Rian Kurniawan
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia

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Synthesis of Iron-Doped Zirconium Titanate as a Potential Visible-Light Responsive Photocatalyst Rian Kurniawan; Sri Sudiono; Wega Trisunaryanti; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (243.375 KB) | DOI: 10.22146/ijc.38616

Abstract

Synthesis and properties of iron-doped zirconium titanate (ZrTiO4) as a potential visible-light-responsive photocatalyst had been conducted. Various iron dopant concentration and calcination temperature were investigated toward the properties of Fe-doped ZrTiO4. The photocatalyst material was synthesized by sol-gel and impregnation method. Titanium tetraisopropoxide (TTIP) was used as a precursor, embedded on zirconia fine powder. A certain amount of iron (1, 3, 5, 7 and 9 wt.%) was introduced into the photocatalyst system from iron(II) sulfate heptahydrate (FeSO4·7H2O). Photocatalyst with various iron concentration calcined at 500 °C. ZrTiO4 with 5% iron additionally was calcined at 700 and 900 °C. Characterization was performed by using XRD, FT-IR, SR-UV, and SEM-EDX. The presence of iron on the surface of ZrTiO4 was proved by EDX analysis. Fe-doped ZrTiO4 with the lowest bandgap (2.83 eV) is 7% of iron content after calcination at 500 °C.
Synthesis and Characterization of Cu-Doped Zirconium Titanate as A Potential Visible-Light Responsive Photocatalyst Katarina Rachma Andita; Rian Kurniawan; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 19, No 3 (2019)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (14.502 KB) | DOI: 10.22146/ijc.39778

Abstract

Synthesis and characterization of Cu-doped zirconium titanateas a potential visible-light responsive photocatalyst had been conducted. Titanium tetraisopropoxide (TTIP) was used as a precursor of Ti source, reacted to ZrO2 powderand CuSO4·5H2O with various Cu concentrations of 0, 1, 3, 5, 7 and 9% (w/w) by sol-gel method. Zirconium titanate with Cu concentration of 5% was calcined at various temperatures of 500, 700 and 900 °C. All materials were characterized by using XRD, FTIR, SRUV, and SEM-EDX. The characterization proved that the materials were potential as a model of visible-light responsive photocatalyst. Composite with optimum bandgap energy (Eg) was obtained at 5% Cu content after 500 °C with an absorption edge wavelength of 431.93 nm and the bandgap of 2.87 eV.
Cobalt Doping on Zirconium Titanate as a Potential Photocatalyst with Visible-Light-Response Emilya Faridatul Sulaikhah; Rian Kurniawan; Mokhammad Fajar Pradipta; Wega Trisunaryanti; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 20, No 4 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (14.694 KB) | DOI: 10.22146/ijc.49459

Abstract

Synthesis of cobalt-doped zirconium titanate (Co-doped ZrTiO4) as a potential photocatalyst with visible-light-response had been conducted. Materials used in this research were titanium tetraisopropoxide (TTIP) as a precursor of TiO2, ZrO2 as another semiconductor for coupling, and CoSO4·7H2O as the source of cobalt dopant. The composite was prepared by the sol-gel method with various cobalt contents and calcination temperatures. Composites with various Co dopant contents (0, 1, 3, 5, 7, and 9% (Co wt./Ti wt.)) were calcined at 500 °C for 4 h. In addition, the composite with 5% of dopant content was calcined at 700 and 900 °C to observe the influence of calcination temperature. All samples were characterized by using X-ray powder diffraction method (XRD), Fourier-transform infrared spectroscopy (FTIR), specular reflectance UV-Vis spectroscopy (SRUV), and scanning electron microscopy equipped with X-ray energy dispersive spectroscopy (SEM-EDS). Co-doped ZrTiO4 with the lowest bandgap (2.94 eV) was achieved in a sample containing 3% of cobalt content calcined at 500 °C.
Zinc-Doped Titania Embedded on the Surface of Zirconia: A Potential Visible-Responsive Photocatalyst Material Azizia Alifi; Rian Kurniawan; Akhmad Syoufian
Indonesian Journal of Chemistry Vol 20, No 6 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (14.651 KB) | DOI: 10.22146/ijc.51172

Abstract

The preparation and characterization of zirconia-supported titania with a zinc dopant had been studied. Zinc-doped titania was grown on the surface of zirconia by the sol-gel method. Various zinc contents and calcination temperatures were applied to investigate the zinc doping effect and crystal structure of the zirconia-titania composite. X-ray diffraction method, Fourier-transform infrared spectroscopy, and UV-Vis reflectance spectroscopy were performed to characterize the composite. The morphology of the composite was observed by using a scanning electron microscope, and its composition was analyzed by using energy dispersive spectroscopy. Among various zinc dopant contents and calcination temperatures investigated, doping with 5% zinc (Zn wt./Ti wt.) at 900 °C calcination shows the best result in response to visible light with a bandgap of 2.87 eV and absorption edge wavelength of 432.61 nm.