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Jurnal Akademika Kimia
Published by Universitas Tadulako
ISSN : 24775185     EISSN : 23026030     DOI : -
Core Subject : Science, Education,
Jurnal Akademika Kimia merupakan jurnal elektronik open access yang bertujuan untuk mempublikasi hasil-hasil penelitian terbaru dalam area pendidikan akademik khususnya pada bidang pendidikan kimia meliputi asesment pembelajaran, model pembelajaran dan pengembangan perangkat pembelajaran, serta kimia murni termasuk kimia organik, kimia anorganik, kimia analitik, kimia fisik, biokimia dan bidang kimia lainnya seperti kimia lingkungan.
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Articles 8 Documents
Search results for , issue "Vol 5, No 3 (2016)" : 8 Documents clear
Penentuan Waktu Optimum Dalam Pembuatan Bioetanol Dari Bonggol Pisang Tanduk(Musa paradisiaca formatypisa) Melalui Fermentasi Setiawati, Eka Lilis; Gonggo, Siang Tandi; Abram, Paulus Hengky
Jurnal Akademika Kimia Vol 5, No 3 (2016)
Publisher : Universitas Tadulako

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Abstract

Banana tuber contains 76% starch as a source of organic material that can be changed to bioethanol which is an alternative of fuel oil. This study aimed to determine the optimum time of fermentation in the process of producing bioethanol from banana (musa paradisiaca formatypisa) tuber. In this study the fermentation of banana tuber is determined using saccharomyces cereviseae with the variation time of 3, 4, 5, 6, 7, 8 and 10 days. The stages carried out in this study were preliminary or sample preparation, delignification, hydrolysis, fermentation and separation. Bioethanol from the fermented ricestraw was analyzed using alcoholmeter. The content of bioethanol product increased on days 3 to 7 and reach the optimum on the day 7 which was 8.90%, where on the day 8 and 10 decreased the ethanol content.
Uji Efektivitas Ekstrak Daun Sambiloto (A. Paniculata [burm.F] ness) Sebagai Bahan Pengawet Alami Tomat Dan Cabai Merah Pusung, Widya Astuti; Abram, Paulus Hengky; Gonggo, Siang Tandi
Jurnal Akademika Kimia Vol 5, No 3 (2016)
Publisher : Universitas Tadulako

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Abstract

Preservation synthetically or naturally is intended to extend the storability of tomato and red chili. Sambiloto (A. paniculata [Burm.f] Nees) is containing saponins that has anti-bacterial properties, therefore can be used as a preservative. The aim of this study was to investigate whether the extract of sambiloto leaf can be used as a natural preservative for tomato and red chili, and to determine the concentration of extract of sambiloto leaf which was effectively used as the preservative. The method used in this study was maceration to produce extract and iodometric titration to determine the levels of vitamin C before and after preservation. The results showed that the pickling tomatoes and red chili using extract of sambiloto leaf with a concentration of 6% sustained tomates up to 9 days and red chilies up to 11 days. Level of vitamin C contained in tomato was decreasing from 39.9 mg/100g to 37.54 mg/100g of material while red chilli is decreasing from 79.78 mg/100g to 72.74 mg/100g of material.
Uji Efektivitas Ekstrak Buah Bengkuang (Pachyrhizus erosus (L.) Urb.) Sebagai Pengawet Alami Cabai Merah (Capsicum annuum L) Citra Larasari; Baharuddin Hamzah; Suherman Suherman
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

Red chili is one of the food susceptible to decay. It caused by its high water content and so it causes to keep power of red chili abbreviated. Jicama (pachyrizuserosus (L.) Urb.) can act as a natural preservative for red chili due to the saponin compounds contained there in. This study aimed to prove the use of jicama extract as a natural preservative for red chili and to determine the most effective concentration of jicama extract as a natural preservative. The methods used in this study were a maceration to prepare the extract of jicama, and an iodimetric titration to determine the levels of vitamin C before and after curing. The results showed that jicama extract can be used as a natural preservative for red chili. The most effective concentration of jicama extract in preserving the red chili was 4% with preservation durability of red chili for 14 days in which the smallest level of vitamin C decreased among other concentrations, i.e. from 84.47 mg/100 g to 75.13 mg/100 g of material.
Bioetanol dari Limbah Kulit Singkong (Manihot Esculenta Crantz) Melalui Proses Fermentasi Erna, Erna; Said, Irwan; Abram, Paulus Hengky
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

Carbohydrates can be obtained from tubers such as cassava. Cassava is a plant from family euphorbiaceae and typical tropical plants. Cassava peel is a major waste that contains carbohydrates. The peel of cassava can be used as an energy source, namely ethanol.The purpose of this study is to determine the contents of ethanol through the fermentation process of cassava peel where obtainable from Malino village, Batu Daka West, Tojo Una-Una. The parameters in this study was content of ethanol that was obtained by fermentation using saccaromyces cerevisiae yeast. The fermentation process was conducted by varying day of fermentation, 4, 6, 8, and 10 days. The results showed the fermentation of ethanol with time variation respectively is 4.50, 5.20, 6.00 and 4.00%. In conclusion, it can be said that the highest ethanol content is 6.00% with the fermentation time of 8 days.
Pengaruh Ekstrak Seledri (Apium graveolens L.) Terhadap Kelarutan Kalsium Dalam Batu Ginjal Dewi, Evie Kurnia Maya; Walanda, Daud K.; Sabang, Sri Mulyani
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

