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Journal : KOVALEN: Jurnal Riset Kimia

Antioxidant Potential of Ethanol Extract from Mango Parasite (Dendrophthoe petandra) to Maintain Crude Palm Oil (CPO) Quality Ninik Triayu Susparini; Rohmatulloh; Boima Situmeang; Isna Lailatusholihah; Siti Rohmiyati
KOVALEN: Jurnal Riset Kimia Vol. 8 No. 2 (2022): August Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2022.v8.i2.15954

Abstract

The present study aimed to determine the effectiveness of adding natural antioxidants from ethanolic extract of mango parasite (Dendrophthoe petandra) to oxidation stability of crude palm oil (CPO) during storage. The parameters tested were levels of free fatty acid (FFA), acid values, and deterioration of bleachability index (DOBI). The antioxidant activity of D. petandra extract obtained was IC50 of 6.369 ppm. Concentrations of D. petandra extract range from 200 to 1000 ppm. Based on the results, the ethanolic extract of D. petandra was able to reduce the FFA and acid value and increase the DOBI compared to the negative control. The lowest FFA levels and acid numbers were obtained from samples with addition of 1000 ppm natural antioxidants with FFA of 4.2% and acid value of 7.4 mg KOH/g, while the DOBI value increased to 1.300.
Validation of Boron Analytical Methods on Standard Reference Material Tomato Leaves from NIST No. 1573a with Isothermal Distillation by UV-Vis Spectrophotometry Isna Lailatusholihah; Roto; Agus Kuncaka; Ninik Triayu Susparini
KOVALEN: Jurnal Riset Kimia Vol. 8 No. 2 (2022): August Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2022.v8.i2.15955

Abstract

Boron analysis by UV-Vis spectrophotometry has been developed through distilling triethoxy borane into the curcumin solution. In the distillation of ester borane, an esterification reaction occurs between borate and ethanol. Validation of isothermal distillation methods by UV-Vis spectrometry needs to be done to obtain specific, accurate, and reproducible results. The distillation for 24 hours at 25°C gave the optimum result. UV-Vis spectrophotometry wavelength was 535 nm. The standard curve was linear in the concentration range of 1-5 ppm (R2 = 0.9995) with a sensitivity of 0.0902 ppm-1, a limit of detection of 0.002±0.001 ppm, the limit of quantification of 0.006±0.001 ppm, and percent recovery of 88%.