Peni Pujiastuti
Program Studi Analis Kimia, Fakultas Teknik Universitas Setia Budi, Surakarta

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Degradation Degradasi Pewarna Tekstil Remazol Violet 5R Dengan Metode Elektrooksidasi Menggunakan Elektroda Grafit: Degradation of Remazol Violet 5R Textile Dyes with Electrooxidation Method Using Graphite Electrode Suseno Suseno; Petrus Darmawan; Peni Pujiastuti; Sumardiyono Sumardiyono
JURNAL SAINS TEKNOLOGI & LINGKUNGAN Vol. 8 No. 2 (2022): JURNAL SAINS TEKNOLOGI & LINGKUNGAN
Publisher : LPPM Universitas Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jstl.v8i2.370

Abstract

Remazol Violet 5R textile dye degradation experiment has been carried out by electrooxidation method using graphite electrodes. The electrooxidation device consists of a plastic tub with a size (p x l x h) = 20 x 20 x 25 cm which is equipped with an electric stirrer and graphite electrodes using a used battery anode. Graphite electrodes consist of 3 pairs arranged in parallel. This dye degradation experiment was carried out using a batch system (not continuous) with variations in stirring time of 15, 30, 45, and 60 minutes, while the other variables were fixed, namely the concentration of dye 100.24 mg/liter, electrolyte NaCl 2.06 g/liter, 12 V voltage, and a stirring speed of 250 rpm. The dye solution before degradation and after degradation was measured for absorbance using a UV-Vis spectrophotometer at the maximum wavelength, to determine the percentage decrease in absorbance and optimum contact time. The experimental results showed that the percentage decrease in absorbance was constant after a contact time of 30 minutes with an absorbance of 98.36%. This indicates that the optimum contact time for the degradation of Remasol Violet 5R dye is 30 minutes. From the experiments that have been carried out, it can be concluded that the electrooxidation method using graphite electrodes can be used as an alternative waste treatment method, especially in terms of removing dyes in textile industry wastewater.
Chemical Oxygen Demand (COD) Analysis Ink Printing Waste Water Using Titrimetry Method: Analisis Chemical Oxygen Demand (COD) Air Limbah Tinta Industri Percetakan Menggunakan Metode Titrimetri Dian Khristiani Suhari; Peni Pujiastuti
Jurnal Kimia dan Rekayasa Vol. 1 No. 1 (2020): Jurnal Kimia dan Rekayasa Edisi Juli 2020
Publisher : Program Studi S1 Teknik Kimia, Fakultas Teknik, Universitas Setia Budi

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (73.728 KB) | DOI: 10.31001/jkireka.v1i1.9

Abstract

The printing industry produces wastewater from the ink used. Contains organic and inorganic pollutants such as lead, cadmium, chromium and zinc. Having a quality that exceeds the quality standards for wastewater. If it is discharged into the environment it can pollute the receiving water body. Need to do an analysis of organic pollutant content, by measuring the parameters of Chemical Oxygen Demand (COD). Determination of COD numbers in printing industry wastewater ink using titrimetry method (SNI 6989.73: 2009). Perform oxidation-reduction titration using Ferro Ammonium Sulfate (FAS) solution in printing industry ink wastewater. This study conducted three sampling replications. The results of the first day research obtained a COD rate of 33,088 mg /L; second day 69,694.6 mg /L; third day 67,830.4 mg /L. All three samples had COD figures exceeding the printing industry wastewater quality standard of 125 mg / L. Printing industry wastewater is not suitable to be discharged into the environment. Abstrak Industri percetakan menghasilkan limbah cair dari tinta yang digunakan. Mengandung polutan organik dan anorganik seperti timbal, kadmium, kromium, dan zink. Memiliki kualitas yang melebihi baku mutu air limbah. Apabila dibuang ke lingkungan dapat mencemari badan air penerima. Perlu dilakukan analisis kandungan polutan organik, dengan mengukur parameter Chemical Oxygen Demand (COD). Penentuan angka COD pada air limbah tinta industri percetakan dengan menggunakan metode titrimetri (SNI 6989.73:2009). Melakukan titrasi oksidasi-reduksi menggunakan larutan Ferro Amonium Sulfat (FAS) pada sampel air limbah tinta industri percetakan. Penelitian ini melakukan tiga kali ulangan sampling. Hasil penelitian hari pertama diperoleh angka COD sebesar 33.088 mg/L; hari kedua sebesar 69.484,6 mg/L; hari ketiga sebesar 67.830,4 mg/L. Ketiga sampel memilik angka COD melebihi baku mutu air limbah industri percetakan sebesar 125 mg/L. Air limbah tinta industri percetakan tidak layak dibuang ke lingkungan.
Potensial Fatty Oil Pollution from Restaurant Wastewater: Potensi Pencemaran Minyak Lemak Dari Air Limbah Rumah Makan Virgian Nur Kharismasari Faradillah; Peni Pujiastuti
Jurnal Kimia dan Rekayasa Vol. 3 No. 1 (2022): Jurnal Kimia dan Rekayasa Edisi Juli 2022
Publisher : Program Studi S1 Teknik Kimia, Fakultas Teknik, Universitas Setia Budi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31001/jkireka.v3i1.40