Celery (apium graveolens L.) contains chemicals that can be used as traditional medicine for various treatments. The research objective is to determine the effect of celery (apium graveolens L.) extractsin dissolving calcium kidney stones and calcium to determine the relationship between the concentration of extract of celery (apium graveolens L.) with the solubility of calcium in the kidney stones. Determination of the solubility of calcium in an extract of celery is by flame fotometer. The concentration of the extract was varried into 1, 5, 10, 15 and 20%. It showed that a concentration of 1% can dissolve the calcium as much as 15.104%; concentration of 5% can dissolve the calcium as much as 18.708%; concentration of 10% can dissolve the calcium as much as 23.683%; concentration of 15% can dissolve the calcium as much as 28.869%; and to a concentration of 20% can dissolve the calcium as much as 35.048%. It can be concluded that celeries extract can dissolve calcium of kidney stones.
Studi Perbandingan Model Pembelajaran Kooperatif Tipe Jigsaw dan NHT (Numbered Head Together)Terhadap Hasil Belajar Stoikiometri Siswa Kelas X SMAN 8 Palu Nizar Nizar; Irwan Said; Suherman Suherman
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

The aim of this study is to compare the learning outcomes of student in SMA Negeri 8 Palu using the cooperative learning model between jigsaw and NHT (numbered head together) on the stoichiometry. This research using a quasi-experimental design with factorial 2 x 2. The population of this study is all student of class X SMA 8 Palu with academic year 2015/2016 which consists of four classes. The sample of this study consists of two classes, namely class XB with amount of 16 students (experimental class) and class XC with amount of 17 students (control class) which was determined by purposive sampling. Data was collected by using test instruments, namely an achievement test that contains the stoichiometry material. The examination of data was conducted by using statistical analysis t-test two sides and one side (right side) non-parametric or Mann-Whitney U test. The average score of the learning outcomes of student by using the jigsaw type was (78.00; SD = 13.63), and by using NHT type was (70.47; SD = 16.51). Based on statistical analysis of the hypothesis test for two sides, it was obtained a value of 0.195 Asymp sig (2-tailed) and was obtained a value 0.204 Exact Sig (1-tailed) of 0.204, both of datas were at the rejection area of H0 which was a significance value greater than 0.05 (P> 0.05). Therefore, it can be concluded that there was a difference in learning outcomes using the cooperative model jigsaw type with NHT type, furthermore the type of jigsaw better than the NHT on the learning outcomes of students of stoichiometry in class X SMA Negeri 8 Palu.
Pemanfaatan Ampas Tahu Sebagai Bahan Baku Pembuatan Biodiesel Trisnawati, Trisnawati; Walanda, Daud K.; Said, Irwan
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

Biodiesel is an alternative raw material for fuel of diesel motor made from vegetable oil. This study attempted to utilize tofu dregs as raw material for biodiesel. This study aimed to determine the yield of biodiesel produced and the content of methyl esters in the biodiesel yield, and to analyze the quality of biodiesel produced based on Indonesian national standard (SNI). This study consisted of four stages: the provision of samples, pre-treatment, esterification and transesterification, and analysis of the quality of biodiesel produced which include the density at 15 °C, the viscosity at 40 °C, and the moisture content. The results showed that the yield of biodiesel was 4.01%, and the content of methyl ester shown by larger Rf (0.87) using eluent of hexane:diethylether:formic acid. Results of the analysis of biodiesel quality obtained the density at 15°C was 864 kg/m3, the viscosity at 40 °C was 2.57 mm2/s, and the water content was 4%. Based on the parameters ofthe density at 15 °C and the viscosity at 40 °C, the product of biodiesel met the requirements of SNI, while in term of the water content the product did not meet the requirements of SNI.
Serbuk Dari Limbah Cangkang Telur Ayam Ras Sebagai Adsorben Terhadap Logam Timbal (Pb) Satriani, Dewi; Ningsih, Purnama; Ratman, Ratman
Jurnal Akademika Kimia Vol 5, No 3 (2016)
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Abstract

The aim of this study is to determine the optimum time and weight required for eggshell powder when it absorbs Pb, and to determine the adsorption capacity of the eggshell powder at the optimum condition for Pb with the shaking time variation of 10, 20, 30, 40 and 50 minutes. The weight variation of adsorbent is 0.25, 0.50, 0.75, 1 and 1.25 grams. The work steps in this study were production of the eggshell powder as the adsorbent, making of a solution of Pb 60 ppm, and determination the Pb concentration at equilibrium using a spectrophotometer spektrodirect respectively. The results obtained after the adsorption process for the time variation was 30 minutes, this optimum time giving %Pb absorbed was 94.65%. The weight variation of adsorbent is 1 gram, this optimum weight giving %Pb absorbed was 98.91%. Furthermore, the absorption capacity adsorbent of eggshell powder in both optimum conditions was 0.078 mg Pb/mg adsorbent.

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