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Journal : Bulletin of Chemical Reaction Engineering

Kinetic Study of Anaerobic Digestion of Ketchup Industry Wastewater in a Three-stages Anaerobic Baffled Reactor (ABR) Indro Sumantri; Budiyono Budiyono; Purwanto Purwanto
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 2 Year 2019 (August 2019)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (785.981 KB) | DOI: 10.9767/bcrec.14.2.2838.326-335

Abstract

The anaerobic digestion of the ketchup industry’s wastewater in a three-stage 60 L capacity baffled reactor has been studied. The effect of concentrations of the initial chemical oxygen demand (2727.3-12086.7 mg/L), on the ABR performance and kinetic models were investigated. The ABR performance was evaluated by measuring the concentrations of each compartment of the COD, calculating its percentage removal, and the acquired data were fitted to the kinetic models. From the initial input, the three-stage ABR successfully removed 90 % of COD, for the initial COD until the concentration was 5324.6 mg/L it achieved stationary phase with HRT 5-10 days, while for initial COD until the concentration was 12086.7 mg/L is attained, the stationary was at 10 days. The kinetic model of second order Grau was suitable for the data, with k2 of 0.6061 d-1 and R2 of 0.9955. 
Optimization of Monoglycerides Production Using KF/CaO-MgO Heterogeneous Catalysis Luqman Buchori; Didi Dwi Anggoro; Indro Sumantri; Riko Rikardo Putra
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2655.954 KB) | DOI: 10.9767/bcrec.14.3.4251.689-696

Abstract

The production of monoglyceride or monoacylglycerol (MAG) from triglycerides and glycerol has been studied. The purpose of this research was to study the effect of using KF/CaO-MgO catalyst on MAG production with batch reactor. The effect of reaction temperature, reaction time, and catalyst loading was investigated using Response Surface Methods (RSM). The reaction temperature, reaction time, and catalyst loading were varied at 200-220 ºC,  2-4 hours, and 0.1-0.3 % w/w, respectively. The maximum yield of monoglyceride 41.58% was achieved the optimum conditions of  catalyst loading of 0.19 % (w/w), reaction temperature of 208.4 ºC, and reaction time of 3.20 hours.  
Kinetic of Biogas Production in a Batch Anaerobic Digestion Process with Interference of Preservative Material of Sodium Benzoate Indro Sumantri; Hadiyanto Hadiyanto
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 3 Year 2020 (December 2020)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.3.9366.898-906

Abstract

Sodium benzoate is a preservative compounds which are widely used for both food and beverage products. The treatment of waste water containing this compound was normally conducted in a anaerobic digestion (AD) using a batch reactor system at a room temperature. The anaerobic process eventually produced biogas which can be used for bioenergy. This research was aimed to evaluate the production of biogas from by synthetic solution models containing sodium benzoate (SB). The experiment was performed in a variation of Mixed Liquor Suspended Solid (MLSS) of 4.8 and 7.2 g/L, and initial sodium benzoate concentration of 400, 600, and 800 mg/L. The digestion was performed at 60 days, while the biogas content was measured every 2 days. The results indicated a reduction in the cumulative biogas by the addition of sodium benzoate, compared to the control condition. Moreover, the decrease in organic loading rate (OLR) of SB in wastewater follows the first order kinetic with kinetic rate constant (k) was 0.0432 to 0.1254 (day−1) for MLSS of 4.8 g/L and 0.0276 to 0.0372 (day−1) for 7.2 g/L MLSS. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).