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An Enhanced Nickel Recovery from Mixed Hydroxide Precipitate Through Selective Leaching with KMnO4 Oxidant Muhammad Dikdik Gumelar; Rahayu; Saputra; Agustanhakri; Husin; Andrameda; Taqwatomo; Putra; Indrijarso; Saudi; Indriasari; Arfiana; Yuliani; Mumtaz; Mirahati
Jurnal Sains Materi Indonesia Vol. 26 No. 1 (2024): Jurnal Sains dan Materi Indonesia
Publisher : BRIN Publishing (Penerbit BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/jsmi.2024.3136

Abstract

Mixed Hydroxide Precipitate (MHP), a metal precipitate with the dominant nickel and cobalt content in hydroxide compounds, can be leached as a lithium battery precursor. In this study, KMnO4 was used as an oxidant agent to increase the solubility of Ni and Co. The variation of the sulfuric acid concentration (0.5 - 1.5 M) as a leachate reagent, the concentration of KMnO4 (2.5 - 7.5 g/L), and the selective leaching temperature (60 - 80°C) were investigated. Solvent extraction using CYANEX 272 and D2EHPA was performed to separate the Ni, Co, and Mn. Atomic Absorption Spectrometry (AAS), Inductively coupled plasma mass (ICP-OES), and X-ray Fluorescence (XRF) were used to analyze the chemical compositions. At the same time, crystallographic analysis was observed with X-Ray Diffraction. It was observed that potassium permanganate increased the dissolution of Ni and Co to 91.3% and 85.4% but decreased the dissolution of Mn (37.53%) under the following conditions: 1.75 M sulfuric acid, 7.5 g/L potassium permanganate, and 60°C temperature. High purity of nickel crystal (99.64%) was observed with spontaneous nucleation due to the supersaturated nickel solution after solvent extraction with CYANEX 272. Thus, using permanganate ion as selective leaching of Ni and Co from Mn is promising.
Mass balance of nickel manganese cobalt cathode battery recycle process Sri Handayani; Wahyudi Isqi Shahril; Ismojo Ismojo; Sri Rahayu; Yurian Ariandi Andrameda; Muhammad Dikdik Gumelar; Hanif Yuliani; Dita Adi Saputra; Saddam Husin
Journal of Bioresources and Environmental Sciences Vol 3, No 3 (2024): December 2024
Publisher : BIORE Scientia Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/jbes.2024.19939

Abstract

Batteries made from lithium, nickel, manganese, and cobalt are widely used, especially in the electrical industry, because they have high specific capacity, high safety, and low production costs. According to the International Energy Agency (IEA), the consumption of batteries used for electric vehicles will increase from 8 million in 2019 to 50 million in 2025 and to 140 million in 2030. As a result, the waste produced is also increasing. This type of lithium ion battery (LIB) which contains heavy metal elements such as nickel, manganese and cobalt can be recycled. This research aims to calculate the mass balance of the recycling process for nickel manganese cobalt (NMC) battery cathodes.   The processing process begins with mixing, leaching, filtration, drying the results of the filtration process, molarity adjustment, Flame Assisted Spray Pyrolysis, and calcination. Based on the results of mass balance calculations for the NMC recycle battery cathode, the amount obtained was 43.427 kg/batch from 100 kg of cathode waste raw material. Apart from that, data was obtained on the metals that were successfully recycled, namely NiO, MnO, CoO, Fe2O3, MgO, Al2O3, Cr2O3, and Li2O. The research results provide information that NMC battery waste can be an opportunity for the NMC metal supply chain and can reduce environmental pollution.