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Enhancing biodegradable polymer surface wettability properties through atmospheric plasma treatment and nanocellulose incorporation Shi, Shih-Chen; Hsieh, Chia-Feng; Rahmadiawan, Dieter
Jurnal Pendidikan Teknologi Kejuruan Vol 7 No 2 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v7i2.36723

This study investigates the effects of atmospheric plasma treatment on the surface properties of polylactic acid (PLA)/nanocrystalline cellulose (CNC) composites, aiming to improve their wettability and mechanical properties. The research utilizes a twin-screw extrusion process for fabricating PLA/CNC biocomposites, followed by surface modification using a custom-built, with a tenfold high-voltage atmospheric plasma system. The motivation of this treatment was to improved surface wettability and potential for enhanced adhesive bonding in ecological applications. These findings contribute to developing more sustainable composite materials by providing a method to improve the functionality of biodegradable polymers without compromising their environmental benefits.

Cellulose derivative as protection coating: Effect of nanoparticle additives on load capacity Shi, Shih-Chen; Tsai, Xiao-Ning
Teknomekanik Vol. 5 No. 2 (2022): Regular Issue
Publisher : Universitas Negeri Padang

The cellulose derivative hydroxypropyl methylcellulose (HPMC) has recently been extensively studied and used in mechanical applications. However, the softness and susceptibility to deformation of HPMC limited its further applications. In this study, metal nanoparticles (nano-aluminum and nano-copper) and nano-metal oxide particles (nano-alumina and nano-copper oxide) were used as additives to HPMC to form a composite film with improved mechanical properties, particularly load capacity. The addition of high levels of additives provided a higher load capacity. Among the nano-additives used in the study, Cu (2 wt.%) provided the composite with the highest load capacity, improving the load capacity of pure HPMC by 250%. The surface treatment of strengthening additives is an important step. Adding specific high-strength and high-modulus metal and metal oxide additives to the soft HPMC matrix can effectively improve the load-bearing capacity of the composite material. This study proposes a simple evaluation method for the load-bearing capability of the coating as well.

Enhancing mechanical properties of polylactic acid through the incorporation of cellulose nanocrystals for engineering plastic applications Shi, Shih-Chen; Hsieh, Chia-Feng; Rahmadiawan, Dieter
Teknomekanik Vol. 7 No. 1 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/teknomekanik.v7i1.30072

This study investigates the potential of enhancing the mechanical properties of polylactic acid (PLA) using cellulose nanocrystals (CNC). Recognized for their high specific strength and stiffness, CNCs are considered to improve the performance of PLA in engineering plastic applications. The synthesis involves a twin-screw extrusion process, which facilitates the uniform dispersion of CNC within the PLA matrix. The mechanical properties, including tensile strength and elongation at break, are comprehensively analyzed, highlighting the effects of CNC concentrations on the performance of PLA composites. Notably, the addition of 1 wt% CNC resulted in a 20% increase in strain at break compared to pure PLA, demonstrating enhanced ductility. Additionally, the thermal resistance of the composite increased by 0.3% with the inclusion of 5 wt% CNC. This study highlights the positive effect of CNC addition on the mechanical properties of PLA composites, making them more suitable for specialized engineering uses.

Revolutionizing polymethyl methacrylate toughness: Achieving 190% improvement with nanocellulose reinforcement while maintaining optical clarity Liu, Guan-Ting; Shi, Shih-Chen; Rahmadiawan, Dieter
Jurnal Pendidikan Teknologi Kejuruan Vol 7 No 4 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v7i4.39823

Polymethyl methacrylate (PMMA) is widely used in applications requiring high transparency and durability, such as optical lenses and protective coatings. However, its inherent brittleness limits its application in high-impact environments. This study investigates the incorporation of cellulose nanocrystals (CNCs) into PMMA to significantly enhance its toughness without compromising its optical clarity. By reinforcing PMMA with CNCs, the nanocomposites exhibited a remarkable 190% increase in toughness while maintaining 90% optical transparency. The innovation lies in achieving a balance between toughness and transparency through controlled CNC dispersion within the PMMA matrix, which minimizes excessive bonding that could lead to brittleness. Proper CNC dispersion was achieved through in-situ polymerization, allowing the nanocrystals to interact with the polymer matrix through van der Waals forces rather than covalent bonds. This approach reduces stress concentration and mitigates the formation of defects in the polymer matrix, ultimately leading to a tougher, more flexible material. In addition to enhancing mechanical properties, this study underscores the importance of controlling CNC content to preserve the intrinsic optical transparency of PMMA. These findings open new possibilities for CNC-reinforced PMMA in advanced applications that demand high mechanical performance coupled with excellent optical properties, extending its use in fields such as medical devices, protective coatings, and transparent structural materials.

