JURNAL REKAYASA KIMIA & LINGKUNGAN
Vol 17, No 2 (2022): Jurnal Rekayasa Kimia & Lingkungan (December, 2022)

Characterization and Application of HCl-Activated LTA Zeolite from Lampung Natural Zeolite (LNZ) for Bioethanol Purification

Ginting, Simparmin Br (Unknown)
Wardono, Herry (Unknown)
Islamia, Ulfa (Unknown)
., Darmansyah (Unknown)



Article Info

Publish Date
30 Dec 2022

Abstract

Lynde Type-A (LTA) zeolite as being molecular sieve and hydrophilic zeolite is used to dehydrate water in the purification of bioethanol. LTA zeolite from LNZ has a small surface area of 29,62 m2/g. Adding HCl activators to LTA Zeolite from LNZ was carried out to increase the surface area of LTA zeolite. The activation of LTA zeolite was carried through in a closed erlemeyer with various HCl concentration: 10% w/w, 15 % w/w, and 20% w/w and the ratio acid/LTA zeolite was 10 ml: 1 gram. The XRD analysis showed that the structure of LTA zeolite activated does not change despite the process of activation, and the highest percentage of crystallinity was obtained at 68.25% wt by concentration of HCl at 20 % w/w. The result of XRF analysis showed that the highest of impurity removal and the highest of decreasing ratio of Si/Al was in the LTA zeolite activated by HCl 20% w/w. The result of BET analysis showed the largest surface area at 45.67 m2/g obtained by adding 10% w/w of HCl activator, which was 45.67 m2/g, and the size of zeolites pore volume was 0.027 cc/g. The result performance of LTA zeolite activated obtained the highest purity of bioethanol by 99.74 % v/v at HCl concentration 20% w/w.

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Journal Info

Abbrev

RKL

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Energy Engineering

Description

The Journal of Chemical Engineering and Environment is an open access journal that publishes papers on chemical engineering and environmental engineering. The following topics are included in these sciences: Food and biochemical engineering Catalytic reaction engineering Clean energy technology ...