Indonesian Journal of Chemistry
Vol 20, No 4 (2020)

Cobalt Doping on Zirconium Titanate as a Potential Photocatalyst with Visible-Light-Response

Emilya Faridatul Sulaikhah (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Rian Kurniawan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Mokhammad Fajar Pradipta (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Wega Trisunaryanti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Akhmad Syoufian (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
10 Jun 2020

Abstract

Synthesis of cobalt-doped zirconium titanate (Co-doped ZrTiO4) as a potential photocatalyst with visible-light-response had been conducted. Materials used in this research were titanium tetraisopropoxide (TTIP) as a precursor of TiO2, ZrO2 as another semiconductor for coupling, and CoSO4·7H2O as the source of cobalt dopant. The composite was prepared by the sol-gel method with various cobalt contents and calcination temperatures. Composites with various Co dopant contents (0, 1, 3, 5, 7, and 9% (Co wt./Ti wt.)) were calcined at 500 °C for 4 h. In addition, the composite with 5% of dopant content was calcined at 700 and 900 °C to observe the influence of calcination temperature. All samples were characterized by using X-ray powder diffraction method (XRD), Fourier-transform infrared spectroscopy (FTIR), specular reflectance UV-Vis spectroscopy (SRUV), and scanning electron microscopy equipped with X-ray energy dispersive spectroscopy (SEM-EDS). Co-doped ZrTiO4 with the lowest bandgap (2.94 eV) was achieved in a sample containing 3% of cobalt content calcined at 500 °C.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...