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SINTESIS DAN KARAKTERISASI FOTOKATALIS TiO2 –Cu AKTIF SINAR TAMPAK Riyani, Kapti; Setyaningtyas, Tien; Dwiasi, Dian Windy
Prosiding Vol 3, No 1 (2012)
Publisher : Prosiding

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Penelitian ini diawali dengan pembuatan fotokatalis TiO2-Cu dengan cara impregnasi basah dan fotodeposisi, dengan perbandingan mol TiO2 : Cu2+ adalah 100:0 ; 99:1 ; 98:2 ; 97:3 dan 96:4. Karakterisasi TiO2-Cu menggunakan SEM untuk mengetahui morfologi partikel fotokatalis, UV-Vis DRS untuk mengetahui energi celah pita, FTIR untuk mengetahui gugus fungsi pada fotokatalis yang telah dibuat serta kristalinitas fotokatalis dianalisis menggunakan XRD. Hasil penelitian menunjukkan bahwa telah berhasil dilakukan sintesis TiO2-Cu, dilihat dari analisis morfologi menggunakan SEM. Dari analisis SEM terlihat bahwa penambahan logam Cu akan merubah morfologi dari fotokatalis TiO2. Perhitungan energi celah pita berdasarkan hasil UV-Vis DRS didapatkan energi celah pita TiO2 sebesar 3,43 eV. Penambahan dopan logam Cu menurunkan energi celah pita dari TiO2. Karakterisasi XRD muncul nilai 2θ pada 29,607 dan 48,401 yang menunjukkan terbentuknya kristal monoclinic H2Ti3O7. Karakterisasi FTIR menunjukkan terjadi perubahan serapan spesifik dari TiO2 yang menandakan terjadi perubahan struktur dari TiO2. Serapan TiO2-Cu secara keseluruhan mengalami peningkatan yang menunjukkan semakin banyak air yang terserap pada permukaan fotokatalis.
Karakteristik Biopelet Karbonisasi Biomassa berbasis Daun Jati dan Jagung menggunakan Perekat Tanah Liat Ropiuidn, Ropiudin; Toibah, Toibah; Dwiasi, Dian Windy; Syska, Kavadya
Jurnal Agritechno Jurnal Agritechno Vol. 18, Nomor 1, April 2025
Publisher : Depertemen Teknologi Pertanian Universitas Hasanuddin

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.70124/at.vi.1804

Abstract

Biomass carbonization plays a vital role in the production of biopellets as a sustainable and environmentally friendly energy source. This study aimed to evaluate the physicochemical characteristics of carbonized biopellets, including density, moisture content, ash content, volatile matter, combustion rate, and mechanical durability. The biopellets were produced from a mixture of teak leaves, corn cobs, and corn stalks, with clay as a binder, and subjected to carbonization under different formulations to assess their influence on final product quality. The experimental design employed a Completely Randomized Design (CRD) with nine treatment combinations and three replications, resulting in a total of 27 experimental units. The treatments consisted of variations in raw material composition (K1, K2, K3) and clay binder proportions (P1, P2, P3). Analyses included physical, chemical, thermal, and durability assessments. Data were analyzed using Analysis of Variance (ANOVA) followed by Duncan’s Multiple Range Test (DMRT) at a 5% significance level. Results indicated that the carbonized biopellets had density values ranging from 0.49 to 0.56 g/cm³, moisture content from 5.34% to 6.82%, ash content from 20.38% to 34.24%, volatile matter from 66.82% to 79.88%, combustion rate from 0.03 to 0.05 g/min, and mechanical durability ranging from 43.72% to 55.03%. The composition of raw materials significantly influenced most parameters, except combustion rate and durability. Meanwhile, binder proportion had a highly significant effect on all parameters except for durability, which showed a significant effect. Based on the results, the carbonized biopellets met the SNI 8021-2014 standard requirements for moisture and volatile matter, while density and ash content were outside the specified limits.