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Cellulose Isolation and Characterization of Green Seaweed C. Lentillifera from Halmahera, Indonesia Mentari, Puji Rizana Ayu; Andreansyah, Ilham; Amanda, Putri; Marlina, Resti; Suharti, Suharti; Agustina, Siti; Syamani, Firda Aulya
Jurnal Bahan Alam Terbarukan Vol 12, No 2 (2023): December 2023 [Nationally Accredited Sinta 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v12i2.44578

Abstract

Caulerpa lentillifera or known as sea grapes is a type of green seaweed which is rich of nutritional components and widespread in the tropical regions in Asia, including Indonesia. Moreover, C. lentillifera contains of polysaccharides, such as cellulose which has the potential to various applications. In this study, C. lentillifera collected from Halmahera, Indonesia was determined for its chemical compositions (moisture, ash, extractives, hemicellulose, α-cellulose contents) and was extracted to obtain cellulose. Isolation of cellulose from C. lentillifera was done by soxhlet extracted using ethanol-benzene solvent to remove extractives, boiling to increase the amount of cellulose extracted, H2O2 bleaching to eliminate any remaining pigments and other contaminants, and freeze drying to get coarse powder of cellulose. The moisture content, ash, extractives, hemicellulose, α-cellulose of C. lentillifera were 11.94%, 31.62%, 11.53%, 35.57%, and 7.95%, respectively. The yield of cellulose obtained was 31.13% based on seaweed dry weight. FE-SEM (Field Emission-Scanning Electron Microscopy) analysis of C. lentillifera showed colonies of diatoms in elliptical shapes. FTIR (Fourier Transform Infrared) measurements indicating cellulose purity after extraction process. X-Ray Diffraction (XRD) analysis resulted some peaks of salt crystals in C. lentillifera and cellulose of C. lentillifera in amorphous form. After extraction, the crystallinity index of cellulose obtained was 37.3%.
Ultraviolet Shielding Performance of Coconut Coir as a Filler in Low-Density Polyethylene (LDPE) Plastic Mulch Andreansyah, Ilham; Mentari, Puji Rizana Ayu; Rahman, Herliati; Syamani, Firda Aulya
Wood Research Journal Vol 14, No 1 (2023): Wood Research Journal
Publisher : Masyarakat Peneliti Kayu Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51850/wrj.2023.14.1.13-24

Abstract

Plastic mulch is a layer of material applied to the soil surface to maintain moisture retention in the soil by preventing evaporation, reduce weed growth by blocking sunlight from reaching underlying weeds, and optimize fertilizer use by minimizing nutrient loss to the environment. However, the degradation of low-density polyethylene (LDPE), a thermoplastic commonly used for mulching, into microplastics due to exposure to UV radiation. This research explored the potential of coconut coir, a natural fiber with a high lignin content ranging from 30 to 46%, as a UV protective agent. The objective was to develop biodegradable plastic-based mulch composites that have better resistance to UV exposure by incorporating coir as a filler material in LDPE-based composites. Different ratios of coconut fiber were used (10%, 20%, 30%, and 40%), and Maleic anhydride grafted polyethylene (PE-g-MAH) was used as a binder at 2% of total weight mixed with LDPE in a rheomixer (80 rpm, 120°C for 10 min). The resulting plastic mulch bio-composites were evaluated for thermal, mechanical, UV resistance, and biodegradability properties. The results showed that the higher addition of coconut coir resulted in a decrease in the thermal and mechanical characteristics of the composite. However, the addition of higher coconut coir in the composite at 40% can provide an increase in the composite's resistance to ultraviolet light exposure, and the properties are easily degraded by the environment (biodegradable). 
Ultraviolet Shielding Performance of Coconut Coir as a Filler in Low-Density Polyethylene (LDPE) Plastic Mulch Andreansyah, Ilham; Mentari, Puji Rizana Ayu; Rahman, Herliati; Syamani, Firda Aulya
Wood Research Journal Vol 14, No 1 (2023): Wood Research Journal
Publisher : Masyarakat Peneliti Kayu Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51850/wrj.2023.14.1.13-24

Abstract

Plastic mulch is a layer of material applied to the soil surface to maintain moisture retention in the soil by preventing evaporation, reduce weed growth by blocking sunlight from reaching underlying weeds, and optimize fertilizer use by minimizing nutrient loss to the environment. However, the degradation of low-density polyethylene (LDPE), a thermoplastic commonly used for mulching, into microplastics due to exposure to UV radiation. This research explored the potential of coconut coir, a natural fiber with a high lignin content ranging from 30 to 46%, as a UV protective agent. The objective was to develop biodegradable plastic-based mulch composites that have better resistance to UV exposure by incorporating coir as a filler material in LDPE-based composites. Different ratios of coconut fiber were used (10%, 20%, 30%, and 40%), and Maleic anhydride grafted polyethylene (PE-g-MAH) was used as a binder at 2% of total weight mixed with LDPE in a rheomixer (80 rpm, 120°C for 10 min). The resulting plastic mulch bio-composites were evaluated for thermal, mechanical, UV resistance, and biodegradability properties. The results showed that the higher addition of coconut coir resulted in a decrease in the thermal and mechanical characteristics of the composite. However, the addition of higher coconut coir in the composite at 40% can provide an increase in the composite's resistance to ultraviolet light exposure, and the properties are easily degraded by the environment (biodegradable).