Indonesian Journal of Chemistry
Vol 23, No 6 (2023)

Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis

Mukhamad Nurhadi (Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda 75119, Indonesia)
Ratna Kusumawardani (Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda 75119, Indonesia)
Teguh Wirawan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Mulawarman, Samarinda 75119, Indonesia)
Sin Yuan Lai (School of Energy and Chemical Engineering, Xiamen University Malaysia, Selangor Darul Ehsan 43900, Malaysia
Kelip-kelip! Center of Excellence for Light Enabling Technologies, Xiamen University Malaysia, Bandar Sunsuria, Sepang 43900, Malaysia
Colle)

Hadi Nur (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
Center of Advanced Materials for Renewable Energy (CAMRY), Universitas Negeri Malang, Jl. Semarang No. 5, Ma)



Article Info

Publish Date
06 Dec 2023

Abstract

Fishbone-derived carbon sulfonate, modified through incipient wetness impregnation with titanium tetraisopropoxide and iron nitrate salts, displays catalytic activity in the oxidation of styrene with hydrogen peroxide (H2O2) as an oxidant. This was done to develop a cost-effective, non-toxic, and environmentally friendly bimetallic oxide catalyst, incorporating titanium and iron oxides on mesoporous-derived carbon fishbone to enhance styrene conversion and benzaldehyde selectivity in styrene oxidation using aqueous H2O2. The catalyst, featuring a combination of titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate, demonstrates higher catalytic activity than single oxide catalysts, such as titanium or iron oxides alone. Factors influencing the catalyst's performance are investigated by using FTIR, XRD, XRF, SEM, and BET surface area. The results reveal that the presence of both titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate and the catalyst's surface area creates a synergistic effect, the primary factors affecting its catalytic activity in styrene oxidation using H2O2 as an oxidant.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...