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Sintesis dan Karakterisasi Bioplastik dari Pati Biji Nangka (Artocarpus heteropyllus) dengan Penguat CMC (Carboxy Methyl Cellulose) Sulfi Indriani; Mohammad Wijaya; Muhammad Syahrir
Chemica: Jurnal Ilmiah Kimia dan Pendidikan Kimia Vol 24, No 1 (2023): CHEMICA
Publisher : Jurusan Kimia FMIPA UNM

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (348.669 KB) | DOI: 10.35580/chemica.v24i1.43981

Abstract

ABSTRAK          Penelitian ini bertujuan untuk mengetahui pengaruh penambahan CMC terhadap karakteristik bioplastik dari pati biji nangka.Tahap penelitian meliputi preparasi sampel, pembuatan bioplastik dan karakterisasi yang meliputi biodegradasi dengan metode Soil Burial Test, ketahanan air, ketahanan panas, kuat tarik dan elongasi dengan Universal Testing Mechine, serta gugus fungsi dengan FT-IR dan morfologi permukaan dengan instrument SEM. Bioplastik yang diperoleh berwarna bening. Variasi komposisi CMC 0%-15% mempengaruhi karakteristik bioplastik yang dihasilkan meliputi biodegradasi 32,66-74,69% , ketahanan air 15,26-93,91%, ketahanan panas 58,33-93°C, kuat tarik 0,7642-2,4549 N/mm2 dan elongasi 6,06-14,25%. Komposisi variasi CMC berbanding lurus dengan persen degradasi dan kuat tarik, serta berbanding terbalik dengan ketahanan air dan ketahanan panas. Hasil identifikasi gugus fungsi FTIR pada bilangan gelombang 3286,63 cm-1 yang mengindikasikan adanya gugus O-H, pada bilangan gelombang 2924,29 cm-1 mengindikasikan adanya gugus C-H, sedangkan pada bilangan gelombang 999,34 cm-1 menunjukkan adanya gugus C-O, pasa bilangan gelombang 1331,59 cm-1, 1416,82 cm-1 dan 1589,79 cm-1 mengindikasikan adanya senyawa aromatik sederhana dan pada bilangan gelombang 702,96 cm-1 mengindikasikan adanya gugus C=C. Morfologi permukaan bioplastik tidak rata dengan adanya retakan dan sisa partikel pati yang tidak larut sempurna. Kata Kunci: Sintesis, Karakterisasi, Bioplastik, Biji Nangka, CMC ABSTRACT          This study aims to determine the effect of the addition of CMC on the bioplastic characteristics of jackfruit seed starch. The research phase includes sample preparation, bioplastic manufacture and characterization which included biodegradation with Soil Burial Test method, water resistance, heat resistance, tensile strength and elongation with the Universal testing Mechine, as wel as fungsional groups with FT-IR and surface morphology with the SEM instrument. The obtained bioplastic is clear. Variations in the composition of CMC 0%-15% affect the characteristics of the resulting bioplastics including biodegradation 32.66-74.69%, water resistance 15.26-93.91%, heat resistance 58.33-93°C, tensile strength 0.7642 -2.4549 N/mm2 and elongation 6.06-14.25%. The composition of the CMC variation is directly proportional to the percent degradation and tensile strength, and inversely proportional to the water resistance and heat resistance. The results of the identification of the FTIR functional group at a wave number of 3286.63 cm-1 which indicates the presence of an O-H group, at a wave number of 2924.29 cm-1 indicates the presence of a C-H group, while at a wave number of 999.34 cm-1 it indicates the presence of a C-O group. wave numbers 1331.59 cm-1, 1416.82 cm-1 and 1589.79 cm-1 indicated the presence of simple aromatic compounds and at wave numbers 702.96 cm-1 indicated the presence of a C=C group. The surface morphology of bioplastics is uneven with cracks and residual starch particles that are not completely dissolved.Keywords: Synthesis, Characterization, Bioplastic, Jackfruit, CMC
Exploration of Cellulose-Based Matrix Materials: A Comparative Study in the Development of Radar Absorbing Materials for Military Applications Indriani, Sulfi; Sri Yanto; I Nengah Putra
Jurnal Serambi Engineering Vol. 11 No. 1 (2026): Januari 2026
Publisher : Faculty of Engineering, Universitas Serambi Mekkah

