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KARAKTERISASI DAN PEMANFAATAN ASAP CAIR DARI TEMPURUNG BUAH BINTARO ( Carbera manghas Linn.) SEBAGAI KOAGULAN GETAH KARET Djeni Hendra; Totok K Waluyo; Arya Sokanandi
Jurnal Penelitian Hasil Hutan Vol. 32 No. 1 (2014): Jurnal Penelitian Hasil Hutan
Publisher : BRIN Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20886/jphh.2014.32.1.27-35

Abstract

Smoke liquid is a condensation product of raw material combustion containing cellulose, hemicellulose and lignin. Itproduces many compounds that have antimicrobial, antibacterial, and antioxidant effect such as organic acids and itsderivatives. Bintaro fruit shell is a waste of oil processing bintaro that are not utilized. Generally, latex coagulation usesformic acid or acetic acid that it's expensive and less environmentally friendly. Bintaro shell pieces is unused material andcontaining cellulose, hemicellulose, and lignin made into smoke liquid that is acidic and could reduce pH so the latex willcoagulate faster. The purpose of this study was to use smoke liquid of shell bintaro fruit shell as an alternative coagulant forrubber latex material.Smoke liquid wasmade using a modified drum kiln with a temperature of 400 C for 7 hours. Smoke liquid is purifiedby distillation up to 200 C. Smoke liquid that has been purified, further analyzed of its physical properties such as watercontent, viscosity, specific gravity, pH, acidity and phenol. Application of smoke liquid as rubber coagulant where doneusing smoke liquid concentration of 5%, 10%, 15%, 20%, while smoke liquid from coconut shell was used as acomparison. The results showed that the best results for coagulating was obtained from bintaro shell concentration of 20%and the fastest time for coagulating obtained from coconut shell smoke liquid concentration of 5%. Bintaro shell smokeliquid can be used as a rubber coagulant but for coagulation time isnot as fast as coconut shell smoke liquid.
KOMPONEN KIMIA SEPULUH JENIS KAYU KURANG DIKENAL : KEMUNGKINAN PENGGUNAAN SEBAGAI BAHAN BAKU PEMBUATAN BIOETANOL Arya Sokanandi; Gustan Pari; Dadang Setiawan; Saepuloh
Jurnal Penelitian Hasil Hutan Vol. 32 No. 3 (2014): Jurnal Penelitian Hasil Hutan
Publisher : BRIN Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20886/jphh.2014.32.3.209-220

Abstract

Lesser known wood species refers to the woods already utilized much by the communities but confined only one or two of uses, generally as sawn timber and merchant wood. Consequently, diversification attempts are necessary to impart more added values to these species. One of the possibilities for such is their uses for bioethanol manufacture. In relevant, research was already performed to look into the possible utilization of 10 local lesser-known wood species, which comprised pangsor (Ficus callosa Willd.), jengkol (Pithecellobium rouslatum Kosterm.), petai (Parkia speciosa Hassk.), mami (Maesopsis eminii Engl.), balsa (Ochroma grandiflora Rowlee), ki cauk (Pisonia umbellifera (Forst) Seem.), buru manuk (Litsea monopeIata Pers.), kei renghas (Buchamania arborescens Blume), kei bonen (Crypteronia paniculata Blume ) dan ki hampelas (Ficus ampelas Burm.f.), as raw material for bioethanol. In assessing for bioethanol manufacture, it necessitates initially the data/ information on basic properties of each wood species, particularly the chemical composition, which was examined through the wood chemical analysis in accordance with the accepted standar, i.e. Norman Jenkin, Indonesian National Standart (SNI) and TAPPI. Analysis result on those 10 woods revealed that the cellulose content varied about 42,03-54,95%, lignin 22,66-35,20%, pentosan 15,36-17,15%, water content 3,95-10,99%, ash content 0,56-2,89%, silica content 0,12-0,84%. Solubility in cold water 1,29-5,55%, solubility in hot water from 4,41-11,19%, solubility in alcohol-benzene from 2,95-4,60% and solubility in NaOH 1% 10,35-22,89%. For bioethanol manufacture, it is desired that the woods base high values of consecutively cellulose and pentosan content, and solubility in NaOH 1%; and concurrently have low content lignin, ash and silica, low solubilities in cold water, hot water and alcohol benzene. Judging from those criteria and aided by the statistics interpretation, it indicates that 8 out of 10 species were technically prospective as raw material for bioethanol, i.e. from most until the least being kei rengas, mami, petai, jering, balsa, ki hampelas, ki cauk, and burumanuk, respectively. Meanwhile, kei bonen and pangsor are regarded as unsuitable for bioethanol.