Risfidian Mohadi
Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia

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ZnAl-Humic Acid Composite as Adsorbent of Cadmium(II) From Aqueous Solution Jeri Rahmadan; Veronika Parhusip; Neza Rahayu Palapa; Tarmizi Taher; Risfidian Mohadi; Aldes Lesbani
Science and Technology Indonesia Vol. 6 No. 4 (2021): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2021.6.4.247-255

Abstract

The modified ZnAl composites with humic acid (HA/ZnAl composite) were a coprecipitation method used as an adsorbent to remove cadmium(II) in an aqueous solution. The synthesized material was characterized using SEM-EDX, FTIR, and XRD. From the analysis using XRD, there is a widening peak at an angle of 2???? (24°), FTIR analysis there is a new peak at 1000 cm−1 and 1220 cm−1 and SEM analysis show that there is a change in surface morphology due to more aggregated particles. The experimental results on HA/ZnAl composite followed the PSO model, where the cadmium(II) removal process was chemical adsorption. The adsorption isotherm follows the Langmuir model where adsorption occurs in a monolayer and maximum adsorption capacity was obtained 38.76 mg/g higher than pristine. Thermodynamics of the adsorption process of cadmium(II) in an aqueous solution occurred spontaneously where G < 0 at all temperatures and endothermic properties were tested. The performance of the HA/ZnAl composite showed that strong potential as an adsorbent of low cost, high efficiency, easy operation, and good reusability. The cadmium(II) was absorbed on the surface of HA/ZnAl composite by surface complexation and chelating interactions, and surface complexation was the main route of cadmium(II) removal. In addition, HA/ZnAl composite has excellent treatment efficiency in actual aqueous solution.
Interlayer Modification of West Java Natural Bentonite as Hazardous Dye Rhodamine B Adsorption Satria Jaya Priatna; Yusuf Mathiinul Hakim; Sahrul Wibyan; Siti Sailah; Risfidian Mohadi
Science and Technology Indonesia Vol. 8 No. 2 (2023): April
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2023.8.2.160-169

Abstract

This work reports the modification of West Java natural bentonite as an effective adsorbent for rhodamine B dye. The modification was finished by sodium intercalation at room temperature to get low-energy preparation. Characterization of bentonite-modified adsorbent was used SEM, XRD, FTIR, and BET analysis. The material pore size and surface area were increased by 0.303 nm and 178.710 m2/g on Na-bentonite. The adsorption mechanism conformed well with the Freundlich isotherm model and pseudo-second-order kinetics equations. The adsorption process by thermodynamic analysis was endothermic and advantageous. Under the optimum condition of pH 6 (confirmed by pHpzc), initial dye concentration of 125 mg/L, and the adsorbent dosage of 0.09 g for 65 minutes, the Na-bentonite has a larger adsorption capacity (Qm) of 142.86 mg/g, while the different adsorbent dosages of 0.11 g for 75 minutes, the adsorption capacity of natural bentonite (Qm) reaches 140.85 mg/g. This work provides a method for establishing a low-energy preparation adsorbent of bentonite-based on Na intercalant as a low-cost and valuable adsorbent for waste dye removal.