Enhanced durability and tribological performance of polyvinyl alcohol/layered double hydroxide/tannic acid composites under repeated swelling cycles Rahmadiawan, Dieter; Shi, Shih-Chen; Zhuang, Wei-Ting; Indrawan, Eko; Fernanda, Yolli; Syahri, Budi; Irzal, Irzal
Teknomekanik Vol. 7 No. 2 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/teknomekanik.v7i2.32872

In recent years, the exploration of polyvinyl alcohol (PVA) composites has garnered significant attention due to their versatility applications in aqueous environments. However, despite their promise, neat PVA exhibit limitations such as significant mechanical degradation under repeated swelling cycles. This study investigates the durability and tribological performance of polyvinyl alcohol (PVA) composites reinforced with nickel-iron layered double hydroxide (LDH) and tannic acid (TA) under repeated swelling cycles. Building on previous research that explored composite preparation and initial characterization, this research emphasizes the effects of cyclic swelling on wear resistance, friction behavior, and mechanical properties. Tribological tests were conducted to evaluate the coefficient of friction (COF) and wear rate before and after multiple swelling cycles, alongside tensile strength and strain measurements. The results revealed that the PVA/TA2/LDH2 composite, containing the highest additive content, exhibited the lowest wear rate of 11.52 × 10⁻⁵ mm³/Nm after 3 swelling cycles, demonstrating superior resistance to material degradation. Although PVA/TA2/LDH1 exhibited a slightly lower COF, its wear rate was higher due to reduced reinforcement. Compared to neat PVA, which showed a COF increase from 0.45 to 0.53, the PVA/LDH/TA composites retained their tribological stability, with only a marginal increase in COF and wear rate. Similarly, tensile strength of PVA/TA2/LDH2 decreased by only 11% after 3 cycles (from 33.3 MPa to 30 MPa), while neat PVA experienced a 25.5% reduction (from 30 MPa to 22.5 MPa). These findings highlight the potential of PVA/LDH/TA composites for applications in aqueous environments, offering significantly enhanced long-term performance and reliability.

Enhanced tribological performance of PLA/CNC composites: A comparison with phenolic resin and nylon Hsieh, Chia-Feng; Shi, Shih-Chen; Rahmadiawan, Dieter
Journal of Engineering Researcher and Lecturer Vol. 3 No. 3 (2024): Regular Issue
Publisher : Researcher and Lecturer Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58712/jerel.v3i3.169

PLA has been developed to replace plastic because it is degradable. For more advanced applications, more research is needed on PLA. This study investigates the tribological properties of phenolic resin, nylon, and PLA/CNC composites under varying sliding distances and loads. Both phenolic resin and nylon demonstrate exceptional wear resistance and stable friction coefficients. PLA/CNC composites exhibit improved wear resistance, showing a 17% reduction in friction coefficient at a 3 wt.% CNC content. While the wear volume of PLA/CNC composites increases with sliding distance, the addition of CNC enhances PLA’s self-lubricating properties and overall wear resistance. The correlation between dissipated energy and wear volume confirms that higher CNC content significantly improves the durability of PLA. These findings suggest that CNC has considerable potential as an additive to enhance the tribological performance of PLA composites, making it a valuable material for various applications requiring superior wear resistance.

Enhancing biodegradable polymer surface wettability properties through atmospheric plasma treatment and nanocellulose incorporation Shi, Shih-Chen; Hsieh, Chia-Feng; Rahmadiawan, Dieter
Jurnal Pendidikan Teknologi Kejuruan Vol 7 No 2 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v7i2.36723

This study investigates the effects of atmospheric plasma treatment on the surface properties of polylactic acid (PLA)/nanocrystalline cellulose (CNC) composites, aiming to improve their wettability and mechanical properties. The research utilizes a twin-screw extrusion process for fabricating PLA/CNC biocomposites, followed by surface modification using a custom-built, with a tenfold high-voltage atmospheric plasma system. The motivation of this treatment was to improved surface wettability and potential for enhanced adhesive bonding in ecological applications. These findings contribute to developing more sustainable composite materials by providing a method to improve the functionality of biodegradable polymers without compromising their environmental benefits.

Revolutionizing polymethyl methacrylate toughness: Achieving 190% improvement with nanocellulose reinforcement while maintaining optical clarity Liu, Guan-Ting; Shi, Shih-Chen; Rahmadiawan, Dieter
Jurnal Pendidikan Teknologi Kejuruan Vol 7 No 4 (2024): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v7i4.39823

Polymethyl methacrylate (PMMA) is widely used in applications requiring high transparency and durability, such as optical lenses and protective coatings. However, its inherent brittleness limits its application in high-impact environments. This study investigates the incorporation of cellulose nanocrystals (CNCs) into PMMA to significantly enhance its toughness without compromising its optical clarity. By reinforcing PMMA with CNCs, the nanocomposites exhibited a remarkable 190% increase in toughness while maintaining 90% optical transparency. The innovation lies in achieving a balance between toughness and transparency through controlled CNC dispersion within the PMMA matrix, which minimizes excessive bonding that could lead to brittleness. Proper CNC dispersion was achieved through in-situ polymerization, allowing the nanocrystals to interact with the polymer matrix through van der Waals forces rather than covalent bonds. This approach reduces stress concentration and mitigates the formation of defects in the polymer matrix, ultimately leading to a tougher, more flexible material. In addition to enhancing mechanical properties, this study underscores the importance of controlling CNC content to preserve the intrinsic optical transparency of PMMA. These findings open new possibilities for CNC-reinforced PMMA in advanced applications that demand high mechanical performance coupled with excellent optical properties, extending its use in fields such as medical devices, protective coatings, and transparent structural materials.

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