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Abstract

Exploring cellulose-based matrix materials for Radar Absorbing Materials (RAM) is a strategic way to advance defence technology, emphasising both technical effectiveness and environmental sustainability. This study uses a systematic literature review (SLR) approach to identify, evaluate and analyse previous research on the use of cellulose-based matrices compared with conventional materials such as epoxy, polyurethane (PU) and graphene. Comprehensive data was collected from indexed scientific databases (ScienceDirect, SpringerLink, Wiley and Google Scholar), covering publications from 2013 to 2025. The findings reveal that, when combined with graphene or carbon nanotube (CNT) fillers, cellulose aerogels can achieve reflection loss (RL) values as low as −70 dB, outperforming most conventional materials. Furthermore, carboxymethyl cellulose (CMC) with an ultrathin thickness of only 0.028 mm demonstrates high absorption efficiency of 98.2%. While limitations remain in terms of bandwidth and thermal stability, cellulose offers significant advantages, including low density, low cost, biodegradability and the availability of renewable resources. These results highlight cellulose as a highly promising alternative matrix material for RAM in military applications, while simultaneously supporting the green defence agenda and strengthening the resilience of the defence industry.
Strategic Risk Assessment of Hazardous Energetic Chemicals in Defense Supply Chains: A Coupled Risk Framework for Ammonium Perchlorate (AP), RDX, and HMX Indriani, Sulfi; Yanto, Sri; Putra, I Nengah; Kurniawati, Firdah Dipi Juni
Indonesian Journal of Advanced Research Vol. 5 No. 4 (2026): April 2026
Publisher : PT FORMOSA CENDEKIA GLOBAL

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55927/ijar.v5i4.16438

Abstract

Energetic materials such as ammonium perchlorate (AP), RDX, and HMX are essential in modern defense systems but pose multidimensional risks across industrial supply chains. This study presents a literature-based assessment integrating hazard profiling with node-based risk characteristics; RDX shows high acute process instability, AP poses environmental risks due to perchlorate mobility in groundwater, and HMX presents strategic coupling risk from production interdependence. A Coupled Risk Triangle Model is proposed, framing energetic chemical governance as a dynamic system linking reactive instability, environmental persistence, and strategic supply concentration. The findings indicate that risks extend beyond occupational safety to environmental regulation and national security resilience. Effective mitigation therefore requires lifecyle-integrated governance, supply diversification, and resilience-oriented industrial strategies.
Nanocellulose for Military Textiles: Innovations, Applications, and Challenges Indriani, Sulfi; Yanto, Sri; Putra, I Nengah
JKPK (Jurnal Kimia dan Pendidikan Kimia) Vol 10, No 3 (2025): JKPK (Jurnal Kimia dan Pendidikan Kimia)
Publisher : Program Studi Pendidikan Kimia FKIP Universitas Sebelas Maret

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/jkpk.v10i3.104648

Abstract

Military textiles must withstand ballistic threats, high temperatures, and chemical exposure while remaining lightweight, durable, and multifunctional. Nanocellulose, especially cellulose nanofibrils (CNF) and cellulose nanocrystals (CNC), offers high specific strength, biodegradability, and tunable surface chemistry, making it a promising complement to conventional high performance fibers such as aramid. This structured review synthesizes peer reviewed studies published from 2015 to 2025 and retrieved from Scopus, Web of Science, and ScienceDirect, focusing on ballistic resistance, flame retardancy, and antibacterial functionality. Evidence shows that CNF and CNC reinforcement improves energy dissipation networks and strength to weight ratios, with several composites approaching aramid based benchmarks. For flame protection, nanocellulose coatings and hybrid layers reduce peak heat release rates by up to 38% and promote dense char barriers that limit heat and mass transfer. Antibacterial performance is typically achieved through functionalization with Ag, ZnO, or chitosan, often delivering over 90% inhibition of Escherichia coli and Staphylococcus aureus. Key barriers include production cost and scalability, moisture sensitivity that can reduce long term durability, and weak interfacial compatibility with aramid and ultra high molecular weight polyethylene (UHMWPE). Future work should prioritize scalable green manufacturing, interface engineering for durable hybrids, and validation under military relevant durability and laundering standards. Overall, nanocellulose is a strong candidate for next generation sustainable military textiles.