Abstract

Wastewater from community activities such as restaurants, with the characteristic number of parameters exceeding the quality standard of wastewater, which is not treated but is directly discharged into the receiving water body, will have the potential to cause environmental pollution. The source of waste generation comes from the use of soap in washing cutlery which will result in an increase in the pH of the wastewater, and the cooking process causes the presence of fatty oil waste. This study aims to determine the potential for water pollution from pH and fatty oil parameters in restaurant wastewater from three different categories in Karanganyar Regency. Laboratory descriptive research method. The test samples were taken in a time-composite manner at the outlets of fast food restaurants, traditional and coffee shops which were selected with the best-selling criteria. Determination of the potential for causing pollution is seen from the number of parameters compared to the quality standard of domestic wastewater according to Central Java Regional Regulation number 5 of 2012. The pH value is determined based on SNI 6989.11:2019, while the fat oil number is determined by the gravimetric method according to SNI 6989.10:2011. The results of the study showed that the pH value of the wastewater test samples from fast food restaurants was 7.5 – 7.82, traditional restaurants were 8.11 – 8.44, and coffee shops were 7.97-8.16. Fat oil figures show differences in the three test samples, fast food restaurant wastewater 92.67 mg/l, traditional restaurant 1,143 mg/l, and coffee 54.33 mg/l. Restaurant wastewater has a great potential to pollute the water environment on the fat oil parameters. Abstrak Air limbah dari kegiatan masyarakat seperti rumah makan, dengan karakteristik angka parameter melebihi baku mutu air limbah, yang tidak dilakukan proses pengolahan namun langsung dibuang ke badan air penerima, akan memiliki potensi menimbulkan pencemaran lingkungan. Sumber timbulan limbah berasal dari penggunaan sabun dalam pencucian alat makan akan mengakibatkan naiknya pH pada air limbah, dan proses memasak menyebabkan adanya limbah minyak lemak. Penelitian ini bertujuan untuk menentukan potensi pencemaran air dari parameter pH dan minyak lemak pada air limbah rumah makan dari tiga kategori yang berbeda di Kabupaten Karanganyar. Metode penelitian diskriptif laboratoris. Contoh uji diambil secara komposit waktu pada outlet rumah makan cepat saji, tradisional dan coffee shop yang dipilih dengan kriteria terlaris. Penentuan potensi menimbulkan pencemaran dilihat dari angka parameter yang dibandingkan dengan baku mutu air limbah domestik sesuai Perda Jateng nomor 5 tahun 2012. Angka pH ditentukan berdasarkan SNI 6989.11:2019, sedangkan angka minyak lemak ditentukan dengan metode gravimetri sesuai SNI 6989.10:2011. Hasil penelitian nilai  pH contoh uji air limbah rumah makan cepat saji sebesar 7,5 – 7,82, rumah makan tradisional 8,11 – 8,44 sebesar, dan coffee shop sebesar 7,97- 8,16. Angka minyak lemak menunjukkan perbedaan pada tiga contoh uji,  air limbah rumah makan cepat saji sebesar 92,67 mg/, rumah makan tradisional l,143 mg/l, dan coffee shop 54,33 mg/l. Air limbah rumah makan memiliki potensi besar menimbulkan pencemaran lingkungan air pada parameter minyak lemak.
Parameter Analysis of Nitrite, Nitrate, Ammonia, Phosphate in Agricultural Wastewater., Genuk Harjo, Wuryantoro, Wonogiri : Analisis Parameter Nitrit, Nitrat, Amoia, Fosfat Pada Air Limbah Pertanian Dusun Bendungan, Genuk Harjo, Wuryantoro, Wonogiri Syahriyati Mutiah; Sumardiyono; Peni Pujiastuti
Jurnal Kimia dan Rekayasa Vol. 3 No. 1 (2022): Jurnal Kimia dan Rekayasa Edisi Juli 2022
Publisher : Program Studi S1 Teknik Kimia, Fakultas Teknik, Universitas Setia Budi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31001/jkireka.v3i1.43

