Jurnal Sains dan Teknologi Reaksi
Vol 21, No 02 (2023): JURNAL SAINS DAN TEKNOLOGI REAKSI

CHARACTERIZATION OF BIODEGRADABLE POLYURETHANE POLYMER BASED ON BENTONITE-CHITOSAN HYBRID PALM

SA, Sabiila Yasara (Unknown)
Syafruddin, S (Unknown)
Rihayat, Teuku (Unknown)



Article Info

Publish Date
18 Dec 2023

Abstract

Corrosion problems that often occur cause various damages and losses. The coating process has the advantage of being able to protect the metal surface from environmental influences that result in corrosion of the metal. The innovation of combining Polyurethane with Bentonite-Chitosan filler is able to make the polymer have better corrosion resistance. This study aims to see the effect of mixing between Polyurethane and Bentonite-Chitosan filler. The sample formulation used is polyurethane with variations of bentonite and chitosan 1%, 3%, 5%, 7%, 9%. The addition of Bentonite-chitosan filler affects the mechanical properties of the material. Characterization with the addition of Bentonite and Chitosan produces a polymer that has good thermal stability and good corrosion resistance. Test result Fourier Transform Infrared(FT-IR) there are functional groups NH, CH, C=O. Based on test resultsThermogravimetric Analysis(TGA) samplePolyurethane with modified bentonite 9%/chitosan 9% w/w has the best thermal stability among other samples where the sample starts to degrade (on set) at 419.22(oC) and stops degrading (end set ) at 521.94 (oC) with a weight loss of -31.156%. Polyurethane samples with 1% bentonite/chitosan 9% w/w modification had lower thermal stability where the sample started to degrade (onset) 312.21 (oC) and stopped degrading (end set) at 391.09 (oC) with a weight loss of -55.729 %. The results of the morphological test using the SEM tool show that the chitosan chains dispersed well into the bentonite interlayer. The corrosion test showed that the addition of bentonite and chitosan affected the corrosion rate, the greater the composition of bentonite and chitosan, the lower the corrosion rates. the best sample with a ratio of Polyurethane/Bentonite/Chitosan 9:9% w/w experienced the smallest corrosion rate of 5.08mpy and a mass loss of 0.1 gram.Keywords: Biodegradable, Corrosion, Polyurethane, Bentonite, Chitosan

Copyrights © 2023






Journal Info

Abbrev

JSTR

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Education Engineering Materials Science & Nanotechnology

Description

Jurnal Sains dan Teknologi Reaksi atau boleh disingkat dengan nama JSTR, berfokus pada banyak Aspek Teknik Kimia, seperti: Teknik Reaksi Kimia, Teknik Kimia Lingkungan, Energi Fosil dan Terbarukan, serta Sintesis dan Pengolahan Material. ...