agriTECH
Vol 44, No 3 (2024)

Synthesis of Biodiesel in Low-Grade Palm Oil using Geopolymer-ZnO Catalyst

Nabila, Yaasinta Lafasha (Unknown)
usman, Thamrin (Unknown)
Alimuddin, Andi Hairil (Unknown)



Article Info

Publish Date
26 Aug 2024

Abstract

This study aimed to synthesize biodiesel (fatty acid methyl ester) from low-grade palm oil using geopolymer-ZnO catalyst. The activity of catalyst was tested by mixing low-grade palm oil and methanol in a mole ratio of 1:10, with varying catalyst concentrations of 1%, 3%, and 5% at a temperature of 67 o C and different time intervals. Subsequently, the progression of the reaction was monitored using thin-layer chromatography (TLC). The results showed that catalyst ratios of 1:0, 1:1, and 1:2 provided complete conversion at concentrations of 3% and 5%. Geopolymer-ZnO catalyst reuse test was carried out using a concentration of 5%, followed by washing with n-hexane. After drying at 100 o C, the sample was reused in biodiesel synthesis. The reuse test findings showed optimum results at 1:2 variation and 2 hours of reaction time with total methyl ester conversion. In addition, the majority of the experiments performed were carried out using a 1:1 variation with a maximum of 3 repetitions, which consistently showed total conversion to methyl ester. Catalyst used was then characterized using FTIR, XRD, and XRF instruments, with the analysis results confirming that it was geopolymer-ZnO. Methyl ester obtained was analyzed using GC-MS, and the findings showed that the main compositions included methyl oleate (47.35%) and methyl palmitate (40.13%).

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Journal Info

Abbrev

agritech

Publisher

Subject

Agriculture, Biological Sciences & Forestry

Description

Agritech with registered number ISSN 0216-0455 (print) and ISSN 2527-3825 (online) is a scientific journal that publishes the results of research in the field of food and agricultural product technology, agricultural and bio-system engineering, and agroindustrial technology. This journal is ...