rata, kekentalan sedang, tidak mengembang dan tidak lengket serta homogen.