Jurnal Pendidikan Kimia (JPKim)
Vol 15, No 2 (2023): August

Unveiling ZrO2/natural zeolite catalytic performance on hydrocracking palm oil mill effluent residue

Junifa Layla Sihombing (Universitas Negeri Medan, Medan 20221, Indonesia)
Herlinawati Herlinawati (Universitas Negeri Medan, Medan 20221, Indonesia)
Ahmad Nasir Pulungan (Universitas Negeri Medan, Medan 20221, Indonesia)
Agus Kembaren (Universitas Negeri Medan, Medan 20221, Indonesia)
Gimelliya Saragih (Medan 20228, Indonesia)
Harmileni Harmileni (Medan 20228, Indonesia)
Rahayu Rahayu (Universitas Negeri Medan, Medan 20221, Indonesia)
Ary Anggara Wibowo (The Australian National University, North Road, 2601, Australian Capital Territory, Australia)



Article Info

Publish Date
27 Aug 2023

Abstract

Palm oil mill effluent (POME) is the largest liquid waste from crude palm oil production. This liquid waste still contains a lot of chemical components, solid deposits, and oil which is dangerous if released directly into the environment. The residual oil and grease components contained in POME can be further extracted and converted into fuel fractions. This study investigates the conversion of residual oil from POME into fuel fractions through hydrocracking. A ZrO2/Sarulla natural zeolite (SNZ) catalyst was used, characterized by a particle size of 1-1.5 µm, a surface area of 73.3 m2/g, a pore volume of 0.161 cc/g, and a pore diameter of 3.35 nm. The effect of catalyst mass was studied, with the total conversion increasing to a certain extent with increasing catalyst mass, however, an increase in coke formation decreased the product yield. The highest gasoline fraction selectivity was obtained with a catalyst mass of 0.09 wt% (~42%), while the kerosene fraction was most obtained with a catalyst mass of 0.15 wt% (~40%). The liquid product with a catalyst mass of 0.15 wt% had the highest HHV of 44.2 MJ/kg, a 12% increase from the HHV of POME oil residue (39.4 MJ/kg). The results demonstrate the potential of using residual oil from POME as a source for fuel production and the use of natural zeolite-based catalysts as hydrocracking catalysts.Keywords: Biofuel; Hydrocracking; Natural zeolite; Oil extracted; Palm oil mill effluent

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Journal Info

Abbrev

jpk

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Education Environmental Science

Description

Jurnal Pendidikan Kimia (JPKim) yang dikelola Program Pascasarjana Universitas Negeri Medan terbit 3 kali setahun, yakni bulan April, Agustus dan Desember. JPKim menerbitkan artikel ilmiah hasil-hasil penelitian pendidikan kimia dan kimia fundamental. JPKim juga menerbitkan artikel Review terkait ...