Abstract

The water quality of the Wuryantoro watershed decreased due to the entry of environmental pollutant burden in the form of land use and various human activities such as settlements, agriculture and industry. The land use of the Wuryantoro watershed was dominated by agricultural land. This study aimed to analyze the quality of agricultural wastewater based on the parameters of Nitrate, Nitrite, Ammonia, Phosphate and calculate the agricultural pollution load originating from the residence time of fertilization. Grabs sampling was carried out at 3 points of agricultural land outlets representing the entire population before entering the Wuryantoro river. The research was conducted in April - June 2015 by analyzing parameters of Nitrate, Nitrite, Ammonia and Phosphate used referring to SNI and APHA using a UV-Vis Spectrophotometer. The end point showed that the level and load of NO3 and NH3 parameters were still below the quality standard according to PP 82 of 2001 concerning Water Quality Management and Water Pollution Control, while the NO¬2 parameter for 2 days and 6 days of fertilization time exceeded the quality standard. The PO4 parameter was above the required threshold based on the Class II criteria according to PP 82 of 2001. AbstrakKualitas perairan DAS Wuryantoro semakin menurun akibat masuknya sumber beban pencemar lingkungan berupa pemanfaatan lahan dan berbagai aktivitas manusia seperti permukiman, pertanian dan industri. Penggunaan lahan DAS Wuryantoro didominasi oleh lahan pertanian. Penelitian ini bertujuan untuk menganalisis kualitas air limbah pertanian berdasarkan parameter Nitrat, Nitrit, Amonia, Fosfat dan menghitung beban pencemaran pertanian yang berasal dari waktu tinggal pemupukan. Teknik sampling secara grabs sampling dilakukan pada 3 titik outlet lahan pertanian yang mewakili dari keseluruhan populasi sebelum masuk ke sungai Wuryantoro. Penelitian dilakukan pada bulan April - Juni tahun 2015 metode analisis parameter Nitrat, Nitrit, Amonia dan Fosfat yang digunakan mengacu pada SNI dan APHA dengan menggunakan alat Spektrofotometer UV-Vis. Hasil penelitian menunjukkan bahwa kadar dan beban pencemaran parameter NO3 dan NH3 masih berada di bawah baku mutu menurut PP 82 Tahun 2001 tentang Pengelolaan Kualitas Air dan Pengendalian Pencemaran Air, sedangkan parameter NO­2 untuk waktu tinggal pemupukan 2 hari dan 6 hari melebihi baku mutu. Pada parameter PO4 sudah di atas ambang batas yang dipersyaratkan berdasarkan kriteria Kelas II menurut PP 82 tahun 2001.
Komparasi Metode Titrimetri Dengan Spektrofotometri UV-Vis pada Analisis Chemical Oxygen Demand (COD) Output IPAL Domestik Berdasarkan Linieritas, Akurasi dan Presisi: Comparison Of Titrimetric With UV-Vis Spectrophotometry Methods For The Analysis Of Chemical Oxygen Demand (COD) Output Domestic IPAL Based On Linierity, Accuracy and Precision Ida Lestari; Peni Pujiastuti; Yari Mukti Wibowo
JURNAL SAINS TEKNOLOGI & LINGKUNGAN Vol. 9 No. 4 (2023): JURNAL SAINS TEKNOLOGI & LINGKUNGAN
Publisher : LPPM Universitas Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jstl.v9i4.416

Abstract

The method of a test must be evaluated and tested to ensure that the method is capable of producing valid data. So that validation needs to be done as a quality control that provides assurance that the measurements and results obtained are reliable. This study aims to determine the value and comparison of the values of linearity, accuracy, and precision of the titrimetric and spectrophotometric methods in COD analysis. Determination of the COD value for the titrimetric method was carried out by redox titration using a solution of Ferro Ammonium Sulphate (FAS). While the spectrophotometric method was carried out using UV-Vis spectrophotometry at a wavelength of 420 nm. The research results obtained a linear regression value for the titrimetric method of 0.9989, while the spectrophotometric method was 0.9991, this indicates that the linear regression value of the spectrophotometric method is better than the titrimetric method. The results of the accuracy analysis for the titrimetric method obtained a value of 111.48%, while for the spectrophotometric method it was 103.11%, this shows that the accuracy value of the spectrophotometric method is better than the titrimetric method. The precision analysis results for the titrimetric method obtained a value of 1.77%, while for the spectrophotometric method it was 1.55%, this shows that the spectrophotometric method has a better precision value than the titrimetric method. Based on the comparison of the results of statistical validation using the T-test, there was no significant difference in data between the titrimetric method and the spectrophotometric method.