Bulletin of Chemical Reaction Engineering & Catalysis
2025: BCREC Volume 20 Issue 1 Year 2025 (April 2025)

Catalytic Performance of Cu-Ni supported on Rice Husk Ash-derived SiO2 for the Hydrogenation of Ethylene Carbonate to Ethylene Glycol

Maharani, Najiah Sephia (Unknown)
Rahmawati, Novia Dwi (Unknown)
Aziz, Isalmi (Unknown)
Maryati, Yati (Unknown)
Agustian, Egi (Unknown)
Widjaya, Robert Ronal (Unknown)
Yati, Indri (Unknown)
Prasetyo, Joni (Unknown)
Rinaldi, Nino (Unknown)
Dwiatmoko, Adid Adep (Unknown)



Article Info

Publish Date
30 Apr 2025

Abstract

Ethylene glycol, a crucial compound extensively utilized in solvents, coolants, antifreeze, polyester fiber production, and as a natural gas-drying agent, can be synthesized via the hydrogenation of ethylene carbonate. In this study, the synthesis, characterization, and catalytic performance of Cu-Ni/SiO2 catalysts for this reaction, utilizing silica (SiO2) derived from rice husk ash, were investigated. Silica was impregnated with copper (Cu) and nickel (Ni) by varying the weight ratio (Cu:Ni = 10, 7:3, 3:7, 10) to prepare bimetallic catalysts. X-ray Diffraction (XRD) analysis confirmed the presence of both Cu and Ni phases in all the catalysts. The 3Cu7Ni/SiO2 catalyst displayed the lowest reduction temperature and the largest surface area (257.97 m²/g). The 7Cu3Ni/SiO2 catalyst exhibited the highest acidity (1.91 mmol/g) and superior metal dispersion, as confirmed by the Field Emission Scanning Electron Microscopy - Energy Dispersive X-Ray (FE-SEM-EDX) analysis. Catalytic activity was evaluated in a batch reactor under 40 bar H2 pressure at 150 °C for 3 h with a catalyst-to-ethylene carbonate ratio of 5:1. Among the catalysts examined, the 7Cu-3Ni/SiO2 composition demonstrated the highest catalytic performance, achieving 15.14% conversion of ethylene carbonate and 80.51% selectivity towards ethylene glycol. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Copyrights © 2025






Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...